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2,6-Bis(tributylstannyl)pyridine is a chemical compound characterized by a pyridine ring with tributylstannyl groups attached to the 2 and 6 positions. The tributylstannyl groups are organotin compounds, each featuring four butyl groups connected to a tin atom. This versatile reagent is widely utilized in organic synthesis, particularly for cross-coupling reactions that promote the formation of carbon-carbon bonds. Its utility in creating complex organic molecules and pharmaceuticals is notable, although care must be taken in handling due to the potential toxicity and environmental impact of organotin compounds.

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  • 163630-07-7 Structure
  • Basic information

    1. Product Name: 2,6-Bis(tributylstannyl)pyridine
    2. Synonyms: 2,6-Bis(tributylstannyl)pyridine
    3. CAS NO:163630-07-7
    4. Molecular Formula: C29H57NSn2
    5. Molecular Weight: 657.18958
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 163630-07-7.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2,6-Bis(tributylstannyl)pyridine(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2,6-Bis(tributylstannyl)pyridine(163630-07-7)
    11. EPA Substance Registry System: 2,6-Bis(tributylstannyl)pyridine(163630-07-7)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 163630-07-7(Hazardous Substances Data)

163630-07-7 Usage

Uses

Used in Organic Synthesis:
2,6-Bis(tributylstannyl)pyridine is used as a reagent in organic synthesis for facilitating cross-coupling reactions, which are essential for the formation of carbon-carbon bonds. Its application is crucial in the creation of complex organic molecules and pharmaceuticals, contributing to the advancement of chemical research and drug development.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 2,6-Bis(tributylstannyl)pyridine serves as a key reagent in the synthesis of various complex molecules with potential therapeutic applications. Its role in cross-coupling reactions allows for the construction of diverse molecular structures that can be further explored for their medicinal properties.
Used in Environmentally Conscious Practices:
While 2,6-Bis(tributylstannyl)pyridine is a valuable reagent, its use also necessitates adherence to environmentally conscious practices. This includes careful handling, disposal, and efforts to minimize the release of organotin compounds into the environment due to their known toxic effects.

Check Digit Verification of cas no

The CAS Registry Mumber 163630-07-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,3,6,3 and 0 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 163630-07:
(8*1)+(7*6)+(6*3)+(5*6)+(4*3)+(3*0)+(2*0)+(1*7)=117
117 % 10 = 7
So 163630-07-7 is a valid CAS Registry Number.

163630-07-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name tributyl-(6-tributylstannylpyridin-2-yl)stannane

1.2 Other means of identification

Product number -
Other names Pyridine,2,6-bis(tributylstannyl)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:163630-07-7 SDS

163630-07-7Downstream Products

163630-07-7Relevant articles and documents

Synthesis, structure, and properties of oligo-tridentate ligands; covalently assembled precursors of coordination arrays

Hanan, Garry S.,Schubert, Ulrich S.,Volkmer, Dirk,Riviere, Emmanuel,Lehn, Jean-Marie,Kyritsakas, Nathalie,Fischer, Jean

, p. 169 - 182 (2007/10/03)

Oligo-tridentate ligands based on alternating pyridines and pyrimidines were synthesised by Stille-type carbon-carbon bond-forming reactions. The terpyridine-like sites are designed to coalign upon metal complexation, giving rise to organized and rigidly spaced metal ions. Peripheral functionalization of the basic bis-tridentate framework was explored. The heterocycles in the ligands are in an all-trans conformation about the interannular bonds as indicated by comparison of their 1H NMR spectra. An X-ray crystal structure analysis of the nonchiral tris-tridentate ligand 2a reveals a helical structure in the solid state. The seven heterocycles form a helical structure with resulting overlap of the terminal pyridines. Their centroid-to-centroid distance is 4.523 A with 38.8° between the planes. NMR investigations support a helical conformation in solution as well. Electrochemical and UV absorption measurements indicate that the LUMO resides on the pyrimidine moiety of the ligands.

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