- Equilibrium Dimerization of Phosphorus Triiodide and Its Organic Derivatives in Solutions
-
Iodides of trivalent phosphorus, including phosphorus triiodide, organyldiiodophosphines, and diorganyliodophosphines, display a tendency to equilibrium dimerization in solutions with formation of dimers of a phosphine - phosphonium structure. The ability
- Feschenko,Miroshnichenko
-
-
- Reaction of tert-Butyl- and Phenyldiiodophosphines with Tetrahydrofuran
-
tert-Butyl- and phenyldiiodophosphines react with tetrahydrofuran, yielding tetraorganylcyclotetraphosphine, 1,4-diiodobutane, and oxygen-containing phosphorus compounds. The reaction proceeds via the stage of phosphine - phosphonium dimer formation with subsequent self-reduction of the latter by the halogenophilic mechanism yielding compounds with a P-P bond, diorganyldiiododisphosphines which are further converted to the final products under the action of tetrahydrofuran.
- Miroshnichenko,Feschenko
-
-