208333-78-2Relevant academic research and scientific papers
Dual reactivity of 1-chloro- and 1-bromo-3,5-dinitrobenzenes in aromatic nucleophilic substitution
Dutov, Mikhail D.,Shevelev, Svyatoslav A.,Koshelev, Vladimir N.,Aleksanyan, David R.,Serushkina, Olga V.,Neverova, Olga D.,Kolvina, Evgeniya V.,Bobrov, Egor S.
, p. 160 - 162 (2017/03/30)
Aromatic nucleophilic substitution reactions in 1-halo-3,5-dinitrobenzenes (where the halogen is bromine or chlorine) can occur with replacement of either a nitro group or a halogen atom, depending on the nature of anionic nucleophile Nu– as a Lewis base (hard, soft or intermediate), as well as on the polarity of the dipolar aprotic solvent.
