208453-80-9

Basic information

• Product Name: D-Alanine, N-(methoxycarbonyl)-, methyl ester (9CI)
• Synonyms: D-Alanine, N-(methoxycarbonyl)-, methyl ester (9CI)
• CAS NO: 208453-80-9
• Molecular Formula: C6H11NO4
• Molecular Weight: 161.15584
• Product Categories: GLYCINESCAFFOLD
• Mol File: 208453-80-9.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: D-Alanine, N-(methoxycarbonyl)-, methyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: D-Alanine, N-(methoxycarbonyl)-, methyl ester (9CI)(208453-80-9)
• EPA Substance Registry System: D-Alanine, N-(methoxycarbonyl)-, methyl ester (9CI)(208453-80-9)

Safety Data

• Hazardous Substances Data: 208453-80-9(Hazardous Substances Data)

Upstream product

• 5445-17-0 Methyl 2-bromopropionate 
• 76637-56-4 2-<(methoxycarbonyl)amino>-2-propenoic acid methyl ester 
• 67-56-1 methanol 
• 590-28-3 potassium cyanate 

Relevant articles and documents

DIAZAPHOSPHACYCLES

Diazaphosphacycles comprising compounds having the formula XI : and salts of the compound are provided, wherein the variables W, T, R1, R14, and R15 are as described herein. Transition metal catalysts incorporating such diazaphosphacycles and methods of u

Aminosaeuren, I. Darstellung von Aminosaeuren aus Halogencarbonsaeure-alkylestern mit Alkalimetallcyanaten

α- and ω-halo- as well as α,ω-dihalocarboxylic alkyl esters react with potassium cyanate in the presence of alcohol at 80 - 120 deg C in dipolar aprotic solvents to yield α- and ω-(alkoxycarbonylamino)- and α,ω-bis(alkoxycarbonylamino)carboxylic alkyl esters, respectively, in good yields.Hydrolytic cleavage of these mono- or diurethanes with an aqueous solution of hydrochloric acid/formic acid leads to the corresponding amino acid hydrochlorides in nearly quantitative yields.

Process for the production of aminoacid hydrochlorides/or diaminoacid dihydrochlorides

Aminoacid hydrochlorides or diaminoacid dihydrochlorides are produced by first reacting a halocarboxylic acid ester with an alkali metal cyanate in the presence of an alcohol to form the corresponding mono- or diurethane and then saponifying this to the corresponding mono- or dihydrochloride. The new process is relatively versatile in its use and above all opens up an elegant synthesis route for lysine.