Synthesis of α,β-Unsaturated Ketones Containing a Perfluorinated Group
Acylation of various alkenes with trifluoroacetic anhydride in the presence of the dimethyl sulfide-boron trifluoride complex yields corresponding unsaturated ketones with a perfluoroacyl moiety.The effect of the substrate structure on the reaction direct
Nenaidenko, V. G.,Balenkova, E. S.
p. 1030 - 1036
(2007/10/03)
Perfluoroacylation of alkenes
Reaction of direct electrophilic perfluoroacylation of different structure alkenes with trifluoroacetic anhydride activated by BF3·SMe2 complex leads to trifluoromethylalkenylketones with different structure of alkenyl group. Possibl
Nenajdenko, Valentine G.,Gridnev, Ilya D.,Balenkova, Elizabeth S.
p. 11023 - 11038
(2007/10/02)
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