22480-64-4

Basic information

• Product Name: Lithium,(4-bromophenyl)-
• Synonyms: Lithium,(p-bromophenyl)- (6CI,7CI,8CI); Benzene, bromo-, lithium complex; (p-Bromophenyl)lithium; 1-Bromo-4-lithiobenzene; 4-Bromophenyllithium
• CAS NO: 22480-64-4
• Molecular Formula: C₆H₄BrLi
• Molecular Weight: 162.95
• Mol File: 22480-64-4.mol

Chemical Properties

• CAS DataBase Reference: Lithium,(4-bromophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium,(4-bromophenyl)-(22480-64-4)
• EPA Substance Registry System: Lithium,(4-bromophenyl)-(22480-64-4)

Safety Data

• Hazard Codes: 3:
• Safety Statements: −. See also LITHIUM COMPOUNDS." target="_blank">Explodes on exposure to oxygen. When heated to decomposition it emits toxi
• Hazardous Substances Data: 22480-64-4(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Industry:
Lithium,(4-bromophenyl)is used as a reagent in the synthesis of complex organic molecules for the development of new pharmaceuticals. Its ability to form carbon-carbon and carbon-heteroatom bonds is essential in creating the molecular structures required for various medicinal applications.
Used in Agrochemical Industry:
In the agrochemical sector, Lithium,(4-bromophenyl)serves as a key intermediate in the synthesis of active ingredients for pesticides and other agricultural chemicals. Its nucleophilic properties facilitate the formation of necessary chemical bonds to produce effective compounds for crop protection and enhancement.
Used in Fine Chemicals Industry:
Lithium,(4-bromophenyl)is employed as a building block in the production of fine chemicals, which are high-purity chemicals used in various applications such as fragrances, dyes, and specialty chemicals. Its strong basic and nucleophilic nature allows for the creation of intricate molecular structures with specific properties.
Used in Organic Synthesis Research:
In academic and industrial research settings, Lithium,(4-bromophenyl)is utilized as a versatile reagent for exploring new synthetic pathways and developing innovative methods in organic chemistry. Its reactivity and selectivity make it a valuable tool for creating novel compounds and understanding reaction mechanisms.

Upstream product

• 106-37-6 1.4-dibromobenzene 
• 811-49-4 ethyllithium 
• 17946-45-1 tris-(4-bromophenyl)stibine 
• 109-72-8 n-butyllithium 

Downstream Products

• 24641-31-4 2-(4-bromophenyl)quinoline 
• 16839-13-7 4-bromophenylphosphonic acid 
• 18737-40-1 4-bromophenyltriphenylsilane 
• 198066-39-6 bis-(4-bromo-phenyl)-phenyl-methanol 
• 109014-68-8 (4-bromo-phenyl)-(3-chloro-phenyl)-selenide 
• 111356-37-7 biphenyl-2-yl-(4-bromo-phenyl)-selenide 
• 15799-67-4 (4-bromophenyl)triphenyl stannane 
• 2378-48-5 4,4'-Dibrom-α,α'-difluor-stilben 
• 1735-38-2 α,α'-Difluor-4-bromstilben 
• 1839-98-1 4-Brom-α,α'-difluor-2'-methyl-stilben 
• 52890-37-6 (1-Bromo-1-methyl-ethyl)-(4-bromo-phenyl)-dimethyl-silane 
• 38109-41-0 trans-1-(p-bromophenyl)-4-t-butyl-1-methyl-1-silacyclohexane 
• 38109-42-1 1r-(4-bromo-phenyl)-4c-tert-butyl-1-methyl-silinane 
• 22217-79-4 5-(4-bromophenyl)-3,4-dihydro-2H-pyrrole 

Relevant articles and documents

NOVEL COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND ELECTRONIC DEVICE

A compound is represented by a formula (1) below. In the formula (1), X1 to X8 each independently represent a carbon atom to be bonded to a group represented by a formula (20) below, CRX or a nitrogen atom. At least one of X1 to X8 is a carbon atom to be bonded to the group represented by the formula (2). RX is independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, and the like.

NEW DIAMINE DERIVATIVES AND ORGANIC ELECTRONIC DEVICE USING THE SAME

The present invention relates to a new diamine derivative, and an organic electronic device using the same. The diamine derivative according to the present invention can serve as a hole injecting, hole transporting, electron injecting, electron transporting, or light emitting material in an organic electronic device including an organic light emitting device. Particularly, it can serve as a light emitting dopant as used alone, in particular, a blue light emitting dopant. The organic electronic device according to the present invention exhibits excellent characteristics in terms of efficiency, drive voltage, life time, and stability.

Preliminary Studies of the Mechanism of Metal-Halogen Exchange. The Kinetics of Reaction of n-Butyllithium with Substituted Bromobenzenes in Hexane Solution

Initial measurements of the rate of reaction of bromobenzene with n-butyllithium in hexane solution have shown the exchange to be first order in bromobenzene and first order in n-butyllithium, with an activation energy of 12 kcal mol-1 (52 kJ mol-1).A Hammett relationship for the reaction of substituted bromobenzenes with n-butyllithium suggests negative charge character in the transition state (ρ ca 2).The addition of a Lewis donor (p-methylanisole) to the hexane solution was found to result in an increase in the rate of exchange, but did not affect the Hammett reaction constant.Several transition-state structures are considered; available evidence suggests that the exchange may be concerted, with either a four-centered structure, or SN2-type attack of the n-butyl anion at the bromine of the aryl bromide