1619-84-7

Basic information

• Product Name: HEXAFLUOROACETONE AZINE
• Synonyms: HEXAFLUOROACETONE AZINE
• CAS NO: 1619-84-7
• Molecular Formula: C₆F₁₂N₂
• Molecular Weight: 328.06
• Product Categories: Nitrogen Compounds;Organic Building Blocks;Others
• Mol File: 1619-84-7.mol

Chemical Properties

• Boiling Point: 67-68 °C(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.439 g/mL at 25 °C(lit.)
• Vapor Pressure: 759mmHg at 25°C
• Refractive Index: n20/D 1.3(lit.)
• BRN: 1916266
• CAS DataBase Reference: HEXAFLUOROACETONE AZINE(CAS DataBase Reference)
• NIST Chemistry Reference: HEXAFLUOROACETONE AZINE(1619-84-7)
• EPA Substance Registry System: HEXAFLUOROACETONE AZINE(1619-84-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 1619-84-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C6F12N2/c7-3(8,9)1(4(10,11)12)19-20-2(5(13,14)15)6(16,17)18

Upstream product

• 791-50-4 2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane 
• 1619-95-0 N-bromo-1,1,1,3,3,3-hexafluoro-2-propanimine 
• 53912-00-8 (CF₃)2CN-radical 
• 684-16-2 Hexafluoroacetone 
• 94718-61-3 1,1,1,3,3,3-Hexafluoro-2-[N'-(2,2,2-trifluoro-1-hydroxy-1-trifluoromethyl-ethyl)-hydrazino]-propan-2-ol 
• 684-23-1 bis(trifluoromethyl)diazomethane 
• 302-01-2 hydrazine 
• 3024-50-8 3,3-bis(trifluoromethyl)diazirine 
• 7803-57-8 hydrazine hydrate 
• 63465-11-2 Bis-(trifluormethyl)-bis-(trifluormethoxy)-sulfuran 
• 31340-36-0 lithium perfluoro isopropylideneamide 
• 66632-47-1 bis(hexafluoroisopropylideneamido)bis(trifluoromethyl)oxosulfur(VI) 

Downstream Products

• 53174-53-1 (CF₃)2CNC(CF₃)2(NP(OCH₃)(C₆H₅)2) 
• 53174-56-4 (CF₃)2CNC(CF₃)2(NP(OC₂H₅)(C₆H₅)2) 
• 883-67-0 <2,2,2-Trifluor-1-(bis-fluormethyl)-aethyl>-cyclohexan 
• 71268-08-1 Hexafluoraceton-<1,1-bis-(trifluormethyl)-3-phenyl-2-propinylhydrazon> 
• 36336-61-5 7,7-bis(trifluoromethyl)-norcarane 
• 36336-60-4 3-(2',2',2'-trifluoro-1'-trifluoromethylethyl)-cyclohex-1-ene 
• 67374-53-2 5-Diethylamino-1,1,1,8,8,8-hexafluor-6-phenyl-2,7-bis(trifluormethyl)-3,4-diazaocta-2,4,6-trien 
• 82488-73-1 1,1,1,6,6,6-Hexafluor-5-(2-morpholino-2-cyclohexen-1-yl)-2,5-bis(trifluormethyl)-3,4-diaza-2-hexen 
• 82489-22-3 1,1,1-Trifluor-7-methoxy-7-phenyl-2,5,5-tris(trifluormethyl)-3,4-diazahepta-2,6-dien 
• 1540-86-9 (1-anilino-2,2,2-trifluoro-1-trifluoromethyl)ethylhydrazine 
• 82489-28-9 7-Diethylamino-1,1,1-trifluor-6-phenyl-2,5,5-tris(trifluormethyl)-3,4-diazahepta-2,6-dien 
• 56263-80-0 1,5-dimethyl-1,5-diphenyl-3,3,7,7-tetrakis-trifluoromethyl-tetrahydro-pyrazolo[1,2-a]pyrazole 
• 690-39-1 1,1,1,3,3,3-hexafluoropropane 
• 58203-71-7 1,1,1-trifluoro-4-methyl-2-trifluoromethyl-hex-2-ene 

Related news

The structure of HEXAFLUOROACETONE AZINE (cas 1619-84-7) bis(triphenylphosphine)platinum07/24/2019

The crystal structure of hexafluoroacetone azine bis(triphenylphosphine)platinum, C42H30F12N2P2Pt, has been determined by single-crystal X-ray diffraction techniques. The compound crystallizes in the monoclinic space group C2/c with a 31.155(3), b 13.091(1), c 21.828(2) Å, β 109.23(1)° and Z =...detailed

Unsaturated nitrogen compounds containing fluorine. Part 20. Reactions of 2,5-dichloro-1,1,1,6,6,6-hexafluoro-3,4-diazahexa-2,4-diene and HEXAFLUOROACETONE AZINE (cas 1619-84-7) with cycloheptatriene07/23/2019

Thermal reaction (70 °C) of the dichloroazine CF3CCl=NN=CClCF3, 1, with cycloheptatriene (7) gave a complex mixture from which the major products were separated and identified as the dehydrochlorinated rearranged [32] cycloadducts 9 (28%) and 10 (23%) containing a CF3CHClN= group, a rearranged ...detailed

Relevant articles and documents

Synthesis and pyrolysis of perfluoroazo-2-propane

An improved method has been used to synthesize perfluoroazo-2-propane. Pyrolysis over the temperature range 450-514 K in a static system has been shown to be a homogeneous, first-order process. No pressure dependence was observed in the presence of excess inert gas (SF6). The only products were nitrogen and perfluoro-2,3-dimethylbutane. The rate constant (k) for the decomposition process is given by: log(k/s-1) = 16.7 ± 0.2 - (9856 ± 109)/T These results lead to a straightforward mechanism for the decomposition process (1) i-C3F7N2 i-C3F7 → i-C3F7N2 + i-C3F7 (2) i-C3F7N2 → i-C3F7 + N2 (3) 2i-C3F7 → (i-C3F7)2 The results are compared with those for other azo compounds.

Reaction of Pentafluoro-2-aza-1-propene with Perfluorinated Carbenes

Perfluorinated carbenes like :CF2 and:C(CF3)2 do not react with perfluoro-2-aza-1-propene (1) to yield the expected aziridines 2 and 8, respectively.Assuming the intermediacy of bis(trifluoromethyl)amide anion (4) the formation of the well known dimer of 1, (CF3)2N-CF=N-CF3 (3), can be explained as well as the formation of (CF3)2N-CF2H (5) and (CF3)2N-CF2Br (6).From 1,1,1,3,3,3-hexafluoro-2-propanimine (10) and :C(CF3)2 we did not obtain the aziridine 11 but (CF3)2C=N-CH(CF3)2 (12), which is formed by insertion into the NH-bond. - The structure of C4Cl8N2, which is formed as a by-product of the synthesis of perchloro-2-aza -1-propene, has been determined: Cl2C=N-CCl2-N=CCl2.

Stable fluorinated sulfuranes and sulfurane oxides. Synthesis and reactions

Bis(trifluoromethyl) sulfide, tetrafluoro-1,3-dithietane, and bis(trifluoromethyl) sulfoxide undergo oxidative addition when photolyzed with trifluoromethyl hypochlorite to form a new family of sulfuranes, bis(trifluoromethyl)bis(trifluoromethoxy)sulfurane (1) and tetrafluoro-1,3-tetrakis(trifluoromethoxy)dithietane (3), and of sulfurane oxides, bis(trifluoromethyl)bis(trifluoromethoxy)sulfurane oxide (2). Compounds 1 and 2 are hydrolyzed to bis(trifluoromethyl) sulfoxide and bis(trifluoromethyl) sulfone, respectively. Pyrolysis of 1, 2, or 3 gives bis(trifluoromethyl) sulfide, bis(trifluoromethyl) sulfoxide, and tetrafluoro-1,3-dithietane, respectively, plus bis(trifluoromethyl) peroxide. With primary amines, 1 and 2 yield N-alkylbis(trifluoromethyl)sulfimides and sulfoxyimides, and with N,N′-diethylaminotrimethylsilane, imine formation occurs. Sulfurane oxide 2 forms a new type of stable sulfurane oxide (4), bis(trifluoromethyl)bis(hexafluoroisopropylidenimido)sulfurane oxide, with lithium hexafluoroisopropylidenimine. Sulfurane 1 acts in a similar manner with the nucleophile but the sulfurane 5 is not isolated. Compounds 1 and 2 form α,α,α-(trifluoromethyl)anisole derivatives with substituted phenols. Secondary and tertiary alcohols are dehydrated by 1 or 2 to olefins but symmetrical alkyl ethers result when primary alcohols are reacted.