- Direct isocoumarin synthesis through LDA-promoted addition of acetaldehyde on orsellinate. An abrupt synthesis of 6-hydroxymellein, a fungal phytotoxin
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The LDA-promoted addition of acetaldehyde on orsellinate gives (±) 6-hydroxymellein, a fungal phytotoxin, with a 51% yield.
- Barbier,Devys
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p. 2757 - 2762
(2007/10/02)
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- Synthesis of Chlorinated Isocoumarin Derivatives
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Syhtheses of 5-chloro-, 7-chloro-, and 5,7-dichloro-isocoumarin derivatives, including the fungal metabolites 5-chloro-3,4-dihydro-8-hydroxy-6-methoxy-3-methylisocoumarin (3), 7-chloro-3,4-dihydro-8-hydroxy-6-methoxy-3-methylisocoumarin (2), and 5,7-dichl
- Henderson, Graeme B.,Hill, Robert A.
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p. 1111 - 1116
(2007/10/02)
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- Biosynthesis of Fungal Metabolites. Terrein, a Metabolite of Aspergillus terreus Thom
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Terrein, a metabolite of Aspergillus terreus Thom, is biosynthesised from 3,4-dihydro-6,8-dihydroxy-3-methylisocoumarin by contraction of an aryl ring.The direction of the ring contraction has been investigated using acetate as precursor.
- Hill, Robert A.,Carter, Rachel H.,Staunton, James
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p. 2570 - 2576
(2007/10/02)
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