24901-19-7Relevant academic research and scientific papers
Equilibrium Dimerization of Phosphorus Triiodide and Its Organic Derivatives in Solutions
Feschenko,Miroshnichenko
, p. 72 - 76 (2007/10/03)
Iodides of trivalent phosphorus, including phosphorus triiodide, organyldiiodophosphines, and diorganyliodophosphines, display a tendency to equilibrium dimerization in solutions with formation of dimers of a phosphine - phosphonium structure. The ability
Reaction of tert-Butyl- and Phenyldiiodophosphines with Tetrahydrofuran
Miroshnichenko,Feschenko
, p. 77 - 79 (2007/10/03)
tert-Butyl- and phenyldiiodophosphines react with tetrahydrofuran, yielding tetraorganylcyclotetraphosphine, 1,4-diiodobutane, and oxygen-containing phosphorus compounds. The reaction proceeds via the stage of phosphine - phosphonium dimer formation with subsequent self-reduction of the latter by the halogenophilic mechanism yielding compounds with a P-P bond, diorganyldiiododisphosphines which are further converted to the final products under the action of tetrahydrofuran.
