17095-00-0

Basic information

• Product Name: 1,1'-Biphenyl, 4,4'-bis(4-nitrophenoxy)-
• CAS NO: 17095-00-0
• Molecular Formula: C24H16N2O6
• Molecular Weight: 428.401
• Mol File: 17095-00-0.mol

Chemical Properties

• CAS DataBase Reference: 1,1'-Biphenyl, 4,4'-bis(4-nitrophenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-Biphenyl, 4,4'-bis(4-nitrophenoxy)-(17095-00-0)
• EPA Substance Registry System: 1,1'-Biphenyl, 4,4'-bis(4-nitrophenoxy)-(17095-00-0)

Safety Data

• Hazardous Substances Data: 17095-00-0(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
1,1'-Biphenyl, 4,4'-bis(4-nitrophenoxy)is used as a chemical intermediate for the synthesis of dyes, pigments, and pharmaceuticals. Its unique structure allows for the creation of a wide range of compounds with diverse applications.
Used in Organic Synthesis:
In the field of organic synthesis, 1,1'-Biphenyl, 4,4'-bis(4-nitrophenoxy)serves as a valuable reagent, facilitating various chemical reactions and contributing to the development of new organic compounds.
Used in Laboratory Applications:
As a chemical reagent, 1,1'-Biphenyl, 4,4'-bis(4-nitrophenoxy)is utilized in various laboratory applications, including research and analysis, due to its chemical properties and reactivity.
Used in Flame Retardancy:
1,1'-Biphenyl, 4,4'-bis(4-nitrophenoxy)has been found to have potential as a flame retardant, making it a candidate for use in industries where fire safety is a concern, such as in the production of plastics, textiles, and other materials.
Used in Coating Additives:
In the coatings industry, 1,1'-Biphenyl, 4,4'-bis(4-nitrophenoxy)can be used as an additive to enhance the properties of coatings, improving their performance and durability in various applications.

Upstream product

• 92-88-6 4,4'-Dihydroxybiphenyl 
• 586-78-7 para-nitrophenyl bromide 
• 100-00-5 4-chlorobenzonitrile 

Downstream Products

• 13080-85-8 4,4'-bis(4-aminophenoxy)biphenyl 

Relevant articles and documents

Green synthesis of symmetric aryl ether dinitro compounds in deep eutectic solvents

A series of symmetric aryl ether dinitro compounds were synthesized by 4Urea/ZnCl2 as green solvent and catalyst, and halogenated aromatic hydrocarbon derivatives and dihydroxy compounds as raw materials. This method has the advantages of easy operation, simple recrystallization, environmental friendliness and biodegradability. The structures of the products were subjected to 1H NMR, and the reaction conditions, reaction mechanism and greening advantages of deep eutectic solvents were discussed at the end of the experiments. We learned from the results of the experiments that both the aliphatic dihydroxy compounds and the aromatic dihydroxy compounds could proceed effectively in Ullmann reaction, and the desired products could be obtained in acceptable yields. When using this methodology, symmetric aryl ether dinitro compounds could be synthesized simply at 80oC in 2 h with high yields (66%~94%). Meanwhile, the DES, called deep eutectic solvent which is composed of 4Urea/ZnCl2, could be recycled at least five times without an obvious decraese in the catalytic activity.

Synthesis, Characterization, and Phytotoxic and Antifungal Activities of Biphenyl Derivatives

Three series of biphenyl derivatives are synthesized, characterized and evaluated for Lemna minor phytotoxicity and antifungal activity. The synthetic biphenyl analogues 2c and 6c demonstrate significant activity, while compounds 4b and 6b demonstrate hig

Preparation method of 4,4'-bis(4-aminophenoxy)biphenyl

The invention relates to a preparation method of 4,4'-bis(4-aminophenoxy)biphenyl. The preparation method includes the steps that with biphenol and p-nitrchlorobenzene as raw materials, a salt forming agent and a strong-polarity aprotic solvent are added and mixed under nitrogen protection, a reflux reaction is performed for 3-5 h at 130-140 DEG C, filtration is performed at the high temperature, filtration residues are removed, deionized water is dropwise added into filtrate, and cooling, filtration, washing and drying are performed to obtain 4,4'-bis(4-nitrophenoxy)biphenyl; with 4,4'-bis(4-nitrophenoxy)biphenyl as a raw material, organic amine, Ni and an ester organic solvent are added under nitrogen protection, a heat preservation reaction is performed for 5-8 h at the pressure of 10-20 atm and the temperature of 40-70 DEG C, filtration is performed, the solvent is removed, and then 4,4'-bis(4-aminophenoxy)biphenyl is obtained. A catalyst selected for the preparation method has high selectivity, subsequent purification is not needed, the product quality and yield are high, the operation process is simple and safe, the cost is low, and industrial production is facilitated.

Synthesis of Monosubstituted Polynuclear Phenols Containing a Nitrophenoxy Fragment

A numbers of monosubstituted polynuclear phenols have been synthesized by reaction of p-chloronitrobenzene or m-dinitrobenzene with various bisphenols.