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Product FOB Price Min.Order Supply Ability Supplier
Ethylene
Cas No: 74-85-1
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 100 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
ETHYLENE
Cas No: 74-85-1
No Data 1 Kilogram Metric Ton/Day Henan Allgreen Chemical Co.,Ltd Contact Supplier
Ethylene
Cas No: 74-85-1
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Ethene
Cas No: 74-85-1
USD $ 4.0-10.0 / Gram 10 Gram 1000 Metric Ton/Week HUBEI AOKS BIO-TECH CO.,LTD Contact Supplier
high purity 99.99% Ethylene CAS:74-85-1, C2H4
Cas No: 74-85-1
No Data 100 Kilogram 10000 Metric Ton/Month Changchun Artel lmport and Export trade company Contact Supplier
Top sale 74-85-1 ETHYLENE with best price
Cas No: 74-85-1
USD $ 1000.0-1500.0 / Kilogram 1 Kilogram 100 Metric Ton/Month Hebei Guanlang Biotechnology Co., Ltd. Contact Supplier
High quality Ethylene cas 74-85-1
Cas No: 74-85-1
USD $ 100.0-150.0 / Kilogram 1 Kilogram 1000 Metric Ton/Day Wuhan Monad Medicine Tech Co.,LTD Contact Supplier
ETHYLENE
Cas No: 74-85-1
USD $ 1.0-1.0 / Gram 1 Gram 300 Metric Ton/Month Jilin Tely Imp.& Exp.Co., Ltd. Contact Supplier
Ethylene
Cas No: 74-85-1
No Data No Data 1-10 Metric Ton/Month Shandong Hanjiang Chemical Co., Ltd. Contact Supplier
High Quality ETHYLENE
Cas No: 74-85-1
USD $ 1.0-1.0 / Gram 1 Gram 3000 Metric Ton/Year Qingdao Sigma Chemical Co., Ltd. Contact Supplier

74-85-1 Usage

Purification Methods

Purify ethylene by passage through a series of towers containing molecular sieves or anhydrous CaSO4 or a cuprous ammonia solution, then conc H2SO4, followed by KOH pellets. Alternatively, it has been condensed in liquid nitrogen, with melting, freezing and pumping to remove air before passage through an activated charcoal trap, followed by a further condensation in liquid air. A sputtered sodium trap was used to remove oxygen. [Beilstein 1 IV 677.]

Health Hazard

Moderate concentration in air causes drowsiness, dizziness, and unconsciousness. Overexposure causes headache, drowsiness, muscular weakness.

Uses

Oxyethylene welding and cutting metals; manufacture of alcohol, mustard gas, and many other organics. manufacture of ethylene oxide (for plastics), "Polythene", polystyrene and other plastics. Plant growth regulator; used commercially to accelerate the ripening of various fruits.

Air & Water Reactions

Highly flammable.

Chemical Properties

colourless gas

General Description

A colorless gas with a sweet odor and taste. ETHYLENE is lighter than air. ETHYLENE is easily ignited and a flame can easily flash back to the source of the leak. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. Can cause explosion.

Reactivity Profile

Peroxidizable monomer may initiate exothermic polymerization of the bulk material [Bretherick 1979. p. 160]. ETHYLENE in the presence of aluminum chloride may undergo a violent reaction [J. Inst. Pet. 33:254. 1947]. Ozone and ETHYLENE react explosively [Berichte 38:3837]. ETHYLENE can polymerize at low pressure if catalyzed by titanium halides. (Sundaram, K. M, M. M. Shreehan, E. F. Olszewski. thylene. Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. 2001.)
InChI:InChI=1/C2H4/c1-2/h1-2H2

74-85-1 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (03484)  Ethylene  ≥99.9% 74-85-1 03484-3.2KG 23,318.10CNY Detail
Sigma-Aldrich (03482)  Ethylene  purum, ≥99.9% 74-85-1 03482-700G 5,955.30CNY Detail
Aldrich (536164)  Ethylene  99.99% 74-85-1 536164-110G 9,605.70CNY Detail

74-85-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name ethene

1.2 Other means of identification

Product number -
Other names Ethen

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Fuels and fuel additives,Intermediates,Processing aids, specific to petroleum production
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:74-85-1 SDS

74-85-1Synthetic route

ethanol
64-17-5

ethanol

ethene
74-85-1

ethene

Conditions
ConditionsYield
With mesoporous silica MCM-4l/Al at 399.84℃; under 21.0021 - 94.5095 Torr; for 50h; Inert N2;100%
With H-USY zeolite at 299.84℃; under 760.051 Torr; for 1.5h; Catalytic behavior; Reagent/catalyst; Time; Temperature; Inert atmosphere; Flow reactor;100%
With water at 380℃; under 1500.15 Torr; Reagent/catalyst;99%
oxirane
75-21-8

oxirane

dipropylphosphinous iodide
81373-58-2

dipropylphosphinous iodide

A

ethene
74-85-1

ethene

B

2-iodoethyl dipropylphosphinate

2-iodoethyl dipropylphosphinate

Conditions
ConditionsYield
In dichloromethane for 1h; Yields of byproduct given;A n/a
B 100%
oxirane
75-21-8

oxirane

iodo-diphenyl-phosphine
20472-52-0

iodo-diphenyl-phosphine

A

ethene
74-85-1

ethene

B

2-iodoethyl diphenylphosphinate

2-iodoethyl diphenylphosphinate

Conditions
ConditionsYield
In dichloromethane for 1h; Yields of byproduct given;A n/a
B 100%
5-cyclopentylidene-2,2-dimethyl-1,3-dioxane-4,6-dione
3968-30-7

5-cyclopentylidene-2,2-dimethyl-1,3-dioxane-4,6-dione

A

butatriene
2873-50-9

butatriene

B

ethene
74-85-1

ethene

C

carbon dioxide
124-38-9

carbon dioxide

D

cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

E

acetone
67-64-1

acetone

F

benzene
71-43-2

benzene

Conditions
ConditionsYield
With variation of temp. at 550℃; Product distribution;A 4%
B 11.9%
C 100%
D 39.2%
E 101.9 %
F 3.3%
diallyl sulphide
592-88-1

diallyl sulphide

A

2,5-dihydro-thiophene
1708-32-3

2,5-dihydro-thiophene

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With tungsten In octane; chlorobenzene at 80℃; for 1h;A 100%
B n/a
With chloroaryloxide neopentylidene complex of tungsten (1)A 90%
B n/a
(2,6-Ph2C6H3O)2W(Cl)=CHC(CH3)3*OEt2 In chlorobenzene at 80℃; for 3h;A 88%
B n/a
phenyl propionate
637-27-4

phenyl propionate

A

ethene
74-85-1

ethene

B

pentan-3-one
96-22-0

pentan-3-one

C

phenol
108-95-2

phenol

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); triphenylphosphine at 54℃; for 20h; Product distribution; Rate constant; Thermodynamic data; other solvents, reagents, reagents ratio, time, temperature; activation energy, ΔH<*>, ΔS<*>;A 100%
B n/a
C 100%
ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

ethene
74-85-1

ethene

Conditions
ConditionsYield
With trifluoroacetic acid at 120℃;100%
Allyl ether
557-40-4

Allyl ether

A

2,5-dihydrofuran
1708-29-8

2,5-dihydrofuran

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With tungsten In octane; chlorobenzene at 80℃; for 2h;A 100%
B n/a
With Grubbs catalyst first generation In dichloromethane
3-allylsulfanyl-2-methyl-propene
83044-85-3

3-allylsulfanyl-2-methyl-propene

A

3-methyl-2,5-dihydro-thiophene
42855-50-5

3-methyl-2,5-dihydro-thiophene

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With tungsten In octane; chlorobenzene at 80℃; for 1h;A 100%
B n/a
2-phenylethanol
60-12-8

2-phenylethanol

ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

A

ethene
74-85-1

ethene

B

trimethyl(phenethyloxy)silane
14629-58-4

trimethyl(phenethyloxy)silane

Conditions
ConditionsYield
hydrogenchloride; chlorobis(ethylene)rhodium(I) dimer In 1,4-dioxane; chloroform at 20℃; for 2h; Product distribution / selectivity;A n/a
B 100%
chlorobis(cyclooctene)rhodium(I) dimer In toluene at 70℃; for 3h; Product distribution / selectivity;A n/a
B 100%
hydrogenchloride; chlorobis(cyclooctene)rhodium(I) dimer In 1,4-dioxane; chloroform at 20℃; for 2h; Product distribution / selectivity;A n/a
B 96%
ethanol
64-17-5

ethanol

dimethylphenylvinylsilane
1125-26-4

dimethylphenylvinylsilane

A

ethene
74-85-1

ethene

B

dimethyl(ethoxy)phenylsilane
1825-58-7

dimethyl(ethoxy)phenylsilane

Conditions
ConditionsYield
hydrogenchloride; chlorobis(cyclooctene)rhodium(I) dimer In 1,4-dioxane; chloroform at 20℃; for 18h; Kinetics;A n/a
B 100%
isopropyl alcohol
67-63-0

isopropyl alcohol

dimethylphenylvinylsilane
1125-26-4

dimethylphenylvinylsilane

A

ethene
74-85-1

ethene

B

dimethyl(isopropoxy)phenylsilane
17988-21-5

dimethyl(isopropoxy)phenylsilane

Conditions
ConditionsYield
hydrogenchloride; chlorobis(cyclooctene)rhodium(I) dimer In 1,4-dioxane; chloroform at 20℃; for 24h; Kinetics;A n/a
B 100%
tris(1,10-phenanthroline)iron(III)
13479-49-7

tris(1,10-phenanthroline)iron(III)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

A

ethane
74-84-0

ethane

B

ethene
74-85-1

ethene

C

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
With oxygen In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(phen)3(3+) in presence of O2 at 298 K; monitored by (1)H-NMR;A <1
B <1
C 100%
In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(phen)3(3+) at 298 K; monitored by (1)H-NMR;A <1
B <1
C 98%
tris(2,2'-bipyridine)iron(III) ion
18661-69-3

tris(2,2'-bipyridine)iron(III) ion

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

A

ethane
74-84-0

ethane

B

ethene
74-85-1

ethene

C

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(bpy)3(3+) at 298 K; monitored by (1)H-NMR;A <1
B <1
C 100%
diethylbis(triethylphosphine)platinum(II)
75847-39-1, 76189-28-1

diethylbis(triethylphosphine)platinum(II)

A

(ethylene)bis(triethylphosphine)platinum(0)
76136-93-1

(ethylene)bis(triethylphosphine)platinum(0)

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
In cyclohexane Pt-complex evacuated to 0.1 torr, flushed with Ar, dry degassed cyclohexane added, cooled (liq. N2), evacuated (0.1 torr), sealed, warmed to room temp., heated at 118°C (oil bath) for 30 min;A 100%
B 0%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

tetrakis(triphenylphosphine)nickel(0)
15133-82-1

tetrakis(triphenylphosphine)nickel(0)

A

nickel(II) propionate

nickel(II) propionate

B

(triphenylphosphine)3(CO)nickelk
15376-83-7

(triphenylphosphine)3(CO)nickelk

C

ethene
74-85-1

ethene

D

phenol
108-95-2

phenol

Conditions
ConditionsYield
With triphenylphosphine In neat (no solvent) (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and Ni(PPh3)4, mixture stirred at 54°C for 20 h; GLC;A 73%
B n/a
C 100%
D 91%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

phenyl propionate
637-27-4

phenyl propionate

A

(triphenylphosphine)3(CO)nickelk
15376-83-7

(triphenylphosphine)3(CO)nickelk

B

ethene
74-85-1

ethene

C

phenol
108-95-2

phenol

Conditions
ConditionsYield
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 10), mixture stirred at 54°C for 21 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A 80%
B 100%
C 100%
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 4),mixture stirred at 54°C for 20 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A 60%
B 100%
C 100%
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 3),mixture stirred at 54°C for 20 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A 60%
B 90%
C 90%
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 2),mixture stirred at 54°C for 12 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A 30%
B 60%
C 60%
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 1),mixture stirred at 54°C for 12 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A n/a
B 40%
C 50%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

phenyl propionate
637-27-4

phenyl propionate

Tri(p-tolyl)phosphine
1038-95-5

Tri(p-tolyl)phosphine

A

ethene
74-85-1

ethene

B

Ni(CO)(P(C6H4CH3)3)3
74887-07-3

Ni(CO)(P(C6H4CH3)3)3

C

phenol
108-95-2

phenol

Conditions
ConditionsYield
In further solvent(s) Kinetics; (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and P(C6H4CH3)3 (P(Ph-CH3)3/Ni = 3) in acetophenone, mixture stirred at 65°C for 50 h;A 80%
B 85%
C 100%
N,N-Diallyltosylamide
50487-72-4

N,N-Diallyltosylamide

A

ethene
74-85-1

ethene

B

1-[(4-methylphenyl)sulfonyl]-2,5-dihydro-1H-pyrrole
16851-72-2

1-[(4-methylphenyl)sulfonyl]-2,5-dihydro-1H-pyrrole

Conditions
ConditionsYield
With Hoveyda-Grubbs catalyst second generation In dichloromethane at 40℃; for 1h; Concentration; Solvent; Temperature; Grubbs Olefin Metathesis; Flow reactor;A n/a
B 100%
With Hoveyda-Grubbs catalyst second generation In (2)H8-toluene at 29.84℃; Reagent/catalyst;
1,3-dithiolane-2-thione
822-38-8

1,3-dithiolane-2-thione

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

A

4,5-bis(methoxycarbonyl)-1,3-dithiole-2-thione
7396-41-0

4,5-bis(methoxycarbonyl)-1,3-dithiole-2-thione

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
at 120 - 140℃;A 99.6%
B n/a
ethylene dibromide
106-93-4

ethylene dibromide

ethene
74-85-1

ethene

Conditions
ConditionsYield
With triethylamine In water at 20℃; for 2h; Inert atmosphere; Irradiation;99%
With vanadocene In hexane Product distribution; vanadocene monobromide, vanadocene monochloride; other temperature and reaction time.;62%
Electrolysis;
2,2-diphenyl-1,3-dithiolane
6317-10-8

2,2-diphenyl-1,3-dithiolane

A

benzophenone
119-61-9

benzophenone

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
In chlorobenzene for 24h; Heating;A 99%
B n/a
7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid diisopropyl ester dimethyl ester
85597-87-1

7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid diisopropyl ester dimethyl ester

A

ethene
74-85-1

ethene

B

1H-Pyrrole-2,3,4,5-tetracarboxylic acid diisopropyl ester dimethyl ester
85597-95-1

1H-Pyrrole-2,3,4,5-tetracarboxylic acid diisopropyl ester dimethyl ester

Conditions
ConditionsYield
at 90 - 120℃; for 3h;A n/a
B 99%
ethanol
64-17-5

ethanol

A

diethyl ether
60-29-7

diethyl ether

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With alumina at 449.84℃; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere; Overall yield = 100 %;A 0.1%
B 98.9%
C2I2O2Rh(1-)*C8H20N(1+); tetraethylammonium iodide; hydrogen iodide In water at 110℃; Product distribution / selectivity; Inert atmosphere; Autoclave;A 10%
B 50%
1-methyl-3-(propyl-3-sulfonyl)imidazolium trifluoromethanesulfonate; CF3O3S(1-)*CHF3O3S*C7H13N2O3S(1+) at 240 - 260℃; for 4h; Product distribution / selectivity;A n/a
B 12%
methane
34557-54-5

methane

ethene
74-85-1

ethene

Conditions
ConditionsYield
under 760.051 Torr; Recess waveguide; Gas phase;98.53%
With hydrogen under 760.051 Torr; Product distribution / selectivity; Microwave irradiation;96.4%
Stage #1: methane
Stage #2: With alumina at 125℃; Reagent/catalyst; Temperature;
55%
ethane
74-84-0

ethane

ethene
74-85-1

ethene

Conditions
ConditionsYield
With oxygen; V-Mo-Nb-Te oxide98%
at 800℃; under 760.051 Torr; for 1h; Catalytic behavior; Gas phase; Flow reactor;84%
With disulfur; iron(II,III) oxide at 940℃; Reagent/catalyst; Temperature; Flow reactor;75.9%
methane
34557-54-5

methane

A

propene
187737-37-7

propene

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With iron sulfide at 800 - 900℃; other metal sulfides;A 2%
B 98%
With SAPO-34/HZSM-5 nanostructure In water at 370℃; for 20h; Reagent/catalyst; Inert atmosphere;
7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid tetramethyl ester
85597-84-8

7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid tetramethyl ester

A

ethene
74-85-1

ethene

B

tetramethyl 1H-pyrrole-2,3,4,5-tetracarboxylate
2703-15-3

tetramethyl 1H-pyrrole-2,3,4,5-tetracarboxylate

Conditions
ConditionsYield
at 90 - 120℃; for 3h;A n/a
B 98%
7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid di-tert-butyl ester dimethyl ester
85597-90-6

7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid di-tert-butyl ester dimethyl ester

A

ethene
74-85-1

ethene

B

1H-Pyrrole-2,3,4,5-tetracarboxylic acid di-tert-butyl ester dimethyl ester
85597-98-4

1H-Pyrrole-2,3,4,5-tetracarboxylic acid di-tert-butyl ester dimethyl ester

Conditions
ConditionsYield
at 90 - 120℃; for 3h;A n/a
B 98%
7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid dicyclohexyl ester dimethyl ester
85597-92-8

7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid dicyclohexyl ester dimethyl ester

A

ethene
74-85-1

ethene

B

1H-Pyrrole-2,3,4,5-tetracarboxylic acid dicyclohexyl ester dimethyl ester
85598-00-1

1H-Pyrrole-2,3,4,5-tetracarboxylic acid dicyclohexyl ester dimethyl ester

Conditions
ConditionsYield
at 90 - 120℃; for 3h;A n/a
B 98%
ethene
74-85-1

ethene

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With trimethylamine-N-oxide; [N(4-C6H4Br)3][B(C6F5)4]; triethylaluminum; [Cr(CO)4(2-C6H4(MeO))2PN(Me)P(2-C6H4(MeO))2] In toluene at 60℃; under 30002.4 Torr; for 1h;100%
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;99%
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;99%
ethene
74-85-1

ethene

ethane
74-84-0

ethane

Conditions
ConditionsYield
With hydrogen; [Ru2(μ-O2C-C6H4-CO2)2] at 20℃; for 5.4h; Kinetics; Product distribution; Further Variations:; Catalysts; reaction times;100%
With [1,1-(1,3-dimethylimidazol-2-ylidene)(PPh3)-3-(Py)-1,2-RhSB9H8]; hydrogen In dichloromethane-d2 under 3750.38 Torr; for 12h; Catalytic behavior; Time; Inert atmosphere;73%
With hydrogen; palladium25%
ethene
74-85-1

ethene

bis(2-chloroethyl)selenium dichloride
106471-36-7

bis(2-chloroethyl)selenium dichloride

Conditions
ConditionsYield
With selenium tetrachloride In benzene100%
With tetrachlorosilane; chloroform
With diselenium dichloride; benzene
ethene
74-85-1

ethene

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With bis(benzonitrile)palladium(II) dichloride; py.Co(N,N'-bis(alicylidene-o-phenylene)diamino).NO2 In tetrahydrofuran at 50℃; under 760 Torr; for 0.916667h;100%
With bis(benzonitrile)palladium(II) dichloride; py.Co(N,N'-bis(alicylidene-o-phenylene)diamino).NO2 In tetrahydrofuran at 50℃; under 760 Torr; for 0.916667h; Product distribution; influence of Pd/Co ratio, solvent, further olefins;100%
With aluminum(III) sulfate; water at 350 - 360℃;
styrene
292638-84-7

styrene

ethene
74-85-1

ethene

3-phenylbut-1-ene
934-10-1

3-phenylbut-1-ene

Conditions
ConditionsYield
With silver trifluoromethanesulfonate; triphenylphosphine; bi(allylnickel bromide) In dichloromethane at -55℃; under 760 Torr; for 2h;100%
With bi(allylnickel bromide); silver trifluoromethanesulfonate; triphenylphosphine In dichloromethane at -55℃; under 760 Torr; for 2h; Addition; Hydrovinylation;95%
With 2; diethylaluminium chloride; triphenylphosphine In dichloromethane; toluene under 7500.6 Torr; for 0.5h;90%
ethene
74-85-1

ethene

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

1,2-Bis-trifluormethyl-mercapto-ethan
674-64-6

1,2-Bis-trifluormethyl-mercapto-ethan

Conditions
ConditionsYield
Irradiation (UV/VIS); 44 h;100%
Irradiation (UV/VIS); 44 h;100%
Irradiation;
ethene
74-85-1

ethene

1,4-Dithia-7-azanorbornylium hexafluoroarsenate
106726-64-1

1,4-Dithia-7-azanorbornylium hexafluoroarsenate

Conditions
ConditionsYield
With dithionitronium hexafluoroarsenate In liquid sulphur dioxide Ambient temperature;100%
With dithionitronium hexafluoroarsenate In liquid sulphur dioxide for 1h; Ambient temperature;100%
ethene
74-85-1

ethene

carbon monoxide
201230-82-2

carbon monoxide

di-n-propylamine
142-84-7

di-n-propylamine

tri-n-propylamine
102-69-2

tri-n-propylamine

Conditions
ConditionsYield
di(rhodium)tetracarbonyl dichloride In ethanol at 115℃; under 37503 Torr; for 1.5h;100%
ethene
74-85-1

ethene

4-ethoxyphenylacetic acid chloride
10368-35-1

4-ethoxyphenylacetic acid chloride

6-ethoxy-3,4-dihydro-2(1H)-naphthalenone
69788-78-9

6-ethoxy-3,4-dihydro-2(1H)-naphthalenone

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane for 4h; Ambient temperature;100%
ethene
74-85-1

ethene

polyethylene

polyethylene

Conditions
ConditionsYield
With triphenylphosphine; bis(1,5-cyclooctadiene)nickel (0) In toluene at 25℃; under 22502.3 Torr; for 70h;100%
With tetramethyldialuminoxane; N,N'-(1,1-Me2-ethylene)bis(salicylideneaminato)Zr(IV)Cl2*THF In toluene at 25℃; under 7500.6 Torr; for 24h; Polymerization;
Pd-2 at 22℃; under 4137.18 Torr; for 12h; Polymerization;
ethene
74-85-1

ethene

3-acetoxy-3-(4-methoxyphenyl)prop-1-yne
99520-55-5

3-acetoxy-3-(4-methoxyphenyl)prop-1-yne

acetic acid 1-(4-methoxy-phenyl)-2-methylene-but-3-enyl ester

acetic acid 1-(4-methoxy-phenyl)-2-methylene-but-3-enyl ester

Conditions
ConditionsYield
With RuCl2(P(C6H11)3)(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)(=CHC6H5) In toluene at 80℃; under 760 Torr; for 0.5h;100%
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃; under 760.051 Torr; for 0.5h;100%
ethene
74-85-1

ethene

acetic acid 5-phenylpent-2-ynyl ester

acetic acid 5-phenylpent-2-ynyl ester

acetic acid 2-methylene-3-phenethylbut-3-enyl ester

acetic acid 2-methylene-3-phenethylbut-3-enyl ester

Conditions
ConditionsYield
With RuCl2(P(C6H11)3)(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)(=CHC6H5) In toluene at 80℃; under 760 Torr; for 0.5h;100%
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃; under 760.051 Torr; for 2h;94%
ethene
74-85-1

ethene

(1S,4R,5S,6R)-5,6-Bis-prop-2-ynyloxy-bicyclo[2.2.1]hept-2-ene
441741-15-7

(1S,4R,5S,6R)-5,6-Bis-prop-2-ynyloxy-bicyclo[2.2.1]hept-2-ene

(4aS,4bR,8aS,9aR)-2,7-Divinyl-4a,4b,6,8a,9,9a-hexahydro-3H-4,5-dioxa-fluorene
441741-16-8

(4aS,4bR,8aS,9aR)-2,7-Divinyl-4a,4b,6,8a,9,9a-hexahydro-3H-4,5-dioxa-fluorene

Conditions
ConditionsYield
Grubbs catalyst first generation In dichloromethane at 20℃; for 4h;100%
Grubbs catalyst first generation In dichloromethane at 20℃; for 4h;53%
ethene
74-85-1

ethene

N-(cyclopentenylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide
477977-14-3

N-(cyclopentenylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide

2-(toluene-4-sulfonyl)-1,2,3,4,5,6-hexahydro-cyclohepta[c]pyrrole

2-(toluene-4-sulfonyl)-1,2,3,4,5,6-hexahydro-cyclohepta[c]pyrrole

Conditions
ConditionsYield
Cl2(PCy3)(N,N'-(Mes)2-imidazolidin-2-yl)Ru=CHC6H5 In dichloromethane under 760.051 Torr; for 26h; Heating;100%
ethene
74-85-1

ethene

8,8-dimethyl-4-phenyl-6,10-dioxa-spiro[4.5]deca-1,3-diene-1,2-dicarboxylic acid dimethyl ester
780755-05-7

8,8-dimethyl-4-phenyl-6,10-dioxa-spiro[4.5]deca-1,3-diene-1,2-dicarboxylic acid dimethyl ester

C22H26O6

C22H26O6

Conditions
ConditionsYield
In toluene at 100℃; for 192h; Diels-Alder reaction; ambient pressure;100%
ethene
74-85-1

ethene

Pentafluoroethyl iodide
354-64-3

Pentafluoroethyl iodide

1,1,1,2,2-pentafluoro-4-iodobutane
40723-80-6

1,1,1,2,2-pentafluoro-4-iodobutane

Conditions
ConditionsYield
With Vazo64100%
With triethyl phosphite71%
With hydrazine hydrate; copper (I) acetate In isopropyl alcohol at 30℃; under 22800 Torr; for 4h;69%
copper at 80℃; under 6000.6 - 7500.75 Torr; for 1.33333h; Product distribution / selectivity;
With VAZO 64 at 65 - 81℃; under 4897.34 - 8931.21 Torr; for 3h; Industry scale; Autoclave;97.3 %Chromat.
N-(1S)-[(2S)-2-((1R)-1-hydroxy-3-trimethylsilyl-2-propyn-1-yl)-4-pentenoyl]bornane-10,2-sultam

N-(1S)-[(2S)-2-((1R)-1-hydroxy-3-trimethylsilyl-2-propyn-1-yl)-4-pentenoyl]bornane-10,2-sultam

ethene
74-85-1

ethene

N-(1S)-[1-[(1S,2R)-2-hydroxy-3-(1-trimethylsilylethen-1-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

N-(1S)-[1-[(1S,2R)-2-hydroxy-3-(1-trimethylsilylethen-1-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

Conditions
ConditionsYield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃;100%
N-(1S)-[(2R,3R)-6-benzyloxy-3-hydroxy-2-allyl-hex-4-ynoyl]bornane-10,2-sultam

N-(1S)-[(2R,3R)-6-benzyloxy-3-hydroxy-2-allyl-hex-4-ynoyl]bornane-10,2-sultam

ethene
74-85-1

ethene

N-(1S)-[1-[(1R,2R)-2-hydroxy-3-(3-(benzyloxy)prop-1-en-2-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

N-(1S)-[1-[(1R,2R)-2-hydroxy-3-(3-(benzyloxy)prop-1-en-2-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

Conditions
ConditionsYield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃;100%
N-(1S)-[(2R,3R)-6-benzyloxy-3-triethylsilyloxy-2-propen-3-yl-hex-4-ynoyl]bornane-10,2-sultam

N-(1S)-[(2R,3R)-6-benzyloxy-3-triethylsilyloxy-2-propen-3-yl-hex-4-ynoyl]bornane-10,2-sultam

ethene
74-85-1

ethene

N-(1S)-[1-[(1R,2R)-2-triethylsilyloxy-3-(3-(benzyloxy)prop-1-en-2-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

N-(1S)-[1-[(1R,2R)-2-triethylsilyloxy-3-(3-(benzyloxy)prop-1-en-2-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

Conditions
ConditionsYield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃;100%

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