A general, efficient and stereospecific route to sphingosine, sphinganines, phytosphingosines and their analogs
Sphingosine, sphinganines and phytosphingosines and their analogs were synthesized by an aldol condensation between an iminoglycinate bearing a (+)-(1R,2R,5R)-2-hydroxy-3-pinanone group as chiral auxiliary and an appropriate aldehyde. All condensations proceeded with excellent enantioselectivity to generate the (2S,3R)-d-erythro structures in good yields. The Royal Society of Chemistry 2006.
Cai, Ye,Ling, Chang-Chun,Bundle, David R.
p. 1140 - 1146
(2008/02/03)
More Articles about upstream products of 24006-62-0