24407-32-7

Basic information

• Product Name: 3,4,5,6-TETRABROMOPHTHALIMIDE
• Synonyms: TETRABROMOPHTHALIMIDE;3,4,5,6-TETRABROMOPHTHALIMIDE;1H-Isoindole-1,3(2H)-dione, 4,5,6,7-tetrabromo-;4,5,6,7-Tetrabromo-1H-isoindole-1,3(2H)-dione;Tetrabromophthalimide,97%;3,4,5,6-Tetrabromophthalimide 97%;4,5,6,7-Tetrabromo-1H-isoindole-1,3(2H)-dione, 4,5,6,7-Tetrabromoisoindolin-1,3-dione
• CAS NO: 24407-32-7
• Molecular Formula: C₈HBr₄NO₂
• Molecular Weight: 462.72
• EINECS: 246-232-8
• Mol File: 24407-32-7.mol

Chemical Properties

• Melting Point: >300°C
• Appearance: /
• Density: 2.685g/cm³
• Refractive Index: 1.721
• CAS DataBase Reference: 3,4,5,6-TETRABROMOPHTHALIMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,5,6-TETRABROMOPHTHALIMIDE(24407-32-7)
• EPA Substance Registry System: 3,4,5,6-TETRABROMOPHTHALIMIDE(24407-32-7)

Safety Data

• Statements: R36/37/38:Irritating to eyes, respiratory system and skin.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36:Wear suitable prot
• Hazardous Substances Data: 24407-32-7(Hazardous Substances Data)

Usage

Uses

Used in Flame Retardant Applications:
3,4,5,6-Tetrabromophthalimide is used as a flame retardant in various industries for its capacity to prevent or slow down the spread of flames. This application is crucial in the production of materials that require enhanced fire safety measures, such as in the manufacturing of electronics, textiles, and construction materials.
Used in Industrial and Consumer Product Manufacturing:
3,4,5,6-TETRABROMOPHTHALIMIDE is incorporated into the production of a wide range of industrial and consumer products to enhance their fire resistance. This is particularly important in industries where the risk of fire is high, such as in the production of electrical equipment, furniture, and automotive components.
Used in Environmental and Health Risk Assessment:
Given its persistence in the environment and potential for bioaccumulation, 3,4,5,6-Tetrabromophthalimide is also used as a subject of study in environmental and health risk assessments. These assessments aim to understand the compound's behavior in the environment, its potential impact on ecosystems, and the development of strategies to mitigate any adverse effects.
It is essential to handle and dispose of 3,4,5,6-Tetrabromophthalimide with caution, adhering to safety guidelines to minimize its potential risks to human health and the environment.

InChI:InChI=1/C8HBr4NO2/c9-3-1-2(8(15)13-7(1)14)4(10)6(12)5(3)11/h(H,13,14,15)

Upstream product

• 1336-21-6 ammonium hydroxide 
• 632-79-1 Tetrabromophthalic anhydride 
• 85-44-9 phthalic anhydride 
• 76240-79-4 SS-diphenyl-N-tetrabromophthalimidosulphoximide 
• 77287-34-4 formamide 

Downstream Products

• 119812-71-4 4-O-Acetyl-2,3-dideoxy-3-tetrabromophthalimido-1-<9-(6-phenylamino-2-methylpurinyl)>-β-D-threo-pentopyranose 
• 1202888-50-3 methyl (R)-2-[phenyl(4,5,6,7-tetrabromo-1,3-dioxoisoindolin-2-yl)methyl]acrylate 
• 1446318-07-5 C₁₈H₁₂Br₄N₂O₄ 
• 1353155-51-7 [2-(2-methyl)-3-(2-methylphenyl)-4(3H)-quinazolin-8-yloxy-N-(4,5,6,7-tetrabromo-1,3-dioxoisoindolin-2-yl)]acetamide 
• 110509-24-5 2,3-Dideoxy-3-(3,4,5,6-tetrabromophthalimido)-β-D-threo-pentopyranose 
• 110472-45-2 2,3-Dideoxy-3-(3,4,5,6-tetrabromophthalimido)-α-D-threo-pentopyranose 
• 110472-56-5 2,3-Dideoxy-3-(3,4,5,6-tetrabromophthalimido)-5-O-(triphenylmethyl)-α-D-erythro-pentofuranose 
• 110472-57-6 2,3-Dideoxy-3-(3,4,5,6-tetrabromophthalimido)-5-O-(triphenylmethyl)-β-D-erythro-pentofuranose 
• 54098-90-7 tetrabromoanthranilic acid 

Relevant articles and documents

Synthesis of N-unsubstituted cyclic imides from anhydride with urea in deep eutectic solvent (DES) choline chloride/urea

N-Unsubstituted cyclic imides were readily synthesized in deep eutectic solvent (DES) choline chloride (ChCl)/urea from anhydrides with urea. Urea serves as both a DES component and a nitrogen source, which endows the protocol with advantages of smooth reaction, easy separation of products, simple recovery and recycling of ChCl/urea.

Grinding imidation of anhydrides on smectite clays as recyclable and heterogeneous catalysts under solvent-free conditions

Imidation of various anhydrides employing solvent-free grindstone technique using smectite clays as recyclable and green catalysts was examined and obtained excellent yields.

An expedient and convenient approach for one-pot synthesis of 1H-isoindole-1,3(2H)-diones

An easy and expedient method for the one-pot synthesis of 1H-isoindole-1,3(2H)-diones has been developed by the reaction of the corresponding cyclic anhydrides with guanidinium chloride as a nitrogen source in the presence of FeCl3 as a catalyst under mild reaction conditions.

A facile and convenient synthesis of 1H-isoindole-1,3(2H)-diones

A facile synthesis of 1H-isoindole-1,3(2H)-diones (3a-h) has been developed by the reaction of the corresponding anhydrides (1a-h) with potassium cyanate (4a) or sodium thiocyanate (4b). The reactions were carried out in neutral media under reflux or under microwave irradiation without use of catalyst. Good to excellent yields of the products were obtained in high purity with very simple work-up.{A figure is presented}.

Benzocyclobutenes. Part 4. Synthesis of Benzocyclobutene-1,2-diones by Pyrolytic Methods

Oxidation of the cyclic hydrazides prepared from phthalic anhydrides in the presence of anthracene gives the corresponding Diels-Alder adducts which, on flash vacuum pyrolysis, give benzocyclobutene-1,2-dione (BBD) and its 4-chloro, 3,6- and 4,5-dichloro, 4,5-dibromo, and 4,5-dimethyl derivatives in 75-98percent yield.Cyclobuta- and cyclobuta-naphthalene-1,2-dione as well as cyclobuta- and cyclobuta-pyridine-1,2-dione have been prepared similarly; the last three of these diones are very unstable.Cyclobutanaphthalene-1,2-dione has also been made by pyrolysis of benzindene-1,2,3-trione.Attempts to make thiophen and furan analogues of BBD from appropriate anthracene adducts failed as did attempts to make tetrachloro- and tetrabromo-derivatives of BBD by the pyrolysis of tetrahalogenophthalimidosulphoximides.

Halobenzoyl tetrahalophthalimides

This invention discloses fire retardant chemical compounds of the formula SPC1 Wherein X and Y are each chlorine or bromine and n is an integer from 2 to 5 which are useful in polymeric compositions.