20283-21-0Relevant articles and documents
The kinetics of acid-catalyzed decomposition of decanepersulfonic acid
Zaripov,Mukhametzyanova,Safiullin,Komissarov
, p. 201 - 202 (1999)
The kinetics of thermal decomposition of decanepersulfonic acid (RSO2OOH, R = C10H21) in CCl4 in the presence of cyclohexanesulfonic and trifluoroacetic acids at 323-343 K was studied. The reaction has an autocatalytic character. The kinetics of consumption of the persulfonic acid is described by the equation -d[RSO2OOH]/df = k1[RSO2OOH] + k2[RSO2OOH] · [HX].
KINETICS OF THE REACTION OF DECANESULFOPERACID WITH SO2 IN THE PRESENCE OF WATER
Safiullin, R. L.,Zaripov, R. N.,Savel'eva, G. G.,Komissarov, V. D.
, p. 469 - 471 (1991)
A study has been made of the kinetics of the oxidation of SO2 by decanesulfoperacid in the presence of water in a medium of CH3CN.Retardation of the process by acids has been observed, the retarding effect decreasing with decreasing strength of acid.A mechanism for the reaction has been suggested which explains the experimental results obtained.