- High-efficiency synthesis method of halogenated 1, 3-indanedione compound
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The invention relates to the technical field of new material synthesis, in particular to a novel efficient synthesis method of an organic photoelectric intermediate material. The method is characterized in that the synthesis technology is simple, efficient, easy to operate and good in repeatability. The specific synthesis details are as follows: halogenated phthalic acid which is very easy to obtain in industry is used as a raw material, and a corresponding anhydride is obtained after dehydration treatment; different acid anhydrides are reacted with ethyl acetoacetate or tert-butyl acetoacetate at room temperature, and then carboxyl is mildly removed in a hydrochloric acid aqueous solution to obtain the halogenated 1, 3-indanedione compound. Simple and efficient synthesis of the organic intermediates is achieved through the method, synthesis raw materials are easy to obtain, the synthesis process is simple, the path is short, and the synthesis cost is greatly reduced.
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Paragraph 0028-0030
(2020/08/09)
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- Design, Synthesis, and Photovoltaic Characterization of a Small Molecular Acceptor with an Ultra-Narrow Band Gap
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The design of narrow band gap (NBG) donors or acceptors and their application in organic solar cells (OSCs) are of great importance in the conversion of solar photons to electrons. Limited by the inevitable energy loss from the optical band gap of the photovoltaic material to the open-circuit voltage of the OSC device, the improvement of the power conversion efficiency (PCE) of NBG-based OSCs faces great challenges. A novel acceptor–donor–acceptor structured non-fullerene acceptor is reported with an ultra-narrow band gap of 1.24 eV, which was achieved by an enhanced intramolecular charge transfer (ICT) effect. In the OSC device, despite a low energy loss of 0.509 eV, an impressive short-circuit current density of 25.3 mA cm?2 is still recorded, which is the highest value for all OSC devices. The high 10.9 % PCE of the NBG-based OSC demonstrates that the design and application of ultra-narrow materials have the potential to further improve the PCE of OSC devices.
- Yao, Huifeng,Cui, Yong,Yu, Runnan,Gao, Bowei,Zhang, Hao,Hou, Jianhui
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supporting information
p. 3045 - 3049
(2017/03/13)
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- Intermediates in the preparation of 4,5-difluoroanthranillic acid
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Compounds of the formula STR1 which are intermediates in the preparation of 4,5-difluoroanthranilic acid, an intermediate itself in the synthesis of quinolone antibacterials, and methods of preparing these intermediates.
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- Synthesis of 2-bromo-4,5-difluorobenzoic acid
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The synthesis of 2-bromo-4,5-difluorobenzoic acid was achieved from difluorophthalic anhydride by either using a Losen rearrangement or the Barton bromodecarboxylation reaction.
- Braish,Fox
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p. 3067 - 3074
(2007/10/02)
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