Dual reactivity of 1-chloro- and 1-bromo-3,5-dinitrobenzenes in aromatic nucleophilic substitution
Aromatic nucleophilic substitution reactions in 1-halo-3,5-dinitrobenzenes (where the halogen is bromine or chlorine) can occur with replacement of either a nitro group or a halogen atom, depending on the nature of anionic nucleophile Nu– as a Lewis base (hard, soft or intermediate), as well as on the polarity of the dipolar aprotic solvent.
Dutov, Mikhail D.,Shevelev, Svyatoslav A.,Koshelev, Vladimir N.,Aleksanyan, David R.,Serushkina, Olga V.,Neverova, Olga D.,Kolvina, Evgeniya V.,Bobrov, Egor S.
p. 160 - 162
(2017/03/30)
Reaction of polyfluorinated alcohols with 1,3,5-trinitrobenzene and its analogs
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Shevelev,Dutov,Korolev,Sapozhnikov,Rusanov
p. 1623 - 1624
(2007/10/03)
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