167421-51-4Relevant articles and documents
Asymmetric total synthesis of (?)-perforanoid A
Lv, Chao,Tu, Qian,Gong, Jianxian,Hao, Xiaojiang,Yang, Zhen
, p. 3612 - 3621 (2017)
Asymmetric total synthesis of (?)-perforanoid A, a novel limonoid isolated from the leaves of Harrisonia perforata, has been achieved. The key features of our total synthesis include the Rh-catalyzed intramolecular Pauson–Khand reaction of an allene and an alkene, the Pd-catalyzed lactonization of an allylic alcohol with a vinyl ether, and the enantioselective alkenylation of 3-furaldehyde.
Cyclohydrocarbonylation of substituted alkynes and tandem cyclohydrocarbonylation-CO insertion of α-keto alkynes catalyzed by immobilized Co-Rh heterobimetallic nanoparticles
Park, Kang Hyun,Kim, So Yeon,Chung, Young Keun
, p. 395 - 398 (2007/10/03)
The use of cobalt-rhodium (Co2Rh2) heterobimetallic nanoparticles in the cyclohydrocarbonylation of substituted alkynes and tandem cyclohydrocarbonylation-CO insertion of α-keto alkynes to give 2(3H)- or 2(5/7)-furanones is described