- Increased intensity of tert-butoxyl radical emission in 4-chloro-2- methylphenoxyacetic acid (MCPA) synthesis
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The important herbicide, 2-methyl-4-chlorophenoxyacetic acid (MCPA) was synthesized by the chlorination of 2-methylphenoxyacetic acid with tert-butyl hypochlorite in the presence of methyl N,N-dimethylglycinate as a catalyst, giving a high yield and regioselectivity. The reaction was investigated using the spin-trapping technique in electron paramagnetic resonance measurement conditions, with nitrosodurene as a spin trap. Increased intensity emission of the tert-butoxyl radical (2.9 times in relation to the starting level) was observed after the catalyst had been introduced into the reaction mixture, indicating a free radical mechanism for the reaction.
- Jezierski, Adam,Zakrzewski, Jerzy,Moszczyski, Wiesaw
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p. 1229 - 1232
(2007/10/03)
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