17865-32-6Relevant articles and documents
METHOD FOR PRODUCING ORGANOSILICON COMPOUND HAVING CYCLIC ALKYL GROUP
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Paragraph 0022; 0025; 0028; 0031; 0034; 0035; 0036, (2019/01/06)
PROBLEM TO BE SOLVED: To provide a method for producing an organosilicon compound that can efficiently produce an organosilicon compound, particularly an organic silicon compound having a cyclic alkyl group. SOLUTION: A method according to the present inv
METHOD OF PRODUCING A HYDROLYZABLE SILICON-CONTAINING COMPOUND
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Page/Page column 17-18; 20, (2012/07/14)
The present invention provides a safe, inexpensive, and high yield means of producing a hydrolyzable silicon-containing compound, e.g., an organooxysilane and the like. A compound (A) represented by the general formula R1-O-R2 wherein R1 represents a C4-30, substituted or unsubstituted, tertiary alkyl group or aralkyl group and R2 represents a C1-30, substituted or unsubstituted, monovalent hydrocarbyl group or acyl group, is reacted in the presence of a Lewis acid catalyst with a halosilane (B) represented by the general formula R3mSiX4-m wherein R3 represents the hydrogen atom or a C1-30 substituted or unsubstituted monovalent hydrocarbyl group, X is independently bromine or chlorine, and m represents an integer from 0 to 3.
Practical conversion of chlorosilanes into alkoxysilanes without generating HCl
Wakabayashi, Ryutaro,Sugiura, Yasushi,Shibue, Toshimichi,Kuroda, Kazuyuki
supporting information; experimental part, p. 10708 - 10711 (2011/12/05)
Alcohol-free: A versatile, efficient, and practical synthesis of alkoxysilanes without generation of HCl involves the reaction of chlorosilanes with unsymmetrical ethers in the presence of a Lewis acid (see scheme). The reaction proceeds through selective cleavage of C-O bonds and is superior to conventional processes. Industrially feasible reagents are used and only one by-product results. Copyright