- Synthesis of 2-Mono- and 2,2-Bis[2-(1H-tetrazol-5-yl)ethyl] Derivatives of Dipterocarpol
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The azidation of 2,2-bis(2-cyanoethyl)-20-hydroxydammar-24-en-3-one afforded new tetrazole derivatives of natural dipterocarpol, 2-(2-cyanoethyl)-2-[2-(1H-tetrazol-5-yl)ethyl]-20-hydroxydammar-24-en- 3-ones, 2,2-bis[2-(1H-tetrazol-5-yl)ethyl]-20-hydroxydammar-24-en-3-one, and 2,2-bis[2-(1H-tetrazol-5-yl)- ethyl]-3-oxo-25,26,27-trinordammaran-(20S),24-olide. The structure of the final and intermediate products was determined by NMR spectroscopy and X-ray analysis.
- Rodionov,Kovaleva,Zorina,Starova,Trifonov
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- DAMMARANE TRITERPENES FROM THE STEM BARK OF COMMIPHORA DALZIELLI
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From the stem bark of Commiphora dalzielii the isolation and identification of the 20,24-epoxydammarane triterpenes cabraleadiol 3-acetate, cabraleadiol and cabraleone and isofouquierone are reported.Both the acetate and isofouquierone appear to be novel.The chemotaxonomic implications of findings this type of triterpene in the Burseraceae are discussed.Key Word Index - Commiphora dalzielii; Burseraceae; dammaranes; cabraleadiol; cabraleadiol 3-acetate; cabraleone; isofouquierone; chemical taxonomy.
- Waterman, Peter G.,Ampofo, Stephen
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- VELLOZONE, A TETRACYCLIC TRITERPENE FROM VELLOZIA STIPITATA
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The isolation of (20R)-20-hydroxy-24-methylenedammar-3-one from Vellozia stipitata is described. - Key Word Index: Vellozia stipitata; V. aloifolia; Velloziaceae; tetracyclic triterpene; (20R)-20-hydroxy-24-methylenedammar-3-one.
- Pinto, Angelo C.,Baker, Paul M.,Gilbert, Benjamin,Pinchin, Richard,Reis, Francisco A. M.,et al.
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- Synthesis and properties of 2-cyanoethoxy derivatives of dammarane triterpenoids
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Cyanoethylation of dammaran-3β-ols and 3-oxime dammarene, semisynthetic derivatives of the natural dipterocarpol, afforded a series of new dammarane triterpenoids containing 2-cyanoethoxy fragment at the carbon atom in the position 3 of the tetracyclic scaffold. A notable antiviral activity was found in 20(S)-3-[(2-cyanoethoxy)imino]-dammar-24-en-20-ol and 20(S)-3-O-(2-cyanoethyl)-25,26,27-trinor-20,24-olidedammarane.
- Kaledina,Zorina,Zarubaev,Anokhina,Erkhitueva,Trifonov
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p. 1627 - 1632
(2015/12/30)
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- Ozonolysis of dipterocarpol and its derivatives
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Oxidation of dipterocarpol and its derivatives with ozone gave compounds containing lactone, lactol, alkoxytetrahydrofuran, aldehyde, and methyl ketone fragments in the side chain, as well as 1,2,4-trioxolane fragment in the A ring. The molecular and crystalline structures of dipterocarpol were determined by X-ray analysis. Pleiades Publishing, Ltd., 2012.
- Smirnova,Thu, H. Do Thi,Kazakova,Tolstikov,Kukovinets,Lobov,Suponitskii
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p. 1370 - 1376
(2013/02/22)
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- Polymeric derivatives of dipterocarpol, a dammarane triterpenoid
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Polymeric derivatives of dammarane triterpenoids with both labile and strong (covalent) polymer-triterpenoid bonds were prepared from N-vinylpyrrolidone copolymers. Pleiades Publishing, Inc., 2006.
- Zorina,Balykina,Nazarova,Rebezov
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p. 654 - 659
(2008/02/09)
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- TRITERPINOIDS FROM MANGIFERA INDICA
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Key Word Index - Mangifera indica; Anacardiaceae; triterpinoids. - From the neutral fraction of the n-hexane extract of stem bark of Mangifera indica (var./cv Banganpalli) six new tetracyclic triterpenoids, cycloart-24-ene-3β,26-diol, the C-24 epimers of cycloart-25-ene-3β,24,27-triol, the C-24 epimers of cycloartane-3β,24,25-triol and 3-ketodammar-24E-ene-20S,26-diol together with known compounds cycloartenol, α-amyrin, β-amyrin, sitosterol, 3β-hydroxycycloart-25-en-26-al, dammarenediol II, the C-24 epimers of cycloart-25-ene-3β,24-diol, 24-methylenecycloartane-3β,26-diol, ψ-taraxastane-3β,20-diol and ocotillol II have been isolated.The acidic fraction of the same extract, on esterification with diazomethane followed by chromatography, yielded methyl mangiferonate, methyl isomangiferolate, methyl mangiferolate and diazomethane adduct of methyl mangiferolate.The structures were elucidated by spectroscopic and chemical methods.
- Anjaneyulu, V.,Prasad, K. Harischandra,Ravi, K.,Conolly, J. D.
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p. 2359 - 2368
(2007/10/02)
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- TRITERPENOIDS FROM THE LEAVES OF THE SIBERIAN SPECIES OF BIRCH Betula nana and B. exilis
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The compositions of the triterpene fractions of the unsaponifiable part of the ethereal extracts of the leaves of B. nana and B. exilis have been studied.The leaves of B. exilis have yielded a new triterpene for which the structure of 3α,20(S),25-trihypro
- Pokhilo, N. D.,Malinovskaya, G. V.,Makhan'kov, V. V.,Denisenko, V. A.,Uvarova, N. I.
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p. 328 - 332
(2007/10/02)
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