Welcome to LookChem.com Sign In|Join Free
  • or

110-83-8

Post Buying Request

110-83-8 Suppliers

Recommended suppliersmore

Product FOB Price Min.Order Supply Ability Supplier
Cyclohexene suppliers in China
Cas No: 110-83-8
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Cyclohexene supplier in China
Cas No: 110-83-8
No Data 1 Metric Ton 30 Metric Ton/Month Simagchem Corporation Contact Supplier
Cyclohexene CAS 110-83-8
Cas No: 110-83-8
USD $ 1.0-1.0 / Metric Ton 1 Metric Ton 3000 Metric Ton/Year Hefei TNJ chemical industry co.,ltd Contact Supplier
Amadis Chemical offer CAS#110-83-8;CAT#A802251
Cas No: 110-83-8
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Cyclohexene
Cas No: 110-83-8
No Data No Data Metric Ton/Day ORCHID CHEMICAL SUPPLIES LTD Contact Supplier
Cyclohexene
Cas No: 110-83-8
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Cyclohexene CAS: 110-83-8
Cas No: 110-83-8
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
Cyclohexene 110-83-8
Cas No: 110-83-8
USD $ 1.0-1.0 / Gram 1 Gram 100 Gram/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
Cyclohexene / Hexanaphthylene CAS 110-83-8
Cas No: 110-83-8
USD $ 70.0-100.0 / Kilogram 1 Kilogram 100 Metric Ton/Month HUBEI AOKS BIO-TECH CO.,LTD Contact Supplier
Nice Quality Cyclohexene CAS 110-83-8
Cas No: 110-83-8
USD $ 1.0-3.0 / Gram 10 Gram 1000 Kilogram/Month Wuhan Monad Medicine Tech Co.,LTD Contact Supplier

110-83-8 Usage

Cycloolefin

Cyclohexene is a cyclic olefin, and is a colorless, flammable liquid with a special pungent odor at room temperature. Long-term placement in the air it can be oxidated into peroxide by air. Naturally present in coal tar, soluble in acetone, carbon tetrachloride, benzene, ether, hexane, ethanol and other organic solvents, can form binary azeotrope with lower alcohols, acetic acid, etc. Cyclohexene has the general nature of olefin, decomposes rapidly in the presence of uranium salts under sunlight or ultraviolet rays, is constant as being heated in a sealed tube at 200 ℃ for a long time, forms benzene and naphthalene at 400~500 ℃.
It is obtained by dehydration of cyclohexanol at high temperature in the presence of an acid catalyst in industrial. It is obtained by sulfated dehydration of cyclohexanol in the laboratory.

Figure 1 is the chemical reaction equation of sulfated dehydration of cyclohexanol to obtain cyclohexene.
Cyclohexene is an important chemical raw materials, used for the production of adipic acid, adipic aldehyde, maleic acid, Cyclohexane acid, cyclohexane aldehyde, maleic acid, cyclohexyl carboxylic acid, cyclohexanecarboaldehyde in industry. It is also used as the extraction agent, the stabilizer having a high-octane gasoline. Inhalation can cause mild poisoning.
Here are some of these important compounds prepared by cyclohexene, (1)chlorinated cyclohexane is made, useful as pharmaceutical intermediates, a solvent and rubber additives. (2) cyclohexanone is made from cyclohexene, can be used as intermediates raw materials of medicine, pesticides, perfumes, and dyes, as polymer modifiers. (3) cyclohexyl acetate is made, used as a plastic solvent. (4) cyclohexanone phenol is made, can be used as raw materials medicine and pesticides. (5) aminocyclohexanol is made, can be used as surfactants and emulsifiers. (6) The product can also be used directly as organic intermediates, solvents and additives when spices are prepared. It can be used in the preparation of butadiene in the laboratory.
The above information were edited and collated by Yan Yanyong of Chemicalbook.

Explosive hazardous characteristics

It can be explosive mixed with air.

Chemical properties

Colorless flammable liquid. Insoluble in water, soluble in ether.

Category

Flammable liquids.

Extinguishing agent

Dry powder, dry sand, carbon dioxide, foam, 1211 fire extinguishing agent.

Usage

1. Used in organic synthesis, it is also used as a solvent.
2. It is used as organic synthetic raw materials, such as synthetic raw materials for lysine, cyclohexanone, phenol, polycycloolefin resin, chlorinated cyclohexane, rubber additives, cyclohexanol, etc. It is also used as a catalyst solvent and petroleum extraction agent, high octane gasoline stabilizer.
3. It is used for Preparation of adipic acid, maleic acid, hexahydro benzoic acid and acetaldehyde, preparation of butadiene in the laboratory. It is used as high-octane gasoline stabilizer.

General Description

A colorless liquid. Insoluble in water and less dense than water. Flash point 20°F. Vapors heavier than air. Inhalation of high concentrations may have a narcotic effect. Used to make other chemicals.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Flammability hazard characteristics

In case of fire, high temperature, oxidant, it is flammable, burning produces irritant smoke.

Production method

Cyclohexanol is heated to generate cyclohexene in the presence of sulfuric acid catalyst, distilled to obtain crude products. Washed with a fine saturated salt solution, then sodium sulfate solution is used to neutralize traces of acid, then washed with water, layered, dried, filtration, distillation, collecting 82-85 ℃ distillate products to obtain cyclohexene.

Reactivity Profile

Cyclohexene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154].

Definition

ChEBI: A cycloalkene that is cylohexane with a single double bond.

Purification Methods

Free cyclohexene from peroxides by washing with successive portions of dilute acidified ferrous sulfate, or with NaHSO3 solution, then with distilled water, drying with CaCl2 or CaSO4, and distilling under N2. Alternative methods for removing peroxides include passage through a column of alumina, refluxing with sodium wire or cupric stearate (then distilling from sodium). The diene is removed by refluxing with maleic anhydride before distilling under vacuum. Treatment with 0.1moles of MeMgI in 40mL of diethyl ether removes traces of oxygenated impurities. Other purification procedures include washing with aqueous NaOH, drying and distilling under N2 through a spinning band column, redistilling from CaH2, storing under sodium wire, and passing through a column of alumina, under N2, immediately before use. Store it at <0o under argon. [Coleman & Johnstone Org Synth Coll Vol I 83 1955, Carson & Ipatieff Org Synth Coll Vol II 152 1943, Woon et al. J Am Chem Soc 108 7990 1986, Wong et al. J Am Chem Soc 109 3428 1987.] [Beilstein 5 IV 218.]

Toxicity grading

Toxic

Storage Characteristics

Treasury ventilation low-temperature drying, stored separately from oxidants and acids. Not long storage to prevent polymerization.

Occupational standards

TWA 1015 mg/cubic meter.

Air & Water Reactions

Highly flammable. Insoluble in water.

Chemical Properties

colourless liquid

Acute toxicity

Inhalation-Rats TCL0: 600 PPM/6 hrs/26 weeks.

Uses

Alkylation component. In the manufacture of adipic acid, maleic acid, hexahydrobenzoic acid and aldehyde. To prepare butadiene in the laboratory. Has been suggested for the synthesis of maleic acid and as stabilizer for high octane gasoline.
InChI:InChI=1/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2

110-83-8 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (44028)  Cyclohexene  analytical standard 110-83-8 44028-10ML-F 668.07CNY Detail
Sigma-Aldrich (44028)  Cyclohexene  analytical standard 110-83-8 44028-5ML-F 398.97CNY Detail
Alfa Aesar (A11359)  Cyclohexene, 99%    110-83-8 2500ml 1163.0CNY Detail
Alfa Aesar (A11359)  Cyclohexene, 99%    110-83-8 500ml 247.0CNY Detail
Alfa Aesar (A11359)  Cyclohexene, 99%    110-83-8 100ml 122.0CNY Detail

110-83-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name cyclohexene

1.2 Other means of identification

Product number -
Other names Cykloheksen

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110-83-8 SDS

110-83-8Synthetic route

cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With samarium diiodide; N,N,N',N'',N''-pentamethylethylene triamine; water In tetrahydrofuran at 20℃; for 0.0833333h;100%
With hydrogen In dichloromethane at 40℃; under 3000.3 Torr; for 0.75h;95%
With 1‑cyanopropyl-3-methylimidazolium tetrafluoroborate; hydrogen; palladium dichloride at 100℃; under 34202.3 Torr; for 4h; Reactivity (does not react);90%
cyclohexene sulfide
286-28-2

cyclohexene sulfide

cis-2-methyl-3-phenyloxaziridine
39245-63-1

cis-2-methyl-3-phenyloxaziridine

A

(Z)-azomethane
4143-42-4

(Z)-azomethane

B

N,N'-bis(methyl)sulphur di-imide
13849-02-0, 84878-02-4, 84878-03-5, 84878-04-6

N,N'-bis(methyl)sulphur di-imide

C

benzaldehyde
100-52-7

benzaldehyde

D

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
In chloroform Mechanism; Ambient temperature; via thionitrosomethane, CH3NS (also used: other oxaziridines and episulfides);A n/a
B 83%
C 100%
D 100%
cyclohexene sulfide
286-28-2

cyclohexene sulfide

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With hydrogen sulfide; triphenylphosphine; methyltrioxorhenium(VII) In [D3]acetonitrile for 0.0833333h; Ambient temperature;100%
With sodium In toluene at 110℃; for 7h;99%
With biphenyl; lithium In 1,2-dimethoxyethane for 8h; Heating;73%
trans-1,2-dibromocyclohexane
7429-37-0

trans-1,2-dibromocyclohexane

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; ethylmagnesium bromide In tetrahydrofuran at 0℃;100%
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; tri-n-butyl-tin hydride In tetrahydrofuran for 0.25h; Ambient temperature;100%
With sodium sulfide; cetyltributylphosphonium bromide In toluene at 25℃; for 12h;90%
1,2-cyclohexanediol cyclic sulphate
4705-17-3

1,2-cyclohexanediol cyclic sulphate

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; Product distribution; electrolysis, oth. solvent, var. cathodes;100%
cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With sodium amalgam; chiral Co(II) In tetrahydrofuran-d8 at 20℃; for 6h; deoxygenation;100%
With lithium In tetrahydrofuran for 24h; Heating;96%
With chloro-trimethyl-silane; sodium iodide In acetonitrile for 0.5h; Ambient temperature;94%
(1R,2R)-1-Chloro-2-iodo-cyclohexane
33427-17-7

(1R,2R)-1-Chloro-2-iodo-cyclohexane

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; lithium triethylborohydride In tetrahydrofuran for 0.5h; Ambient temperature;100%
5-cyclohexyloxythianthreniumyl perchlorate

5-cyclohexyloxythianthreniumyl perchlorate

A

thianthrene-5-oxide
2362-50-7

thianthrene-5-oxide

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With thiophenol In acetonitrile at 1℃; for 100h; Product distribution; Elimination;A 105 %
B 100%
1,7-Octadiene
3710-30-3

1,7-Octadiene

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With diazomethyl-trimethyl-silane; ruthenium Schiff-base In toluene at 70℃; for 1h; ring-closing metathesis;100%
With diazomethyl-trimethyl-silane; ruthenium In toluene at 85℃; for 17h; Product distribution; Further Variations:; Catalysts;100%
[2-((2,6-iPr2-Ph-imino)methyl)phenol][p-cymene][=CHPh]Ru2Cl3 In various solvent(s) at 70℃; for 4h; Product distribution; Further Variations:; Catalysts; Temperatures;100%
{Ir(C5Me5)(cyclohexadiene)}

{Ir(C5Me5)(cyclohexadiene)}

A

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With HCl In pentane (N2); HCl gas bubbled through complex soln.;A 93%
B 100%
cyclohexanol
108-93-0

cyclohexanol

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With sulfuric acid at 250℃; for 0.5h;99%
for 2h; Temperature; Heating;98%
With Nafion/SiO2 at 200℃; under 15001.5 Torr; for 6h;90.3%
{(η5-C5H5)Re(NO)(PPh3)(IC6H11)}(1+)BF4(1-)

{(η5-C5H5)Re(NO)(PPh3)(IC6H11)}(1+)BF4(1-)

bis(triphenylphosphoranylidene)ammonium bromide
20545-30-6

bis(triphenylphosphoranylidene)ammonium bromide

A

(η5-C5H5)Re(NO)(PPh3)(I)

(η5-C5H5)Re(NO)(PPh3)(I)

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
In dichloromethane-d2 N2, in an NMR-tube, frozen in liquid N2, CD2Cl2 and PPNBr added, kept at-40°C for 12 h; not isolated, NMR;A 99%
B 57%
1-hexene
592-41-6

1-hexene

cyclohexa-1,4-diene
1165952-92-0

cyclohexa-1,4-diene

A

hexane
110-54-3

hexane

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With C24H72Ba2N4Si8 In (2)H8-toluene at 120℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube;A 99%
B n/a
cyclohexa-1,4-diene
1165952-92-0

cyclohexa-1,4-diene

1-Phenylcyclohexene
771-98-2

1-Phenylcyclohexene

A

1-phenyl-1-cyclohexane
827-52-1

1-phenyl-1-cyclohexane

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With C24H72Ba2N4Si8 In (2)H8-toluene at 120℃; for 3h; Inert atmosphere; Schlenk technique; Sealed tube;A 99%
B n/a
norborn-2-ene
498-66-8

norborn-2-ene

cyclohexa-1,4-diene
1165952-92-0

cyclohexa-1,4-diene

A

norbornene
279-23-2

norbornene

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With C24H72Ba2N4Si8 In (2)H8-toluene at 120℃; for 5h; Inert atmosphere; Schlenk technique; Sealed tube;A 99%
B n/a
aniline
62-53-3

aniline

A

cyclohexane
110-82-7

cyclohexane

B

cyclohexylamine
108-91-8

cyclohexylamine

C

N-cyclohexyl-cyclohexanamine
101-83-7

N-cyclohexyl-cyclohexanamine

D

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With ammonia; hydrogen at 180 - 200℃;A n/a
B 98.4%
C 0.08%
D n/a
With hydrogen at 160 - 200℃; under 150015 Torr;A n/a
B 95.9%
C 0.45%
D n/a
1-bromocyclohexane
108-85-0

1-bromocyclohexane

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With sodium hydroxide; 2,2,2-trifluoroethanol; tetrabutylammomium bromide In 1,2-dichloro-benzene at 73 - 75℃; for 0.5h; phase transfer conditions;98%
With sodium hydroxide; 2,2,2-trifluoroethanol; tetrabutylammomium bromide In 1,2-dichloro-benzene at 73 - 75℃; for 0.5h; phase transfer conditions;98%
With Amberlyst A 26; carbonate form In benzene for 5h; Heating;88%
cis-2-(trimethylsilyl)cyclohexyl trifluoroacetate
80866-33-7

cis-2-(trimethylsilyl)cyclohexyl trifluoroacetate

A

cyclohexene
110-83-8

cyclohexene

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
In ethanol at 65℃; Kinetics; ΔH, ΔG, ΔS (excit.);A 98%
B n/a
In water at 60℃; Kinetics;A 9.2%
B n/a
Ru(C6(CH3)6)(C6H8)
67421-01-6

Ru(C6(CH3)6)(C6H8)

A

[RuCl2(hexamethylbenzene)]2

[RuCl2(hexamethylbenzene)]2

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With HCl In pentane (N2); HCl gas bubbled through complex soln.;A 90%
B 98%
cyclohexanone
108-94-1

cyclohexanone

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With hydrogen at 199.84℃; for 6h; Catalytic behavior;95.8%
With phenylsilane; C28H16F24O8S2Si In 1,2-dichloro-benzene at 100℃; for 72h; Inert atmosphere;61%
With fired clay fragments at 250 - 300℃;
Multi-step reaction with 3 steps
1: diethyl ether; sodium; alcohol / Reagens 4: Kaliumcarbonat
2: fuming hydrochloric acid / 100 °C
3: quinoline
View Scheme
Multi-step reaction with 2 steps
1: PCl5
2: sodium; methanol
View Scheme
cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

A

cyclohexane
110-82-7

cyclohexane

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.333333h; Product distribution; Ambient temperature; various time;A 0.05%
B 95.6%
With ammonium acetate In methanol Electrochemical reaction;A 88%
B 12%
With hydrogen; (η3-C3H5)Co[P(OMe)3]3 for 24h; Ambient temperature;A 7.6%
B 48.3%
benzene
71-43-2

benzene

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With hydrogen; ytterbium at 393℃; under 22501.8 Torr; for 3h;95%
With hydrogenchloride; <η6-C6Me6Ru η4-C6H8>92%
With hydrogen; 2,2'-iminobis[ethanol]; zinc(II) sulfate; zirconium(IV) oxide In water at 150℃; under 37503.8 Torr; Autoclave;63.6%
{(η5-C5H5)Re(NO)(PPh3)(IC6H11)}(1+)BF4(1-)

{(η5-C5H5)Re(NO)(PPh3)(IC6H11)}(1+)BF4(1-)

A

(η5-C5H5)Re(NO)(PPh3)(I)

(η5-C5H5)Re(NO)(PPh3)(I)

B

P(C6H5)3C6H11(1+)*BF4(1-) = P(C6H5)3C6H11BF4
138968-07-7

P(C6H5)3C6H11(1+)*BF4(1-) = P(C6H5)3C6H11BF4

C

fluorocyclohexane
372-46-3

fluorocyclohexane

D

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane-d2 N2, frozen in liquid N2, CD2CL2 and solid PPh3 added, slowly warmed to 0°C; not isolated, NMR, GLC;A 95%
B 24%
C 24%
D 30%
ethanol
64-17-5

ethanol

sodium thiophenolate
930-69-8

sodium thiophenolate

1,2-bis(5-thianthreniumyl)cyclohexane diperchlorate
68843-17-4

1,2-bis(5-thianthreniumyl)cyclohexane diperchlorate

A

2-ethoxycyclohex-1-ene
51122-94-2

2-ethoxycyclohex-1-ene

B

diphenyldisulfane
882-33-7

diphenyldisulfane

C

Thianthrene
92-85-3

Thianthrene

D

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
In ethanol for 360h; Ambient temperature;A 2%
B 81%
C 94%
D 59%
sodium thiophenolate
930-69-8

sodium thiophenolate

1,2-bis(5-thianthreniumyl)cyclohexane diperchlorate
68843-17-4

1,2-bis(5-thianthreniumyl)cyclohexane diperchlorate

A

diphenyldisulfane
882-33-7

diphenyldisulfane

B

Thianthrene
92-85-3

Thianthrene

C

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
In dimethyl sulfoxide for 20h; Ambient temperature;A 84%
B 94%
C 61%
cyclohexyl tosylate
953-91-3

cyclohexyl tosylate

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 14h;94%
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride at 0 - 20℃; Inert atmosphere;94%
With potassium fluoride In N,N,N,N,N,N-hexamethylphosphoric triamide at 65℃; for 5h;90%
boron trifluoride dihydrate

boron trifluoride dihydrate

{Ir(C5Me5)(cyclohexadiene)}

{Ir(C5Me5)(cyclohexadiene)}

A

(η6-benzene)(η5-pentamethylcyclopentadienyl)iridium(III) bis(tetrafluoroborate)

(η6-benzene)(η5-pentamethylcyclopentadienyl)iridium(III) bis(tetrafluoroborate)

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
In benzene (N2); Ir complex soln. treated with BF3*2H2O, stirred for 12 h at 20°C; C6H6 and ether added to H2O layer;A 94%
B 63%
7,7-dimorpholino-cis-bicyclo<4.1.0>heptane
71699-79-1, 79985-08-3

7,7-dimorpholino-cis-bicyclo<4.1.0>heptane

A

5-morpholino-2,3,6,7-tetrahydro-1,4-oxazepine
113628-18-5

5-morpholino-2,3,6,7-tetrahydro-1,4-oxazepine

B

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
at 700℃; under 1E-05 Torr;A 70%
B 93%
acetic acid
64-19-7

acetic acid

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
With palladium diacetate; N,N'-bis(salicylidene)-1,2-phenylene diaminocobalt(II); lithium acetate; oxygen; hydroquinone at 60℃; under 760 Torr; Product distribution; var. metal macrocyclic complexes, var. metal complexes concentration;100%
With palladium diacetate; N,N'-bis(salicylidene)-1,2-phenylene diaminocobalt(II); lithium acetate; oxygen; hydroquinone at 60℃; under 760 Torr; for 20.2h;100%
With manganese(IV) oxide; palladium diacetate; p-benzoquinone at 60℃; for 17h;97%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

cyclohexene
110-83-8

cyclohexene

1-(tert-butylperoxy)-2-cyclohexene
51437-25-3

1-(tert-butylperoxy)-2-cyclohexene

Conditions
ConditionsYield
In decane; toluene at 30℃;100%
With [Cu(4-methyl-1,3-bis(2-pyridylimino)isoindole)(OAc)] In water86%
With pyrazolate-based cobalt(II)-containing MFU-1 metal-organic framework at 70℃; for 2h;11.9%
chloroform
67-66-3

chloroform

cyclohexene
110-83-8

cyclohexene

7,7-dichloro-bicyclo[4.1.0]heptane
823-69-8

7,7-dichloro-bicyclo[4.1.0]heptane

Conditions
ConditionsYield
With sodium hydroxide; Sucrose-ethyleneoxide adducts In chloroform at 20℃; for 2h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis;;100%
With sodium hydroxide; Sucrose-ethyleneoxide adducts In chloroform at 20℃; for 2h; Product distribution; further catalysts: PEG, DB18K6;100%
With potassium hydroxide; 18-crown-6 ether In dichloromethane at 40℃; for 6h;98%
cyclohexene
110-83-8

cyclohexene

diethylazodicarboxylate
1972-28-7

diethylazodicarboxylate

Diethyl 1-(2-cyclohexen-1-yl)-1,2-hydrazinedicarboxylate
17833-25-9

Diethyl 1-(2-cyclohexen-1-yl)-1,2-hydrazinedicarboxylate

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane at -78℃;100%
With tin(IV) chloride In dichloromethane at -60℃; for 0.0833333h;77%
cyclohexene
110-83-8

cyclohexene

cyclohexenone
930-68-7

cyclohexenone

Conditions
ConditionsYield
trans-2 In acetonitrile for 4h; Ambient temperature;100%
With tert.-butylhydroperoxide; C29H26CuN6O2 In acetonitrile for 4h; Inert atmosphere; Reflux;100%
With tert.-butylhydroperoxide; oxygen In acetonitrile at 85℃; for 12h; Catalytic behavior; Reagent/catalyst; Solvent; Time;99%
cyclohexene
110-83-8

cyclohexene

cis-1,2-cyclohexane
1792-81-0

cis-1,2-cyclohexane

Conditions
ConditionsYield
With water; 4-methylmorpholine N-oxide; osmium; Cu-Al-hydrotalcite In toluene at 60℃; for 4.5h;100%
With N-methyl-2-indolinone; fluorous OsO4 In water; acetone; tert-butyl alcohol at 20℃; for 36h;100%
With 4-methylmorpholine N-oxide; In water; acetone Ambient temperature;95%
cyclohexene
110-83-8

cyclohexene

hexanedial
1072-21-5

hexanedial

Conditions
ConditionsYield
With sodium periodate; C31H29Br2N3Ru*CH2Cl2 In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; Inert atmosphere; Schlenk technique;100%
With 1H-imidazole; sodium periodate; MnCl-TPP-(PEO750)4 In water; acetonitrile at 20℃; for 24h;97%
With 1-(3-sulfopropyl)-3-methylimidazolium periodate In water at 35℃; for 36h; Reagent/catalyst; Temperature;93%
cyclohexene
110-83-8

cyclohexene

bicyclohexyl-2,2'-diene
1541-20-4

bicyclohexyl-2,2'-diene

Conditions
ConditionsYield
With methyl cyanoformate; sodium decatungstate In acetonitrile at 8℃; for 90h; Irradiation;100%
at 10℃; for 25h; Product distribution; Irradiation;
With phosphorus pentoxide; benzene
cyclohexene
110-83-8

cyclohexene

cyclohexane
110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen; mer-Os(PPh3)3HBr(CO) at 150℃; under 3800 Torr; for 1h; Product distribution;100%
With hydrogen; decacarbonyldirhenium(0) at 230℃; under 37503 Torr; for 0.25h;100%
With {(η6-C6H6)Ru(NCCH3)3}{BF4}2; water; hydrogen In benzene at 90℃; under 30400 Torr; for 4h;100%
cyclohexene
110-83-8

cyclohexene

trans-Di(2-chlorocyclohexyl) sulfide
16660-57-4

trans-Di(2-chlorocyclohexyl) sulfide

Conditions
ConditionsYield
With sulfur dichloride In dichloromethane at 0℃; for 2h;100%
With thiobismorpholine; trichlorophosphate In dichloromethane at -40 - 20℃;61%
With tetrachloromethane; sulfur dichloride at 70 - 80℃;
With sulfur tetrachloride
With sulfur dichloride
Conditions
ConditionsYield
With N-Bromosuccinimide In water at 0 - 25℃;100%
With N-Bromosuccinimide; water In 1,2-dimethoxyethane 1.) 0 deg C, 30 min, 2.) 20 deg C, 60 min;99%
With tribromo-isocyanuric acid In acetone at 20℃; for 0.0833333h;91%
cyclohexene
110-83-8

cyclohexene

trans-1,2-dibromocyclohexane
7429-37-0

trans-1,2-dibromocyclohexane

Conditions
ConditionsYield
With bromine; thallium(I) acetate In tetrachloromethane for 0.583333h; Ambient temperature;100%
With bromine In Hexadecane for 0.5h; Cooling;100%
With tetra-N-butylammonium tribromide In chloroform Ambient temperature; ultrasonic irradiation;99%
cyclohexene
110-83-8

cyclohexene

cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

Conditions
ConditionsYield
With dihydrogen peroxide; trioctylmethylammonium hydrogen tungstate; phenylphosphonate In 1,4-dioxane at 70℃; for 0.8h;100%
With tert.-butylhydroperoxide; molybdenum(VI) oxide at 80℃; for 1h;100%
With tert.-butylhydroperoxide; C15H12ClMoN3O7 In methanol; dichloromethane for 1h; Reagent/catalyst;100%
cyclohexene
110-83-8

cyclohexene

rac-3-bromocyclohexene
1521-51-3

rac-3-bromocyclohexene

Conditions
ConditionsYield
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 80℃; for 1.5h; Wohl-Ziegler allylic bromination;100%
With N-Bromosuccinimide; 1,3-di-n-butyl-imidazolium tetrafluoroborate at 28 - 35℃; for 0.0833333h;85%
With N-Bromosuccinimide Wohl-Ziegler Bromination; Reflux;84%
propionaldehyde
123-38-6

propionaldehyde

cyclohexene
110-83-8

cyclohexene

cyclohexyl ethyl ketone
1123-86-0

cyclohexyl ethyl ketone

Conditions
ConditionsYield
With dibenzoyl peroxide at 90℃; for 10h;100%
at 27℃; for 22h; (γ-irradiation);
Irradiation;
methanol
67-56-1

methanol

cyclohexene
110-83-8

cyclohexene

bromo-1 methoxy-2 cyclohexane
24618-31-3

bromo-1 methoxy-2 cyclohexane

Conditions
ConditionsYield
With N-Bromosuccinimide100%
With sodium bromide at 60℃; electrolysis in undivided cell, Pt-anode, Cu-Zn-cathode;80%
With tert-butyl hypobromite
With tBuBrO
(diethoxyphosphinothioyl)sulfenyl chloride
1639-18-5

(diethoxyphosphinothioyl)sulfenyl chloride

cyclohexene
110-83-8

cyclohexene

1-chloro-2-(S-diethoxythiophosphoro)cyclohexane
1467-17-0

1-chloro-2-(S-diethoxythiophosphoro)cyclohexane

Conditions
ConditionsYield
100%
cyclohexene
110-83-8

cyclohexene

(1R,2R)-1-Chloro-2-iodo-cyclohexane
33427-17-7

(1R,2R)-1-Chloro-2-iodo-cyclohexane

Conditions
ConditionsYield
With K(1+)*Cl2I(1-) In tetrachloromethane for 0.333333h;100%
With hydrogenchloride; potassium iodate; iodine In water at 5℃; for 0.5h; iodochlorination;98%
With iodine; copper dichloride In pentane for 4h; Ambient temperature;95%
5-Phenyl-1H-tetrazole
18039-42-4

5-Phenyl-1H-tetrazole

cyclohexene
110-83-8

cyclohexene

2-cyclohexyl-5-phenyl-2H-tetrazole
140406-56-0

2-cyclohexyl-5-phenyl-2H-tetrazole

Conditions
ConditionsYield
With sulfuric acid100%
4-Phenyl-1,2,4-triazolidine-3,5-dione
4233-33-4

4-Phenyl-1,2,4-triazolidine-3,5-dione

cyclohexene
110-83-8

cyclohexene

1-(cyclohex-2-enyl)-4-phenyl-1,2,4-triazolidine-3,5-dione
15971-69-4

1-(cyclohex-2-enyl)-4-phenyl-1,2,4-triazolidine-3,5-dione

Conditions
ConditionsYield
In dichloromethane100%
In dichloromethane Ambient temperature;89%
In benzene at 25℃; Rate constant; other solvent;
In benzene at 25℃; Rate constant; other solvent: CH2Cl2;
In toluene at 25℃; under 1490400 Torr; Kinetics; Temperature; Pressure; Concentration;
ethylene glycol
107-21-1

ethylene glycol

cyclohexene
110-83-8

cyclohexene

1-iodo-(2-hydroxyethoxy)cyclohexane
134986-42-8

1-iodo-(2-hydroxyethoxy)cyclohexane

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate; iodine In acetonitrile for 5h; Heating;100%
propargyl alcohol
107-19-7

propargyl alcohol

cyclohexene
110-83-8

cyclohexene

1-Bromo-2-prop-2-ynyloxy-cyclohexane
71960-57-1

1-Bromo-2-prop-2-ynyloxy-cyclohexane

Conditions
ConditionsYield
With N-Bromosuccinimide at 0℃; for 1h;100%
With N-Bromosuccinimide In dichloromethane 1.) -20 deg C, 2 h, 2.) 15 deg C;83%
With N-Bromosuccinimide In dichloromethane at -20 - 23℃; for 17.5h; Inert atmosphere;63%
acetic acid
64-19-7

acetic acid

cyclohexene
110-83-8

cyclohexene

cis-1-acetoxycyclohexane-2-ol
86703-56-2

cis-1-acetoxycyclohexane-2-ol

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate; iodine for 5h; Heating;100%
With ammonium cerium(IV) nitrate; iodine for 10h; Mechanism; Heating; other substrate;80%
With ammonium cerium(IV) nitrate; iodine for 10h; Heating;80%
naphtho<1,2-c><1,2>dithiole-3-thione
62216-53-9

naphtho<1,2-c><1,2>dithiole-3-thione

cyclohexene
110-83-8

cyclohexene

thioquinone methide
62216-54-0

thioquinone methide

Conditions
ConditionsYield
In benzene for 1.5h; Irradiation;100%

110-83-8Related news

Synthesis of the Cyclohexene (cas 110-83-8) segment of portimine08/28/2019

The synthesis of the cyclohexene segment of portimine, a marine cytotoxin from the dinoflagellate Vulcanodinium rugosum, was achieved. The route includes an acylation/aldol reaction from 3-ethoxycyclohex-2-enone to create the C3 center, the 1,4-addition of a vinyl group at C16, the diastereosele...detailed

Effects of NOx, SO2 and RH on the SOA formation from Cyclohexene (cas 110-83-8) photooxidation08/27/2019

We performed a laboratory investigation of the secondary organic aerosol (SOA) formation from cyclohexene photooxidation with different initial NOx and SO2 concentrations at low and high relative humidity (RH). Both SOA yield and number concentration first increase drastically and then, decrease...detailed

Influence of relative humidity on Cyclohexene (cas 110-83-8) SOA formation from OH photooxidation08/26/2019

Secondary organic aerosol (SOA) is a complex mixture consisting of a variety of oxidation products. In this study, the role of relative humidity (RH) on SOA formation with different [H2O2]0/[cyclohexene]0 was investigated in a smog chamber. It was found that the cyclohexene SOA yield increases w...detailed

Catalytic Cyclohexene (cas 110-83-8) oxidation in the nano channels of a copper silicate material08/23/2019

Herein we examined the catalytic activity of the copper silicate material SGU-29 for the aerobic partial oxidation of cyclohexene under mild conditions (1 bar of O2 at 70 °C). In particular, the catalytic properties of the active sites provided by [CuO4] square planar units in SGU-29 were inves...detailed

Low temperature solvent-free allylic oxidation of Cyclohexene (cas 110-83-8) using graphitic oxide catalysts08/22/2019

A range of graphitic oxides have been utilised as metal free carbocatalysts for the low temperature oxidation of cyclohexene. The activity of the catalysts was correlated with the amount of surface oxygen on the graphitic oxide. In the case of cyclohexene oxidation, major selectivity is observed...detailed

Sustainable process for adipic acid production from Cyclohexene (cas 110-83-8) in microemulsion08/21/2019

Adipic acid appears as an intermediate compound for the synthesis of polyamides and preferentially for the production of nylon-6,6 polyamide. It can be synthesized by the oxidation of cyclohexene by hydrogen peroxide in microemulsion media which has the main advantage to lead a better contact be...detailed

Short communicationHighly selective one-step catalytic amination of Cyclohexene (cas 110-83-8) to cyclohexylamine over HZSM-508/20/2019

An atom-economic and moderate approach for highly selective one-step catalytic amination of cyclohexene to cyclohexylamine using HZSM-5 with a Si/Al ratio of 38 has been successfully developed in this work. Results showed that 4.3% cyclohexene conversion with 100% selectivity to cyclohexylamine ...detailed

Please post your buying leads,so that our qualified suppliers will soon contact you!

*Required Fields