cas 20416-08-4, methyl 5-benzyl-3-furoate | Articles data ｜lookchem

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20416-08-4

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Synthesis of substituted 3-furanoates from MBH-acetates of acetylenic aldehydes via tandem isomerization-deacetylation-cycloisomerization: Access to Elliott's alcohol
A new method for the synthesis of 5-substituted furan-3-carboxylates from Morita-Baylis-Hillman acetates of acetylenic aldehydes is reported. The process involves palladium-catalyzed isomerization followed by base-promoted deacetylation and cycloisomerization reactions. The utility of this chemistry is further demonstrated by the synthesis of Elliott's alcohol, a key intermediate of the pyrethroid resmethrins. This journal is The Royal Society of Chemistry 2014.
Reddy, Chada Raji,Krishna, Gaddam,Reddy, Motatipally Damoder
p. 1664 - 1670
(2014/03/21)

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20416-09-5
(5-benzylfuran-3-yl)methanol

Chemical Properties

Boiling Point: 320.6°Cat760mmHg
Flash Point:147.7°C
Density: 1.14g/cm³
Vapor Pressure: 0.000315mmHg at 25°C
PSA: 39.44000
LogP: 2.65700

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