219899-88-4Relevant articles and documents
Au-Catalyzed tandem intermolecular hydroalkoxylation/Claisen rearrangement between allylic alcohols and chloroalkynes
Liu, Congrong,Xu, Jin,Ding, Lianghui,Zhang, Haiyun,Xue, Yunbo,Yang, Fulai
supporting information, p. 4435 - 4439 (2019/05/16)
An efficient protocol for the synthesis of γ,δ-unsaturated α-chloroketones has been developed via Au-catalyzed tandem intermolecular hydroalkoxylation/Claisen rearrangement. In the presence of 1 mol% JohnPhosAuCl and 1 mol% NaBArF, a broad range of allyli
Sequential free radical reactions with xanthates: Cyclopentane ring annulation
Maslak,?ekovi?,Sai?i?
, p. 1435 - 1437 (2007/10/03)
In the presence of electron-rich alkenes, electro- and ambiphilic homoallylic radicals, generated by homolytic decomposition of the corresponding xanthates, undergo annulation with inverse electron-demand, and afford cyclopentane derivatives in moderate t