- Unsaturated phosphate ester for producing high-slump-retaining type polycarboxylic acid water reducing agent
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The invention relates to unsaturated phosphate ester for producing a high-slump-retaining type polycarboxylic acid water reducing agent. The unsaturated phosphate ester is prepared through the following steps of firstly, performing an esterification reaction on one or a mixture of one or more of the unsaturated acid and the unsaturated acid anhydride, and alcohol; then performing a phosphorylation reaction on the prepared unsaturated acid ester and a bonderite so as to obtain unsaturated phosphate ester; and finally performing a radical polymerization reaction on the prepared phosphate ester, and methyl-2-propen-1-ol or one or a mixture of one or more of TPEG, a chain-transfer agent, unsaturated acid and an unsaturated acid derivative at the room temperature so as to obtain the phosphoric acid base high-slump-retaining type polycarboxylic acid high-performance water reducing agent. The unsaturated phosphate ester disclosed by the invention can be used for synthesizing the water reducing agent, so that the water reducing agent is excellent in properties, and has the advantages of being low in mixing quantity, high in water reducing rate, excellent in slump-retaining capacity, good in adaptability to cement, insensitive to mud content of concrete materials and the like.
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Paragraph 0056
(2017/06/13)
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- Preparation of unsaturated polyesters using boric acid as mild catalyst and their sulfonated derivatives as new family of degradable polymer surfactants
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Boric acid-pyridine mixture is presented as mild catalyst for polycondensation of semi-esters of ethylene glycol, in situ-generated by " cyclic anhydride-diol" reaction scheme from maleic, succinic and phthalic anhydrides. This catalyst system was demonstrated to give colorless polyesters in low molecular weights (Mn: 1650-1950 Da) within 4 h at 130 °C 1H NMR spectra of the polyesters derived from maleic anhydride revealed significant isomerization of maleate groups to fumarate units (~80 %) during the polyesterification. Maleate and fumarate double bonds of the unsaturated polyesters (USP) were demonstrated to add bisulfite ions quantitatively to give sulfonated polyesters. The resulting sulfonated polyesters with 50% and 70% succinate units exhibited relatively narrow size spherical and ellipsoidal micelles in aqueous solutions, as inferred from surface tension, DLS and ESEM measurements. The results showed that, this procedure allows preparing a new family of polymer surfactants with tunable hydrophilicity and degradable polyester backbones.
- Alemdar, Neslihan,Erciyes, A. Tuncer,Bicak, Niyazi
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experimental part
p. 5044 - 5050
(2011/11/14)
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