261619-89-0Relevant articles and documents
Highly selective β-hydride elimination in Pd-catalyzed decarboxylative heck-type reaction
Huang, Liangbin,Qi, Ji,Wu, Xia,Huang, Kefan,Jiang, Huanfeng
supporting information, p. 2330 - 2333 (2013/06/27)
A variety of β-aryl ketones and aldehydes were facilely synthesized via a Pd(II)/Ag2CO3-mediated decarboxylative Heck type reaction between readily available benzoic acid derivatives and allylic alcohols under mild conditions. The control experiments indicated that this transformation may proceed via a hydrogen migration process.
Friedel-crafts reaction of activated benzene rings with captodative and electron-deficient alkenes. A one-step synthesis of the natural product methyl 3-(2,4,5-trimethoxyphenyl)propionate
Aguilar, Raul,Benavides, Adriana,Tamariz, Joaquin
, p. 2719 - 2735 (2007/10/03)
Electrophilic aromatic substitution of activated benzenes with the captodative olefin 1-acetylvinyl-1-p-nitrobenzoate (9), and with the electron-deficient alkenes methyl acrylate (8a), methylvinylketone (8b), and acrolein (8c) were evaluated under Lewis a