Welcome to LookChem.com Sign In|Join Free

CAS

  • or
(R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE, with the molecular formula C7H12O2I, is a dioxolane derivative featuring a six-membered heterocyclic ring with two oxygen atoms. (R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE has a chiral center, denoted by the (R) configuration, and includes an iodine atom and an ethyl group in its structure. It is a versatile chemical entity utilized in various applications across different industries.

165657-74-9 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 165657-74-9 Structure
  • Basic information

    1. Product Name: (R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE
    2. Synonyms: (R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE
    3. CAS NO:165657-74-9
    4. Molecular Formula: C7H13IO2
    5. Molecular Weight: 256.08
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 165657-74-9.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE(CAS DataBase Reference)
    10. NIST Chemistry Reference: (R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE(165657-74-9)
    11. EPA Substance Registry System: (R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE(165657-74-9)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 165657-74-9(Hazardous Substances Data)

165657-74-9 Usage

Uses

Used in Organic Synthesis:
(R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE is used as a reagent in organic synthesis for its ability to facilitate the formation of complex organic compounds. Its unique structure with a chiral center and functional groups makes it a valuable component in creating a wide range of molecules.
Used in Pharmaceutical Production:
In the pharmaceutical industry, (R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE is used as an intermediate in the production of various drugs. Its structural properties allow it to be a key building block in the synthesis of medicinal compounds, contributing to the development of new and improved pharmaceuticals.
Used in Agrochemical Production:
Similarly, in the agrochemical sector, (R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE serves as an intermediate for the synthesis of different agrochemicals. Its role in creating complex molecules aids in the development of more effective and targeted products for agricultural applications.
Used in Research and Development:
(R)-4-(2-IODO-ETHYL)-2,2-DIMETHYL-[1,3]DIOXOLANE is also utilized in research and development settings as a building block for the synthesis of more complex organic compounds. Its unique structure and properties make it an attractive candidate for exploring new chemical reactions and creating novel molecules with potential applications in various fields.

Check Digit Verification of cas no

The CAS Registry Mumber 165657-74-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,5,6,5 and 7 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 165657-74:
(8*1)+(7*6)+(6*5)+(5*6)+(4*5)+(3*7)+(2*7)+(1*4)=169
169 % 10 = 9
So 165657-74-9 is a valid CAS Registry Number.

165657-74-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (4R)-4-(2-Iodoethyl)-2,2-dimethyl-1,3-dioxolane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:165657-74-9 SDS

165657-74-9Relevant articles and documents

METHODS FOR SYNTHESIS OF RESOLVINS

-

Paragraph 0084, (2019/04/10)

The present invention provides methods for chemical synthesis of a resolvin compound such as resolvin E1 (RvE1), or a pharmaceutically acceptable salt thereof; and chemically stable formulations of said compound.

METHODS FOR TOTAL SYNTHESIS OF RESOLVIN E1

-

, (2018/09/08)

The present invention provides methods for total chemical synthesis of Resolvin E1 (Rv E1).

Cobalt versus Osmium: Control of Both trans and cis Selectivity in Construction of the EFG Rings of Pectenotoxin 4

Roushanbakhti, Ahria,Liu, Yifan,Winship, Paul C. M.,Tucker, Michael J.,Akhtar, Wasim M.,Walter, Daryl S.,Wrigley, Gail,Donohoe, Timothy J.

supporting information, p. 14883 - 14887 (2017/10/24)

Catalytic oxidative cyclisation reactions have been employed for the synthesis of the E and F rings of the complex natural product target pectenotoxin 4. The choice of metal catalyst (cobalt- or osmium-based) allowed for the formation of THF rings with either trans or cis stereoselectivity. Fragment union using a modified Julia reaction then enabled the synthesis of an advanced synthetic intermediate containing the EF and G rings of the target.

AMINO GROUP-CONTAINING PYRROLIDINONE DERIVATIVE

-

Paragraph 0186, (2014/01/08)

[Problems to be Solved by the Invention] To provide a drug having excellent antibacterial activity against Gram-positive bacteria and Gram-negative bacteria and also being excellent in terms of safety. [Means for Solving the Problems] A compound represented by the following formula (I) or a salt thereof: wherein R represents a hydrogen atom, a hydroxy group, or a halogen atom m represents an integer 0, 1, or 2, n represents an integer 0 or 1 Ar1 represents a bicyclic heterocyclic group represented by the following formula: wherein Aa represents a nitrogen atom or C-Ra, Ab represents a nitrogen atom or C-Rb, and Ac represents a nitrogen atom or C-Rc, Ra, Rb, and Rc independently represent a hydrogen atom or an alkyl group containing 1 to 6 carbon atoms, R1 and R2 independently represent a hydrogen atom, an alkoxy group containing 1 to 6 carbon atoms, a halogenoalkoxy group containing 1 to 6 carbon atoms, a halogen atom, or a cyano group, Ar2 represents a bicyclic heterocyclic group represented by the following formulae:

The first total synthesis of cytopiloyne, an anti-diabetic, polyacetylenic glucoside

Kumar, Chidambaram Ramesh,Tsai, Chi-Hui,Chao, Yu-Sheng,Lee, Jinq-Chyi

experimental part, p. 8696 - 8703 (2011/10/04)

The first total synthesis of cytopiloyne 1, a novel bioactive polyacetylenic glucoside isolated from the extract of Bidens pilosa, is described. The structure of cytopiloyne was determined to be 2-β-D-glucopyranosyloxy-1-hydroxytrideca-5,7,9,11-tetrayne by using various spectroscopic methods, but the chirality of the polyyne moiety was unknown. Herein, the convergent synthesis of two diastereomers of cytopiloyne by starting from commercially available 4-(2-hydroxyethyl)-2,2-dimethyl-1,3-diozolane is described. The synthetic sequence involved two key steps: stereoselective glycosylation of the glucosyl trichloroacetimidate with 1-[(4-methoxybenzyl)oxy] hex-5-yn-2-ol to give the desired β-glycoside and the construction of the glucosyl tetrayne skeleton by using a palladium/silver-catalyzed cross-coupling reaction to form the alkyne-alkyne bond, the first such use of this reaction. Comparison between the observed and published characterization data showed the 2R isomer to be the natural product cytopiloyne.

Stereoselective Additions of Chiral, Functionalized Organozinc Reagents to Achiral and Chiral Aldehydes: a Matched-Mismatched Case in Organozinc Chemistry

Koert, Ulrich,Wagner, Holger,Pidun, Ulrich

, p. 1447 - 1458 (2007/10/02)

The additions of the enantiomerically pure organozinc reagents 17 and 33 to the THF-aldehyde 1 in the presence of the monodentate Lewis acid boron trifluoride-ether give the nonchelation-controlled addition products 7 and 36, respectively (stereoselectivity 95:5, 86:14).These results provide a route to oligo(tetrahydrofuran)s with the relative stereochemistry trans-syn-cis.A stereodirecting effect of the chiral center in the organozinc reagent 17 is found, leading to simple diastereoselectivies in the reaction with achiral aldehydes and to a matched-mismatched case in the reaction with the chiral aldehyde 1. - Key Words: Addition, stereoselective, nonchelation-controlled / Reagent, organozinc / Stereodifferentiation, double / Oligo(tetrahydrofuran)

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 165657-74-9