- Synthesis of 1,3,6,8-tetrabromophenanthrene via a stoichiometric Ullmann reaction
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1,3,6,8-Tetrabromophenantherene (1) is prepared in four steps from 2,4,6-tribromobenzoic acid (4) in an overall yield of 12%. The key transformation used in the synthesis is a stoichiomteric Ullmann reaction.
- Farrar,Sienkowska,Kaszynski
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- Mercury-assisted solvolyses of alkyl halides. Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers
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The reactions of a wide variety of alkyl halides with mercury(I) and/or (II) nitrate in 1,2-dimethoxyethane, mercury(II) acetate in acetic acid, aqueous mercury(II) perchlorate, and mercury(II) perchlorate in alcohol solvents have been investigated; as a result, simple high yield procedures for the conversion of alkyl halides into the corresponding nitrate esters, acetate esters, alcohols and ethers have been developed.
- McKillop,Ford
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p. 2467 - 2475
(2007/10/05)
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