261760-97-8

Basic information

• Product Name: 1,2,4-TRICHLORO-1,1,2-TRIFLUOROBUTANE
• Synonyms: 1,2,4-TRICHLORO-1,1,2-TRIFLUOROBUTANE
• CAS NO: 261760-97-8
• Molecular Formula: C4H4Cl3F3
• Molecular Weight: 215.43
• Mol File: 261760-97-8.mol

Chemical Properties

• Boiling Point: 134-136°C
• Appearance: /
• Density: 1.484±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1,2,4-TRICHLORO-1,1,2-TRIFLUOROBUTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,4-TRICHLORO-1,1,2-TRIFLUOROBUTANE(261760-97-8)
• EPA Substance Registry System: 1,2,4-TRICHLORO-1,1,2-TRIFLUOROBUTANE(261760-97-8)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• HazardClass: IRRITANT
• Hazardous Substances Data: 261760-97-8(Hazardous Substances Data)

Usage

Physical state

Colorless, flammable liquid

Uses

a. Refrigerant
b. Solvent
c. Blowing agent in the production of foams
d. Propellant in aerosol products

Environmental impact

a. High global warming potential
b. Considered a greenhouse gas
c. Potential ozone-depleting substance
d. Regulated under the Montreal Protocol

Health hazards

a. Central nervous system depression
b. Cardiac arrhythmias
c. Respiratory irritation

Regulatory status

Hazardous air pollutant

Efforts to reduce use

a. Finding alternative compounds for various applications
b. Reducing environmental and health impacts

Upstream product

• 235106-11-3 4-chloro-1,1,2-trifluorobut-1-ene 
• 234096-23-2 4-bromo-1,2-dichloro-1,1,2-trifluorobutane 
• 74-85-1 ethene 
• 76-13-1 1,1,2-Trichloro-1,2,2-trifluoroethane 

Downstream Products

• 235106-11-3 4-chloro-1,1,2-trifluorobut-1-ene 

Relevant articles and documents

Method for synthesizing 4 -halo -1, 1 and 2 -trifluoro -1 -butene (by machine translation)

The invention discloses a method for synthesizing 4 -halo -1, 1 and 2 -trifluoro -1 -butene. , Polyhaloethane is synthesized by reaction of chlorotrifluoroethylene with halogen, and then polyhalogenated ethane is reacted with ethylene under the action of a catalyst to synthesize polyhalogenated butane, and finally, 4 - halogenated -1, 1 and 2 -trifluoro -1 -butene are dehalogenated under the action of a reducing agent. The method has the characteristics of simple synthesis method, high product purity and low preparation cost. (by machine translation)

Rearrangement of 3-membered 1,1,2-trifluorobromonium and iodonium ions and comparison of trifluorochloronium to fluorocarbenium ions

(Chemical Equation Presented) Reactions of chlorine (Cl2) with 4-halo-1,1,2-trifluorobut-1-enes (1, 2, or 3) give open-ion intermediates A and E that are in equilibrium. The open-chloronium ions (E) rearrange to a five-membered-ring halonium ion during ionic chlorination of 3 when the number-4 halo-substituent is iodine. Three-membered-ring bromonium and iodonium ions from alkenes 1, 2, or 3 are rather symmetrical and similar in structure. Quantum chemical calculations show that five-membered-ring halonium ion intermediates are 11 to 27 kcal/mol more stable than the three-membered-ring halonium ions or the open-ions A and E. The five-membered-ring intermediates lead to rearranged products. Rearranged products increase as the number-4 halogen (Z) becomes more nucleophilic (Z: Cl Br I). Open chloronium ions from ionic chlorination of terminal fluorovinyl alkenes are compared to the open ions generated by protons to similar alkenes.