233281-31-7Relevant articles and documents
Effect of the linkages on the self-assembly and photophysical properties of 4,7-diphenyl-2,1,3-benzothiadiazole-based luminescent polycatenars
Hu, Jinliang,Xiao, Yulong,Chang, Qing,Gao, Hongfei,Cheng, Xiaohong
, (2019/05/10)
Three series of 4,7-diphenyl-2,1,3-benzothiadiazole (DBTD)based polycatenars containing a central 4,7-diphenyl-2,1,3-benzothiadiazole moiety connected to 3,4,5-trialkoxyl benzene units at both ends through ether (-OCH2-), ester (-OOC-)or amide (-HNCO-)linkages were synthesized via Suzuki coupling reaction as key step. The polarities of the linkages had great effect on their self-assembly and photophycial properties. Both ether and amide compounds were mesogens, while the ester compounds were non-mesogens. The ether compounds displayed Colhex/p6mm phases, while the amide compound displayed two kinds of columnar phases i.e. columnar rectangular phase with p2mm and columnar hexagonal phase with p6mm lattices depending on temperature. The column phases could be aligned in electric field or under mechanical shearing. The ether and amide compounds showed the significant red-shifted maximum absorption and emission. In the solid and gel states, both ether and amide compounds were yellow luminescence, while ester compounds were green luminescence.
Rational Design of Supramolecular Dynamic Protein Assemblies by Using a Micelle-Assisted Activity-Based Protein-Labeling Technology
Sandanaraj, Britto S.,Reddy, Mullapudi Mohan,Bhandari, Pavankumar Janardhan,Kumar, Sugam,Aswal, Vinod K.
, p. 16085 - 16096 (2018/10/15)
The self-assembly of proteins into higher-order superstructures is ubiquitous in biological systems. Genetic methods comprising both computational and rational design strategies are emerging as powerful methods for the design of synthetic protein complexes with high accuracy and fidelity. Although useful, most of the reported protein complexes lack a dynamic behavior, which may limit their potential applications. On the contrary, protein engineering by using chemical strategies offers excellent possibilities for the design of protein complexes with stimuli-responsive functions and adaptive behavior. However, designs based on chemical strategies are not accurate and therefore, yield polydisperse samples that are difficult to characterize. Here, we describe simple design principles for the construction of protein complexes through a supramolecular chemical strategy. A micelle-assisted activity-based protein-labeling technology has been developed to synthesize libraries of facially amphiphilic synthetic proteins, which self-assemble to form protein complexes through hydrophobic interaction. The proposed methodology is amenable for the synthesis of protein complex libraries with molecular weights and dimensions comparable to naturally occurring protein cages. The designed protein complexes display a rich structural diversity, oligomeric states, sizes, and surface charges that can be engineered through the macromolecular design. The broad utility of this method is demonstrated by the design of most sophisticated stimuli-responsive systems that can be programmed to assemble/disassemble in a reversible/irreversible fashion by using the pH or light as trigger.
Dicyanamide Salts that Adopt Smectic, Columnar, or Bicontinuous Cubic Liquid-Crystalline Mesophases
Park, Geonhui,Goossens, Karel,Shin, Tae Joo,Bielawski, Christopher W.
supporting information, p. 6399 - 6411 (2018/04/19)
Although dicyanamide (i.e., [N(CN)2]?) has been commonly used to obtain low-viscosity, halogen-free, room-temperature ionic liquids, liquid-crystalline salts containing such anions have remained virtually unexplored. Here we report a
Coumarin-based emissive hexacatenars: synthesis, 2D and 3D self-assembly and photodimerization
Xiao, Yulong,Tan, Xiaoping,Xing, Wei,Zhao, Kai,Zhang, Bei,Cheng, Xiaohong
supporting information, p. 10782 - 10792 (2018/10/25)
The first examples of unsymmetric coumarin polycatenar liquid crystals consisting of a coumarin central core with 1,2,3-triazole dendritic wings on both sides were synthesized via click reaction. Their properties were investigated using POM, DSC, XRD, SEM
PRECIPITATION PROMOTER AND PRECIPITATION METHOD IN WHICH SAME IS USED
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, (2017/11/29)
Precipitation promoters, which are an organic compound having one or more linear aliphatic hydrocarbon groups having not less than 10 carbon atoms, wherein the aliphatic hydrocarbon group has not less than 20 carbon atoms in total are useful for precipita
POLYCATENAR LIGANDS AND HYBRID NANOPARTICLES MADE THEREFROM
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, (2017/10/13)
Described herein are polycatenar ligand compounds and their use in the production of hybrid nanoparticles, typically nanocrystals. The present disclosure also relates to films containing the hybrid nanoparticles described herein and their use.
HYDROPHOBIN MIMICS: PROCESS FOR PREPARATION THEREOF
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Paragraph 0132; 0133; 0311; 0312; 0313-0319; 0370-0379, (2017/09/02)
The present invention discloses hydrophobin mimics of formula (I) comprising a protein head group, hydrophilic linker and hydrophobic tail and to a process for synthesis of library of hydrophobin mimics thereof. The hydrophobin mimics of the present invention self-assemble to form protein nanoparticles/nanocontainer either alone or in a specified chemical environment. The hydrophobin mimics (I) of the present invention find application in area of bio-nanotechnology.
Polycatenar Ligand Control of the Synthesis and Self-Assembly of Colloidal Nanocrystals
Diroll, Benjamin T.,Jishkariani, Davit,Cargnello, Matteo,Murray, Christopher B.,Donnio, Bertrand
, p. 10508 - 10515 (2016/09/04)
Hydrophobic colloidal nanocrystals are typically synthesized and manipulated with commercially available ligands, and surface functionalization is therefore typically limited to a small number of molecules. Here, we report the use of polycatenar ligands d
STABLE HOMOGENEOUSLY MIXED NANOSCALE COATINGS DERIVED FROM UNIQUE MULTI-FUNCTIONAL AND MULTIDENTATE AROMATIC ADSORBATES
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Paragraph 0075, (2014/01/08)
Novel tridentate-, bidentate-, and monodentate-based aromatic adsorbates including self-assembled monolayers (SAMs), especially, mixed multi-component SAMs, where the adsorbates comprise an aromatic ring including one head group or a plurality of dentate
Solution-phase total synthesis of the hydrophilic natural product argifin using 3,4,5-tris(octadecyloxy)benzyl tag
Hirose, Tomoyasu,Kasai, Takako,Akimoto, Takafumi,Endo, Ayako,Sugawara, Akihiro,Nagasawa, Kazuo,Shiomi, Kazuro,Omura, Satoshi,Sunazuka, Toshiaki
, p. 6633 - 6643 (2011/09/30)
A solution-phase total synthesis of argifin using 3,4,5-tris(octadecyloxy) benzyl tag as a hydrophobic protective group of carboxylic acid was developed to produce 44% overall yield for 16 linear steps. Argifin, a novel class of natural product chitinase