cas 221676-20-6, <(1S,2S)-1-cyclohexyl-2-(methoxymethyl)oxy-3-buten-1-yloxy>(dimethyl)(1-octen-2-yl)silane | Articles data ｜lookchem

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221676-20-6

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A tripartite asymmetric allylboration - Silicon tethered alkene ring closing metathesis - In situ ring opening protocol for the regiospecific generation of functionalized (E)-disubstituted homoallylic alcohols
Molybdenum carbene 6 catalyzed ring closing metathesis of (alkenyl)silyl ethers of homochiral allylic alcohols to afford 1,2-oxasilines which were elaborated in situ to give (E)-4-alkyl-1,2-disubstituted 3-buten-1-ol and (Z)-4-alkyl-4-silyl-1,2-disubstituted 3-buten-1-ol derivatives as single geometric isomers.
Ahmed, Mahmood,Barrett, Anthony G. M.,Beall, Jennifer C.,Braddock, D. Christopher,Flack, Kevin,Gibson, Vernon C.,Procopiou, Panayiotis A.,Salter, Matthew M.
p. 3219 - 3232
(2007/10/03)

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221676-28-4
(5S,6S)-6-cyclohexyl-2,2-dimethyl-3-hexyl-5-<(methoxymethyl)oxy>-5,6-dihydro-2H-1,2-oxasiline

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