684-23-1

Upstream product

• 1584-03-8 perfluoro-2-methylpent-2-ene 
• 74770-43-7 perfluoro(2,5-dimethyl-4-oxa-3,5-diazahex-2-ene) 

Downstream Products

• 6145-14-8 Bis(trifluoromethyl)diazomethan-Triphenylphosphin-Addukt 
• 1619-84-7 hexafluoroacetone azine 
• 116-15-4 perfluoropropylene 
• 360-57-6 1,1,1,4,4,4-hexafluoro-2,3-bis-trifluoromethyl-but-2-ene 
• 865-52-1 tetramethylgermane 
• 34738-69-7 Pt{(CF₃)2CN₂(CF₃)2C}{P(C₆H₅)3}2 
• 50701-22-9 {(C₆H₅)3P}2PtC(CF₂)HCF₃ 
• 838-72-2 cyclo-C₆H₁₁N=NCH(CF₃)2 
• 725-54-2 cyclo-C₆H₁₁NHN=C(CF₃)2 
• 883-67-0 <2,2,2-Trifluor-1-(bis-fluormethyl)-aethyl>-cyclohexan 

Relevant academic research and scientific papers

Polyfluorinated Organic Compounds. X. Reaction of Perfluoro(2-methyl-2-pentene) with Sodium Azide

Perfluoro(2-methyl-2-pentene) reacts with sodium azide in acetonitrile at -10°C to yield perluoro-(3-azido-2-methyl-2-pentene), which is stable only at low temperature. When the reaction is carried out in the presence of ethanol at the same temperature, stable 5-ethoxy-5-pentafluoroethyl-4,4-bis(trifluorornemyl)-4,5-dihydro-1H-1,2,3- triazole is formed. The reaction in the system acetonitrile-ethanol at 2°C yields ethyl pentafluoropropanimidate and bis(trifluoromethyl)diazomethane. Thermolysis and photolysis of perfluoro-(3-azido-2-methyl-2-pentene) in CCl4, as well as in C6H6, toluene, or pentane, results in fromation of 3-pentafluoroethyl-2,2-bis(trifluoromethyl)-2H-azirine.

PERFLUOROALKYL DERIVATIVES OF NITROGEN. PART LIII. REACTION OF PERFLUORO(2,5-DIMETHYL-4-OXA-3,5-DIAZAHEX-2-ENE) WITH FLUORO-OLEFINS

Thermal decomposition of the title compound at 140 deg C gives mainly nitrogen, hexafluoroacetone and tetrakistrifluoromethylhydrazine while reaction with tetrafluoroethylene and chlorotrifluoroethylene affords equimolar mixtures of the 1:1 adducts (CF3)2C=NCF2CFXON(CF3)2 and (CF3)2C=NOCFXCF2N(CF3)2 (X=F and Cl) in highly yield via four-centre addition or a radical-cage process.