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Oxalyl chloride
Cas No: 79-37-8
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High quality 79-37-8 Oxalyl chloride
Cas No: 79-37-8
USD $ 1300.0-1600.0 / Kilogram 1 Kilogram 99999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
High quality Oxalyl chloride supplier in China
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Oxalyl chloride
Cas No: 79-37-8
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Oxalyl chloride 79-37-8
Cas No: 79-37-8
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Oxalyl chloride
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Oxalyl Chloride manufaturer
Cas No: 79-37-8
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Oxalyl chloride
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Factory supply Oxalyl chloride
Cas No: 79-37-8
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Amadis Chemical offer CAS#79-37-8;CAT#A839666
Cas No: 79-37-8
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier

79-37-8 Usage

Production Methods

Oxalyl Chloride, ClCOCOCl, mol wt 126.9, is produced by the reaction of anhydrous oxalic acid and phosphorus pentachloride.

Safety Profile

Poison. Violently decomposed by water and alcohol. Severe irritant to skin, eyes, respiratory tract. Explodeson contact with dimethyl sulfoxide. Forms shock-sensitive explosive mixtures with potassium or with K-Na alloy. Will react with water or steam to

Uses

Oxalyl Chloride is used in the preparation of cardiolipin analogs which induce peroxidase activity by Cytochrome C. It is also used in the preparation of fluorescent indicators for cytosolic calcium.

Reactions

Oxalyl Chloride vigorously reacts with water, alcohols, and amines, and is employed for the synthesis of agrochemicals, pharmaceuticals, and fine chemicals.

Chemical Properties

colourless liquid with a pungent odour
InChI:InChI=1/C2Cl2O2/c3-1(5)2(4)6

79-37-8 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (O0082)  Oxalyl Chloride  >98.0%(GC)(T) 79-37-8 25g 200.00CNY Detail
TCI America (O0082)  Oxalyl Chloride  >98.0%(GC)(T) 79-37-8 100g 450.00CNY Detail
TCI America (O0082)  Oxalyl Chloride  >98.0%(GC)(T) 79-37-8 500g 995.00CNY Detail
Alfa Aesar (H31617)  Oxalyl chloride, 2M soln. in dichloromethane    79-37-8 100ml 651.0CNY Detail
Alfa Aesar (H31617)  Oxalyl chloride, 2M soln. in dichloromethane    79-37-8 500ml 1500.0CNY Detail
Alfa Aesar (A18012)  Oxalyl chloride, 98%    79-37-8 50g 314.0CNY Detail
Alfa Aesar (A18012)  Oxalyl chloride, 98%    79-37-8 100g 561.0CNY Detail
Alfa Aesar (A18012)  Oxalyl chloride, 98%    79-37-8 250g 1108.0CNY Detail
Alfa Aesar (A18012)  Oxalyl chloride, 98%    79-37-8 1000g 4100.0CNY Detail
Aldrich (221015)  Oxalylchloride  ReagentPlus®, ≥99% 79-37-8 221015-5G 238.68CNY Detail
Aldrich (221015)  Oxalylchloride  ReagentPlus®, ≥99% 79-37-8 221015-25G 644.67CNY Detail
Aldrich (221015)  Oxalylchloride  ReagentPlus®, ≥99% 79-37-8 221015-100G 1,708.20CNY Detail

79-37-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Oxalyl Chloride

1.2 Other means of identification

Product number -
Other names oxalyl dichloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:79-37-8 SDS

79-37-8Synthetic route

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

A

oxalyl dichloride
79-37-8

oxalyl dichloride

B

chloroethane
75-00-3

chloroethane

C

1,2-diethoxy-tetrachloro-ethane
63938-37-4

1,2-diethoxy-tetrachloro-ethane

D

ethoxy-dichloro-acetyl chloride
98019-44-4

ethoxy-dichloro-acetyl chloride

E

Ethyl oxalyl chloride
4755-77-5

Ethyl oxalyl chloride

Conditions
ConditionsYield
With phosphorus pentachloride; manganese(ll) chloride at 90℃; for 5h; Product distribution; other catalysts (CuCl2, ZnCl2, CdCl2, CrCl3, FeCl3, CoCl2, PdCl2) and temperatures (from 70 to 130 deg C);A n/a
B n/a
C n/a
D n/a
E 83.7%
4-fluoroanthranilic acid
446-32-2

4-fluoroanthranilic acid

oxalyl dichloride
79-37-8

oxalyl dichloride

Conditions
ConditionsYield
In formamide at 150℃; for 6h;82%
tetrachloro-1,4-dioxin
133349-02-7

tetrachloro-1,4-dioxin

A

oxalyl dichloride
79-37-8

oxalyl dichloride

B

2,3-epoxy-2,3,5,6-tetrachloro-2,3-dihydro-1.4-dioxin
133349-07-2

2,3-epoxy-2,3,5,6-tetrachloro-2,3-dihydro-1.4-dioxin

C

phosgene

phosgene

Conditions
ConditionsYield
With oxygen at 28 - 40℃; under 500 - 600 Torr;A n/a
B 32%
C n/a
With oxygen at 28 - 40℃; under 500 - 600 Torr;A n/a
B 32%
C n/a
pyridine
110-86-1

pyridine

bis(trichloromethyl) oxalate
98020-90-7

bis(trichloromethyl) oxalate

chlorobenzene
108-90-7

chlorobenzene

A

phosgene
75-44-5

phosgene

B

oxalyl dichloride
79-37-8

oxalyl dichloride

1,2-diethoxy-tetrachloro-ethane
63938-37-4

1,2-diethoxy-tetrachloro-ethane

A

oxalyl dichloride
79-37-8

oxalyl dichloride

B

chloroethane
75-00-3

chloroethane

C

ethoxy-dichloro-acetyl chloride
98019-44-4

ethoxy-dichloro-acetyl chloride

Conditions
ConditionsYield
at 165℃;
bis(trichloromethyl) oxalate
98020-90-7

bis(trichloromethyl) oxalate

oxalyl dichloride
79-37-8

oxalyl dichloride

Conditions
ConditionsYield
With pyridine; chlorobenzene
oxalic acid
144-62-7

oxalic acid

oxalyl dichloride
79-37-8

oxalyl dichloride

Conditions
ConditionsYield
With phosphorus pentachloride; trichlorophosphate
With phosphorus pentachloride
With phosphorus pentachloride
oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

oxalyl dichloride
79-37-8

oxalyl dichloride

Conditions
ConditionsYield
With phosphorus pentachloride beim Erhitzen;
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

oxalyl dichloride
79-37-8

oxalyl dichloride

Conditions
ConditionsYield
With pyridine; osmium(VIII) oxide 1) n-hexane, r.t., 2) 150 deg C; Yield given. Multistep reaction;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

oxalic acid
144-62-7

oxalic acid

oxalyl dichloride
79-37-8

oxalyl dichloride

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

oxalyl dichloride
79-37-8

oxalyl dichloride

CO

CO

oxalyl dichloride
79-37-8

oxalyl dichloride

Conditions
ConditionsYield
With pumice stone; chlorine at 200℃; under 147102 Torr;
With metal halide; chlorine at 200℃; under 147102 Torr;
With chlorine; pyrographite at 200℃; under 147102 Torr;
phosgene
75-44-5

phosgene

CO

CO

oxalyl dichloride
79-37-8

oxalyl dichloride

Conditions
ConditionsYield
With pyrographite at 200℃; under 147102 Torr;
With pumice stone at 200℃; under 147102 Torr;
With metal halide at 200℃; under 147102 Torr;
2,3-dichloro-5,6-difluoro-1,4-dioxin
133349-04-9

2,3-dichloro-5,6-difluoro-1,4-dioxin

A

oxalyl dichloride
79-37-8

oxalyl dichloride

B

Carbonyl fluoride
353-50-4

Carbonyl fluoride

C

oxalyl difluoride
359-40-0

oxalyl difluoride

D

C3Cl2F2O3

C3Cl2F2O3

E

C3Cl2F2O3

C3Cl2F2O3

F

C4Cl2F2O3

C4Cl2F2O3

G

COCl2, low oligomers

COCl2, low oligomers

Conditions
ConditionsYield
With oxygen
Trichloroethylene
79-01-6

Trichloroethylene

A

dichloroacethyl chloride
79-36-7

dichloroacethyl chloride

B

oxalyl dichloride
79-37-8

oxalyl dichloride

C

chloral
75-87-6

chloral

D

1,1,2-trichloroethan-2-ol
13287-89-3

1,1,2-trichloroethan-2-ol

Conditions
ConditionsYield
With BaY-coated optical fibers; oxygen Product distribution; Solid phase reaction; Oxidation; Irradiation;
7-hydroxy-3H-phenoxazin-3-one sodium salt
34994-50-8

7-hydroxy-3H-phenoxazin-3-one sodium salt

levulinic acid
123-76-2

levulinic acid

oxalyl dichloride
79-37-8

oxalyl dichloride

Conditions
ConditionsYield
With triethylamine In dichloromethane; water
3-(tert-butoxycarbonylmethyl)bicyclo[1.1.1]pentane-1-carboxylic acid
1113001-76-5

3-(tert-butoxycarbonylmethyl)bicyclo[1.1.1]pentane-1-carboxylic acid

oxalyl dichloride
79-37-8

oxalyl dichloride

3-(tert-butyloxycarbonyl)bicyclo[1.1.1]pentane-1-carboxylic acid

3-(tert-butyloxycarbonyl)bicyclo[1.1.1]pentane-1-carboxylic acid

oxalyl dichloride
79-37-8

oxalyl dichloride

Conditions
ConditionsYield
With triethylamine; trifluoroacetic acid In tetrahydrofuran; [(2)H6]acetone; n-heptane; dichloromethane
indole
120-72-9

indole

oxalyl dichloride
79-37-8

oxalyl dichloride

indolyl-3-glyoxylyl chloride
22980-09-2

indolyl-3-glyoxylyl chloride

Conditions
ConditionsYield
In diethyl ether for 0.416667h;100%
In tetrahydrofuran at 0℃;93%
In diethyl ether at -20℃; for 18h;93%
4-nitro-phenol
100-02-7

4-nitro-phenol

oxalyl dichloride
79-37-8

oxalyl dichloride

p-Nitrophenyl chloroglyoxylate
78974-67-1

p-Nitrophenyl chloroglyoxylate

Conditions
ConditionsYield
for 20h; Heating;100%
for 16h; Heating;
oxalyl dichloride
79-37-8

oxalyl dichloride

2,3-dihydro-2,2-dimethyl-7-benzofuranol methylcarbamate
1563-66-2

2,3-dihydro-2,2-dimethyl-7-benzofuranol methylcarbamate

Chlorooxalyl-methyl-carbamic acid 2,2-dimethyl-2,3-dihydro-benzofuran-7-yl ester
88241-19-4

Chlorooxalyl-methyl-carbamic acid 2,2-dimethyl-2,3-dihydro-benzofuran-7-yl ester

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 80℃;100%
oxalyl dichloride
79-37-8

oxalyl dichloride

4H-1,2,9,10-tetramethoxy-5,6-dihydrodibenzo[de,g]quinoline
39945-38-5

4H-1,2,9,10-tetramethoxy-5,6-dihydrodibenzo[de,g]quinoline

isatine
78178-94-6

isatine

Conditions
ConditionsYield
100%
oxalyl dichloride
79-37-8

oxalyl dichloride

Ethyl isothiocyanate
542-85-8

Ethyl isothiocyanate

2,2-Dichloro-3-ethyl-thiazolidine-4,5-dione
91466-84-1

2,2-Dichloro-3-ethyl-thiazolidine-4,5-dione

Conditions
ConditionsYield
Ambient temperature;100%
oxalyl dichloride
79-37-8

oxalyl dichloride

methyl N-propylcarbamate
35601-83-3

methyl N-propylcarbamate

3-isopropyloxazolidine-2,4,5-trione
91467-24-2

3-isopropyloxazolidine-2,4,5-trione

Conditions
ConditionsYield
for 48h; Ambient temperature;100%
oxalyl dichloride
79-37-8

oxalyl dichloride

(-)-menthol
2216-51-5

(-)-menthol

2-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)-2-oxoacetic acid
70894-19-8

2-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)-2-oxoacetic acid

Conditions
ConditionsYield
Stage #1: oxalyl dichloride; (-)-menthol In diethyl ether at 0 - 23℃; for 1.5h; Inert atmosphere;
Stage #2: With water In diethyl ether at 0 - 23℃; Inert atmosphere;
100%
1) CH2Cl2, room temperature, 2) hydrolysis; Multistep reaction;
In diethyl ether; dichloromethane at 0 - 20℃; for 18h;
oxalyl dichloride
79-37-8

oxalyl dichloride

[2.2]Paracyclophan
1633-22-3

[2.2]Paracyclophan

<2.2>Paracyclophan-4-glyoxylsaeurechlorid
108869-36-9

<2.2>Paracyclophan-4-glyoxylsaeurechlorid

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane at -10℃; for 0.166667h;100%
With aluminum (III) chloride at -10 - 5℃; for 0.333333h;100%
With aluminum (III) chloride In dichloromethane at -20 - -10℃; for 0.333333h;
With aluminum (III) chloride In dichloromethane at -5℃;
With aluminum (III) chloride at -10 - 5℃; for 0.333333h;
oxalyl dichloride
79-37-8

oxalyl dichloride

4'-methoxy-2,6-dichloro-4-methoxydiphenylamine
127792-36-3

4'-methoxy-2,6-dichloro-4-methoxydiphenylamine

N-(4-methoxyphenyl)-N-(2',6'-dichloro-4'-methoxyphenyl)oxaniloyl chloride
127792-37-4

N-(4-methoxyphenyl)-N-(2',6'-dichloro-4'-methoxyphenyl)oxaniloyl chloride

Conditions
ConditionsYield
In benzene for 2h; Ambient temperature;100%
oxalyl dichloride
79-37-8

oxalyl dichloride

2,3-diamino-1,4-naphthoquinone
13755-95-8

2,3-diamino-1,4-naphthoquinone

1,4-dihydro-benzo[g]quinoxaline-2,3,5,10-tetraone
7029-90-5

1,4-dihydro-benzo[g]quinoxaline-2,3,5,10-tetraone

Conditions
ConditionsYield
100%
oxalyl dichloride
79-37-8

oxalyl dichloride

(difluoroamino)difluoroacetamidoxime
115983-87-4

(difluoroamino)difluoroacetamidoxime

O-oxalylbis<(difluoroamino)difluoroacetamidoxime>
129177-46-4

O-oxalylbis<(difluoroamino)difluoroacetamidoxime>

Conditions
ConditionsYield
In diethyl ether 1. -20 deg C, 0.5 h 2. 25 deg C, 0.5 h;100%
oxalyl dichloride
79-37-8

oxalyl dichloride

2-[2-(3,4-Dimethoxy-phenyl)-ethylamino]-cyclohept-1-enecarboxylic acid ethyl ester
130655-37-7

2-[2-(3,4-Dimethoxy-phenyl)-ethylamino]-cyclohept-1-enecarboxylic acid ethyl ester

1-[2-(3,4-Dimethoxy-phenyl)-ethyl]-2,3-dioxo-2,3,4,5,6,7-hexahydro-1H-cyclohepta[b]pyrrole-3a-carboxylic acid ethyl ester
130655-38-8

1-[2-(3,4-Dimethoxy-phenyl)-ethyl]-2,3-dioxo-2,3,4,5,6,7-hexahydro-1H-cyclohepta[b]pyrrole-3a-carboxylic acid ethyl ester

Conditions
ConditionsYield
In benzene at 0℃; for 0.666667h;100%
In benzene for 1h;
oxalyl dichloride
79-37-8

oxalyl dichloride

8-[2-(3,4-Dimethoxy-phenyl)-ethylamino]-1,4-dioxa-spiro[4.5]dec-7-ene-7-carboxylic acid ethyl ester
130655-26-4

8-[2-(3,4-Dimethoxy-phenyl)-ethylamino]-1,4-dioxa-spiro[4.5]dec-7-ene-7-carboxylic acid ethyl ester

C23H27NO8
77793-25-0

C23H27NO8

Conditions
ConditionsYield
In benzene at 0℃; for 0.5h;100%

79-37-8Downstream Products

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