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8-Azabicyclo[3.2.1]oct-2-ene,8-methyl-,(1R,5S)-(9CI) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 208037-81-4 Structure
  • Basic information

    1. Product Name: 8-Azabicyclo[3.2.1]oct-2-ene,8-methyl-,(1R,5S)-(9CI)
    2. Synonyms: 8-Azabicyclo[3.2.1]oct-2-ene,8-methyl-,(1R,5S)-(9CI)
    3. CAS NO:208037-81-4
    4. Molecular Formula: C8H13N
    5. Molecular Weight: 123.2
    6. EINECS: N/A
    7. Product Categories: AMINETERTIARY;PYRROLIDINE
    8. Mol File: 208037-81-4.mol
    9. Article Data: 2
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 8-Azabicyclo[3.2.1]oct-2-ene,8-methyl-,(1R,5S)-(9CI)(CAS DataBase Reference)
    10. NIST Chemistry Reference: 8-Azabicyclo[3.2.1]oct-2-ene,8-methyl-,(1R,5S)-(9CI)(208037-81-4)
    11. EPA Substance Registry System: 8-Azabicyclo[3.2.1]oct-2-ene,8-methyl-,(1R,5S)-(9CI)(208037-81-4)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 208037-81-4(Hazardous Substances Data)

208037-81-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 208037-81-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,0,8,0,3 and 7 respectively; the second part has 2 digits, 8 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 208037-81:
(8*2)+(7*0)+(6*8)+(5*0)+(4*3)+(3*7)+(2*8)+(1*1)=114
114 % 10 = 4
So 208037-81-4 is a valid CAS Registry Number.

208037-81-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name tropidine

1.2 Other means of identification

Product number -
Other names (1R,5S)-8-Methyl-8-aza-bicyclo[3.2.1]oct-2-ene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:208037-81-4 SDS

208037-81-4Relevant articles and documents

Cationic tropidinyl scandium catalyst: A perfectly acceptable substitute for cationic half-sandwich scandium catalysts in cis -1,4-Polymerization of isoprene and copolymerization with norbornene

Liu, Siqian,Du, Gaixia,He, Jianyun,Long, Yingyun,Zhang, Shaowen,Li, Xiaofang

, p. 3567 - 3573 (2014)

Different nonmetallocene rare earth metal alkyl complexes such as monotropidinyl (Trop) scandium dialkyl complex (Trop)Sc(CH2SiMe 3)2(THF) (1), ditropidinyl yttrium alkyl complex (Trop)2Y(CH2SiMe3)(THF) (3) as well as binuclear lutetium alkyl complex bearing one tetradentate dianionic 6-N-methyl-1,4-cycloheptadienyl (NMCH) ligand [(NMCH)Lu(CH2SiMe 3)(THF)]2 (2) have been synthesized in high yields via one-pot acid-base reaction by using of the tris(trimethylsilylmethyl) rare earth metal complexes with the readily available natural product tropidine. The polymerization experiments indicate that the monotropidinyl scandium dialkyl complex 1 displays reactivity akin to that of the analogous monocyclopentadienyl scandium dialkyl complexes. In the presence of activator and a small amount of AlMe3, complex 1 exhibits similar activities (up to 1.6 × 106 g molSc-1 h-1) but higher cis-1,4-selectivities (up to 100%) than (C5H5)Sc(CH 2SiMe3)2(THF) (cis-1,4-selectivity as 95%) in the isoprene polymerization, yielding the pure cis-1,4-PIPs with moderate molecular weights (Mn = 0.5-11.2 × 104 g/mol) and bimodal molecular weight distributions (Mw/Mn = 1.48-6.07). Moreover, the complex 1/[Ph3C][B(C6F 5)4/AliBu3 ternary system also shows good comonomer incorporation ability in the copolymerization of isoprene and norbornene similar to the [C5Me4(SiMe3)] Sc(η3-CH2CHCH2)2/activator binary system, affording the random isoprene/norbornene copolymers with a wide range of isoprene contents around 57-91 mol % containing cis-1,4 configuration up to 88%.

Enantiospecific Synthesis of Natural (-)-Cocaine and Unnatural (+)-Cocaine from D- And L-Glutamic Acid

Lin, Ronghui,Castells, Josep,Rapoport, Henry

, p. 4069 - 4078 (2007/10/03)

Natural (-)-cocaine and unnatural (+)-cocaine have been synthesized enantiospecifically from D-and L-glutamic acid, respectively. The axial-equatorial substitutents were introduced by a stereo-and regiospecific dipolar cycloaddition to the corresponding (1R,5S)- and (1S,5R)-N-BOC-nortropenes with (ethoxycarbonyl)formonitrile N-oxide. A sequence of subsequent stereochemically controlled transformations converted the fused isoxazoline to the requisite β-hydroxy ester. Synthesis of the key intermediate N-BOC-nortropenes involved construction of the 8-azabicyclo[3.2.1]octane framework by Dieckmann condensation of cis-5-substituted D- and L-proline esters. For comparison, (1R,5S)-N-BOC-nortropene also was derived by degradation from natural cocaine. The cis-5-substituted D- and L-proline esters were obtained by sulfide contraction and subsequent catalytic hydrogenation to induce stereospecifically the C-5 stereochemistry from D- and L-thiopyroglutamate, which in turn were prepared from D- and L-glutamic acids, respectively.

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