17878-39-6

Basic information

• Product Name: METHYLPHENYLVINYLSILANE
• Synonyms: METHYLPHENYLVINYLSILANE;VINYLPHENYLMETHYLSILANE;ethenylmethylphenyl-silan;PHENYLMETHYLVINYLSILANE;PHENYLMETHYLCINYLSILANE;Ethenylmethylphenylsilane;Methylvinylphenylsilane;Methylphenylvinylsilane,97%
• CAS NO: 17878-39-6
• Molecular Formula: C₉H₁₂Si
• Molecular Weight: 148.28
• EINECS: 241-830-5
• Mol File: 17878-39-6.mol

Chemical Properties

• Boiling Point: 56-57 °C (7 mmHg)
• Flash Point: 58°C
• Appearance: clear colorless liquid
• Density: 0.89
• Refractive Index: 1.5125-1.5145
• CAS DataBase Reference: METHYLPHENYLVINYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYLPHENYLVINYLSILANE(17878-39-6)
• EPA Substance Registry System: METHYLPHENYLVINYLSILANE(17878-39-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26
• TSCA: Yes
• Hazardous Substances Data: 17878-39-6(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless liquid

InChI:InChI=1/C9H11Si/c1-3-10(2)9-7-5-4-6-8-9/h3-8H,1H2,2H3

Upstream product

• 17306-05-7 phenyl methyl vinyl chlorosilane 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 

Downstream Products

• 17993-81-6 1-(chloro(dimethyl)silyl)-2-[chloro(methyl)(phenyl)silyl]ethane 
• 187389-44-2 methyl(phenyl)(vinyl)silanol 
• 61244-96-0 1,2-dimethyl-1,2-diphenyldivinyldisilane 
• 60592-88-3 ethyl(methoxy)methylphenylsilane 
• 80252-60-4 methoxy(methyl)phenyl(vinyl)silane 
• 1376711-66-8 ((E)-dec-5-en-5-yl)(methyl)(phenyl)(vinyl)silane 
• 1376711-69-1 methyl(phenyl)((E)-1-phenylpent-1-enyl)(vinyl)silane 
• 1376711-65-7 methyl(phenyl)((E)-1-phenylpent-1-en-2-yl)(vinyl)silane 
• 1376711-63-5 methyl(phenyl)((E)-1,2-diphenylvinyl)(vinyl)silane 
• 1449332-43-7 C₁₇H₁₉ClOSi 
• 1449332-45-9 C₁₇H₁₉BrOSi 
• 1449332-46-0 C₁₈H₁₉F₃OSi 
• 1449332-48-2 C₂₁H₂₂OSi 
• 1449332-50-6 C₁₉H₂₇CoSi 

Relevant articles and documents

SILENE STEREOCHEMISTRY. IV. THE CONFIGURATIONAL STABILITY OF 1-PHENYL-1-METHYL-2-NEOPENTYLSILENE UNDER FLASH VACUUM THERMOLYSIS CONDITIONS

When E- or Z-1-phenyl-1-methyl-2-neopentylsilene is generated by retro Diels-Alder flash vacuum thermolysis of their corresponding cyclopentadiene or anthracene adducts at temperatures between 400 and 650 deg C and trapped with 2,3-dimethyl-1,3-butadiene,

Synthesis of difunctional 1,4-dimethyl-1,4-disilacyclohexanes

Transformations of HVinSiCl2, HVinSi(Me)Cl, HVinSi(Me)Ph, and HVinSi(Me)NEt2 in the presence of Pt catalyst were studied. In dilute solutions, the reaction gave a mixture of structural and stereoisomers of five- and six-membered disilacyclanes, resulting from intramolecular cyclization of the initially formed linear dimer. In the case of methyl(phenyl)disilacyclane, the structural isomers were separated and tran.s-1,4-dimethyl-1,4-diphenyl-1,4-disilacyclohexane was isolated. The reaction of this product with HCI in the presence of AlCl3 followed by hydrolysis resulted in the synthesis of trans-1,4-dichloro- and trans-1,4-dihydroxy-1,4-dimethyl-1,4-disilacyclohexanes. The structures of the structural and stereoisomers synthesized were confirmed by 1H, 13C, and 29Si NMR and IR spectroscopies and mass spectrometry.