Merging Halogen-Atom Transfer (XAT) and Copper Catalysis for the Modular Suzuki-Miyaura-Type Cross-Coupling of Alkyl Iodides and Organoborons
We report here a mechanistically distinct approach to achieve Suzuki-Miyaura-type cross-couplings between alkyl iodides and aryl organoborons. This process requires a copper catalyst but, in contrast with previous approaches based on palladium and nickel
Zhang, Zhenhua,Górski, Bartosz,Leonori, Daniele
supporting information
p. 1986 - 1992
(2022/02/01)
Synthesis of C-substituted cyclic amines using azacycloalkyl organozinc reagents
Azetidine and piperidine derived organozinc species have been prepared from the corresponding azacycloalkyl iodides by direct Zn insertion. They have been shown to readily undergo Pd(0) mediated cross-coupling reactions and to transmetallate with CuCN.2LiCl.
Billotte
p. 379 - 380
(2007/10/03)
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