240123-21-1

Basic information

• Product Name: [(κ2-P,N)-2-(N,N-dimethylamino)ethyldiphenylphosphino]dimethylplatinum(II)
• CAS NO: 240123-21-1
• Molecular Weight: 482.465
• Mol File: 240123-21-1.mol

Chemical Properties

• CAS DataBase Reference: [(κ2-P,N)-2-(N,N-dimethylamino)ethyldiphenylphosphino]dimethylplatinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: [(κ2-P,N)-2-(N,N-dimethylamino)ethyldiphenylphosphino]dimethylplatinum(II)(240123-21-1)
• EPA Substance Registry System: [(κ2-P,N)-2-(N,N-dimethylamino)ethyldiphenylphosphino]dimethylplatinum(II)(240123-21-1)

Safety Data

• Hazardous Substances Data: 240123-21-1(Hazardous Substances Data)

Upstream product

• 53199-36-3 (norbornadiene)dimethylplatinum(II) 
• 29679-67-2 N,N-dimethyl-2-diphenylphosphinoethylamine 

Downstream Products

• 484065-56-7 C₁₇H₂₃ClNPPt 
• 484065-58-9 C₁₉H₂₉ClNPPt 
• 1559000-85-9 C₂₁H₃₀NO₂PPt 
• 1559000-88-2 C₂₂H₃₂NO₂PPt 
• 240123-23-3 [(κ(2)-P,N)-Me2NCH2CH2PPh2]Pt[Si(OMe)3]Me 
• 240123-25-5 [(κ(2)-P,N)-Me2NCH2CH2PPh2]Pt[Si(OMe)3]2 
• 484065-56-7 [(κ(2)-P,N)-Ph2PCH2CH2NMe2]Pt(Me)Cl 
• 484065-59-0 [(κ(2)-P,N)-Ph2PCH2CH2NMe2]PtCl(C(Cl)CH2) 
• 256422-21-6 trans-[(κ2-P,N)-2-(N,N-dimethylamino)ethyldiphenylphosphino]iodomethylplatinum(II) 
• 256422-25-0 [(κ2-P,N)-2-(N,N-dimethylamino)ethyldiphenylphosphino][1,2-bis(dimethylsilyl)benzene]platinum(II) 
• 705255-21-6 cis-(Ph₂PC₂H₄NMe₂)2PtMe₂ 

Relevant articles and documents

Transition Metal Silyl Complexes. 62.1 Platinum Dimethyl Complexes with Hemilabile P,N-Chelating Ligands: Synthesis, Structure, and Reactions with Iodotrimethylsilane and 1,2-Bis(dimethylsilyl)benzene

Reaction of (η4-2,5-norbornadiene)dimethylplatinum(II) with (2-diphenylphosphinoethyl)-dimethylamine, (3-diphenylphosphinopropyl)dimethylamine, 2-diphenylphosphino-N,N-dimethylaniline, or (o-diphenylphosphinobenzyl)dimethylamine resulted in the

Transition metal silyl complexes. 60.?,1 enhanced reactivity of a platinum dimethyl complex toward trimethoxysilane due to a P,N-chelating Co ligand

[(K2-P,N)-Me2NCH2CH2PPh 2]PtMe2 reacts with trimethoxysilane to yield the methyl trimethoxysilyl complex [(K2-P,N)-Me2NCH2CH2PPh 2]Pt[Si(OMe)3]Me, the bis(trimethoxysilyl) complex [(K2-P,N)-Me2NCH2CH2-PPh 2]Pt[Si(OMe)3]2, methyltrimethoxysilane, tetramethoxysilane, and small amounts of pentamethoxydisiloxane and hexamethoxydisiloxane. The formation of these compounds can be explained by Si-H oxidative addition / reductive elimination as well as Si-O activation and scrambling reactions of the silicon substituents.