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Phenothrin is a pale yellow to yellow-brown liquid with a faint characteristic odor. It is a non-corrosive insecticide that is used in various settings and applications.

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  • 26002-80-2 Structure
  • Basic information

    1. Product Name: Phenothrin
    2. Synonyms: (3-Phenoxyphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate;3-Phenoxybenzyl (1R)-cis-trans-chrysanthemate;S-2539forte;d-(cis-trans)-Phenothrin 50mg [26002-80-2];(.+/-.)-Phenoxybenzyl-cis,trans-chrysanthemate;(+)-(z,e)-leste;(+)-cis,trans-phenothrin;(+)-trans,cis-fenothrin
    3. CAS NO:26002-80-2
    4. Molecular Formula: C23H26O3
    5. Molecular Weight: 350.45
    6. EINECS: 247-404-5
    7. Product Categories: Pyrethroids;SUMITHRIN;Alpha sort;Insecticides;N-PAlphabetic;P;PER - POLAPesticides;Pesticides&Metabolites
    8. Mol File: 26002-80-2.mol
  • Chemical Properties

    1. Melting Point: 25°C
    2. Boiling Point: 444.44°C (rough estimate)
    3. Flash Point: 186.6 °C
    4. Appearance: Pale yellow to yellow-brown liquid
    5. Density: d2525 1.06
    6. Refractive Index: nD25 1.5483
    7. Storage Temp.: 0-6°C
    8. Solubility: N/A
    9. Water Solubility: 2mg/L(30 oC)
    10. Stability: Stable. Combustible. Incompatible with strong oxidizing agents. Light sensitive.
    11. BRN: 8788185
    12. CAS DataBase Reference: Phenothrin(CAS DataBase Reference)
    13. NIST Chemistry Reference: Phenothrin(26002-80-2)
    14. EPA Substance Registry System: Phenothrin(26002-80-2)
  • Safety Data

    1. Hazard Codes: Xn,N
    2. Statements: 20/21/22-50/53
    3. Safety Statements: 13-60-61-24-23
    4. RIDADR: UN 3082 9/PG 3
    5. WGK Germany: 3
    6. RTECS: GZ1975000
    7. HazardClass: N/A
    8. PackingGroup: N/A
    9. Hazardous Substances Data: 26002-80-2(Hazardous Substances Data)

26002-80-2 Usage

Uses

Used in Ectoparasiticide Applications:
Phenothrin is used as an ectoparasiticide to control and eliminate parasites that live on the surface of the skin.
Used in Insecticide Applications:
Phenothrin is used as an insecticide to control and eliminate insects in various settings, including commercial and industrial settings, medical institutions, and other institutional settings.
Used in Commercial and Industrial Settings:
Phenothrin is used as an insecticide in commercial and industrial settings to control and eliminate insects that can cause damage to products and equipment.
Used in Medical Institutions:
Phenothrin is used as an insecticide in medical institutions to control and eliminate insects that can spread diseases and cause discomfort to patients.
Used in Greenhouses, Homes, and Gardens:
Phenothrin is used as an insecticide in greenhouses, homes, and gardens to control and eliminate insects that can damage plants and crops.
Used in Recreational Areas:
Phenothrin is used as an insecticide in recreational areas to control and eliminate insects that can cause discomfort and annoyance to people.
Used in Public Health:
Phenothrin is used for vector control for mosquitoes both indoor and outdoor to prevent the spread of diseases.
Used in Agricultural Applications:
Phenothrin is used as an insecticide worldwide to control household insects and protect stored grain. It is frequently formulated with other insecticides and is formulated in a number of carriers (aerosols, oil, dust, emulsifiable concentrates), and in powders, shampoos, and lotions.

Air & Water Reactions

Insoluble in water. Hydrolyzed by alkalis.

Trade name

FORTE?; MULTICIDE-2154?; OMS 1809?; OMS 1810?; PHENOXYTHRIN?; PT-515; S-2539?; SUMETHRIN?; SUMITHRIN?; WELLCIDE? Note: The U.S. EPA currently lists 724 active or canceled products, 242 of which are active. Most products are for residential flying insect control, e.g., fleas, wasps, flies, mosquitoes. Not approved for use in EU countries[115]. Registered for use in the U.S. and Canada

Synthesis

Commercially available chrysanthemic acid (231) was converted to the corresponding acyl chloride 232 in 99% yield. Further condensation with 3- phenoxyphenyl methanol (233) in pyridine provided phenothrin (XXVIII) in 96% yield.

Potential Exposure

d-Phenenothrin is a pyrethroid insecticide whic is used world-wide to control household insects and to protect stored grain. It is frequently formulated with other insecticides and is formulated in a number of carriers (aerosols, oil, dust, emulsifiable concentrates), and in powders, shampoos and lotion.

Environmental Fate

Routes and pathways relevant physicochemical Phenothrin is a pale yellow to brown clear liquid with a faint characteristic odor. Its reported solubility is very low<9.7 mg l-1 at 25 °C. It has a low vapor pressure of 1.43 × 10-7 mmHg at 21 C, and a calculated Henry’s Law constant of 6.80  10-6 atm-m3 mol-1. The octanol/water partition coefficient for phenothrin is 1.03 × 106 (log Kow ? 6.01 at 20 °C).

Shipping

UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. UN3349 Pyrethroid pesticide, solid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN3352 Pyrethroid pesticide, liquid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Toxicity evaluation

Acute oral LD50 for rats: >5,000 mg/kg

Incompatibilities

Keep away from alkaline materials. May react violently with strong oxidizers, bromine, 90% hydrogen peroxide, phosphorus trichloride, silver powders or dust. Incompatible with silver compounds. Mixture with some silver compounds forms explosive salts of silver oxalate. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur).

Waste Disposal

Incineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers

Check Digit Verification of cas no

The CAS Registry Mumber 26002-80-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,6,0,0 and 2 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 26002-80:
(7*2)+(6*6)+(5*0)+(4*0)+(3*2)+(2*8)+(1*0)=72
72 % 10 = 2
So 26002-80-2 is a valid CAS Registry Number.

26002-80-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name phenothrin

1.2 Other means of identification

Product number -
Other names 3-phenoxybenzyl (1RS,3RS

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:26002-80-2 SDS

26002-80-2Relevant articles and documents

Cobalt-Catalyzed Reductive Dimethylcyclopropanation of 1,3-Dienes

Werth, Jacob,Uyeda, Christopher

, p. 13902 - 13906 (2018/10/02)

Dimethylcyclopropanes are valuable synthetic targets that are challenging to access in high yield using Zn carbenoid reagents. Herein, we describe a cobalt-catalyzed variant of the Simmons–Smith reaction that enables the efficient dimethylcyclopropanation of 1,3-dienes using a Me2CCl2/Zn reagent mixture. The reactions proceed with high regioselectivity based on the substitution pattern of the 1,3-diene. The products are vinylcyclopropanes, which serve as substrates for transition-metal-catalyzed ring-opening reactions, including 1,3-rearrangement and [5+2] cycloaddition. Preliminary studies indicate that moderately activated monoalkenes are also amenable to dimethylcyclopropanation under the conditions of cobalt catalysis.

Method for producing cyclopropanecarboxylates

-

, (2008/06/13)

There is disclosed a method for producing cyclopropanecarboxylates of the formula (3): by transesterification in the presence of a lanthanoid metal alkoxide

Process for producing cyclopropanecarboxylates

-

, (2008/06/13)

There is disclosed a process process for producing a cyclopropanecarboxylate of formula (1): 1which process comprises reacting cyclopropanecarboxylic acid of formula (2): 2with a monohydroxy compound of formula (3): R6OH??(3),in the presence of a catalyst compound comprising an element of to Group 4 of the Periodic Table of Elements.

Asymmetric copper complex and cyclopropanation reaction using the same

-

, (2008/06/13)

There are disclosed asymmetric copper complex comprising, as components, (a) an optically active bisoxazoline compound of formula (1): wherein R1 and R2 are different and each represent a hydrogen atom, an alkyl group, a cycloalkyl group, or a phenyl or aralkyl group which may be substituted, R3 and R4 each represent a hydrogen atom, an alkyl group, a cycloalkyl group, or a phenyl or aralkyl group which may be substituted, or R3 and R4 may be bonded to each other to form a C3-5 cyclic alkylene group, R5 represents a hydrogen atom or a C1-6 alkyl group, or the two R5 groups may be bonded to each other to represent a C3-5 cyclic alkylene group, (b) a monovalent or divalent copper compound, and (c) a strong acid or a Lewis acid or a mixture thereof, and a process for producing an optically active cyclopropanecarboxylate using the same.

Monoclonal antibodies to synthetic pyrethroids and method for detecting the same

-

, (2008/06/13)

Methods are described for making specific monoclonal antibodies which may be used in a sensitive immunoassay for detection of synthetic pyrethroids in foods and environmental samples. Appropriate sample preparation and enzyme amplification of the immunoassay for this widely-used class of pesticides permits detection at low levels in laboratory and field tested samples.

Insecticidal resin coating film

-

, (2008/06/13)

An insecticidal resin coating film comprising a combination of an acrylonitrile and/or methacrylonitrile copolymer resin and an insecticidal component selected from the group consisting of specified compounds exhibits an insecticidal effect, since the compound is kept on the surface of the coating film in a state capable of exhibiting its insecticidal effect for a long period of time.

Process for preparing cyclopropane-carboxylic acid esters

-

, (2008/06/13)

A process for preparing an organic acid ester of the formula (I), EQU1 wherein R1 is a hydrogen atom or a methyl group, R2 is a methyl group, a vinyl group, a 2,2-dichlorovinyl group, a 1-propenyl group, a 2-methyl-1-propenyl group, a 2-carbomethoxy-1-propenyl group, a 2-methoxymethyl-1-propenyl group, a 1,3-butadienyl group, a 2-methyl-1,3-butadienyl group or a cyclopentylidenemethyl group when R1 is a hydrogen atom, and R2 is a methyl group when R1 is a methyl group; which comprises reacting an acid of the formula (II), EQU2 wherein R1 and R2 are each as defined above, or its reactive derivative, or mixture of the acid and its reactive derivative with a quaternary ammonium salt of the formula (III), SPC1 wherein X is a halogen atom, A is an alkylamine, pyridine or an N-alkylaniline.

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