204262-03-3Relevant articles and documents
On the [3 + 2] annulation of cyclic allylsilanes with N -phenyltriazolinedione: An enantio- and diastereoselective synthesis of cis -1,3-diaminocyclitols
Dey, Raudra T.,Sarkar, Tarun K.
supporting information; experimental part, p. 4521 - 4529 (2010/10/03)
(Figure presented) Improved conditions were found to trigger [3 + 2] annulation of cyclic allylsilanes with N-phenyltriazolinedione (PTAD); the products from this reaction were readily tailored into cis-1,3-diaminocyclitols in highly enantioenriched form with full stereochemical control of up to four contiguous stereogenic centers.
Stereocontrolled Preparation of Cyclohexane Amino Alcohols Utilising a Modified Mitsunobu Reaction
Sammes, Peter G.,Thetford, Dean
, p. 655 - 661 (2007/10/02)
A method for the introduction of amino groups into aliphatic systems is described.Cyclohex-2-enol reacts with aromatic diacylamines under Mitsunobu reaction conditions to give either N-alkylated or O-alkylated products in a controlled, predictable manner.
