177263-29-5Relevant articles and documents
Novel amine-catalysed hydroalkoxylation reactions of activated alkenes and alkynes
Murtagh, Julie E.,McCooey, Seamus H.,Connon, Stephen J.
, p. 227 - 229 (2007/10/03)
Substoichiometric loadings of DBU catalyse the efficient 1,4-addition of alcohols and non-nucleophilic amines such as pyrrole to activated alkenes; the application of this methodology in a one-pot synthesis of a natural product, and as a novel strategy for the synthesis of mono-protected 1,3-carbonyl compounds is reported.
A new synthesis of monosubstituted succinaldehydes and 3-substituted pyrroles from acetonitriles. Formal synthesis of 2,3-dihydro-7-methyl-2H-pyrrolizidin-1-one (Danaidone), a semiochemical of Danaid butterflies
Mendez, Jose Manuel,Flores, Blas,Leon, Fernando,Martinez, Maria Eugenia,Vazquez, Alfredo,Garcia, Gustavo Alberto,Salmon, Manuel
, p. 4099 - 4102 (2007/10/03)
A convenient and versatile synthesis of monosubstituted succinaldehydes and 3-substituted pyrroles from acetonitriles was devised. The methodology was applied to the preparation of 9, the penultimate intermediate in the Meinwald and Meinwald synthesis of Danaidone.12 Copyright
