Synthesis and electro-catalytic properties of a dinuclear palladium(I) 1,3-bis[(2-chloro)benzene]triazenide complex
The reaction of 1,3-bis[(2-chloro)benzene]triazene (HL) and [Pd(CH 3CN)4]Cl2 gave a new dinuclear triazenido complex [Pd2L2] 1 (L = 1,3-bis[(2-chloro)benzene]triazene ion). Electrochemcial studies sho
Synthesis and structures of dinuclear copper(I) and silver(I) 1, 3-bis[(2-chloro)benzene]triazenide complexes
In the presence of Et3N, the reaction of 1, 3-bis[(2-chloro) benzene]triazene (HL) with CuCl or AgNO3 gives the triazenide complexes {Cu2(L)2} (1) and {Ag2(L) 2} (2), respectively. The X-ray crystal structures of both complexes were obtained. The metal-metal distances (Cu...Cu and Ag...Ag) are 2.4974(5) and 2.7208(5) A, respectively. Copyright
Synthesis and properties of amphiphilic photoresponsive gelators for aromatic solvents
A sugar-based photoresponsive supergelator, N-glycosylazobenzene that shows selective gelation of aromatic solvents is described. The partial trans - cis isomerization of the azobenzene moiety allows photoinduced chopping of the entangled gel fibers to short fibers, resulting in controlled fiber length and gel - sol transition. The gelator is useful for the selective removal of toxic aromatic solvents from water.
Facile route for N1-aryl benzotriazoles from diazoamino arynes via CuI-mediated intramolecular N-arylation
A facile and high-yielding protocol for diverse benzotriazoles through intramolecular N-arylation of different o-chloro-1,2,3-benzotriazenes using CuI/Cs2CO3 has been developed.
Kale, Raju R.,Prasad, Virendra,Hussain,Tiwari, Vinod K.
experimental part
p. 5740 - 5743
(2010/11/16)
1,3-Diaryltriazenes: A new class of anorectic agents
A series of substituted 1,3-diaryltriazenes has been synthesized and tested for anorectic activity. Several members of the series were effective; one compound, 1,3-bis[2-cyano-5-(trifluoromethyl)phenyl]triazene, was particularly active, causing weight los