2752-95-6

Basic information

• Product Name: butyl diphenyl phosphate
• Synonyms: butyl diphenyl phosphate;Phosphoric acid, butyl diphenyl ester;phosphoric acid butyl ester diphenyl ester
• CAS NO: 2752-95-6
• Molecular Formula: C₁₆H₁₉O₄P
• Molecular Weight: 306.293421
• EINECS: 220-398-1
• Mol File: 2752-95-6.mol

Chemical Properties

• Boiling Point: 368.4 °C at 760 mmHg
• Flash Point: 190.2 °C
• Appearance: /
• Density: 1.0410 (rough estimate)
• Vapor Pressure: 2.7E-05mmHg at 25°C
• Refractive Index: 1.4820 (estimate)
• Water Solubility: <0.2g/L(25 oC)
• CAS DataBase Reference: butyl diphenyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: butyl diphenyl phosphate(2752-95-6)
• EPA Substance Registry System: butyl diphenyl phosphate(2752-95-6)

Safety Data

• Hazardous Substances Data: 2752-95-6(Hazardous Substances Data)

Usage

Uses

Butyl Phenyl Phosphate is a phosphorus flame retardant additive.

InChI:InChI=1/C16H19O4P/c1-2-3-14-18-21(17,19-15-10-6-4-7-11-15)20-16-12-8-5-9-13-16/h4-13H,2-3,14H2,1H3

Upstream product

• 838-85-7 diphenyl hydrogen phosphate 
• 15383-55-8 O-butyl-N,N'-di-p-tolyl-isourea 
• 2052-49-5 tetra(n-butyl)ammonium hydroxide 
• 115-86-6 phosphoric acid triphenyl ester 
• 429-42-5 tetrabutylammonium tetrafluoroborate 
• 10359-36-1 4-nitro-phenyl diphenyl phosphate 
• 6921-14-8 Diphenyl potassium phosphate 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 71-36-3 butan-1-ol 
• 85328-97-8 (2-Oxo-benzooxazol-3-yl)-phosphonic acid diphenyl ester 
• 78605-38-6 Diphenyl 2-oxo-3-oxazolinylphosphonate 
• 72305-35-2 diphenyl (4,6-dimethyl-2-pyrimidyl) phosphate 
• 56826-01-8 diphenyl (4-oxo-3,4-dihydro-2-pyrimidyl) phosphate 
• 1498-52-8 butyl dichlorophosphate 

Relevant articles and documents

Zinc-catalyzed transformation of diarylphosphoryl azides to diarylphosphate esters and amides

We have developed a facile and efficient procedure for the synthesis of diarylphosphate esters and amides. Using Zn(acac)2 as the catalyst, the reaction of diarylphosphoryl azides with aliphatic alcohols and phenols through an unusual P?N bond cleavage provided a number of diarylphosphate esters in good yields (22 examples, up to 94%). Additionally, various diarylphosphate amides were obtained from the corresponding amines in excellent yields as well (8 examples, up to 96%).

Recyclable copper catalyst on chitosan for facile preparation of alkyl/aryl mixed phosphates via deaminated esterification between diphenylphosphoryl azides and aliphatic alcohols

An efficient methodology was established for the preparation of alkyl/aryl mixed phosphates under aerobic conditions promoted by a easily recoverable heterogeneous catalyst. This highly active copper catalyst was obtained by directly mixing of copper precursor with chitosan solution, followed by a simple work-up process. In this catalytic system, different phosphoryl azides and aliphatic alcohols were employed to generate desired products in moderate to excellent yields with good functional group tolerance. This protocol provided a practical application of the chitosan supported heterogeneous copper catalyst towards a novel P–O bond formation.

Copper catalyzed synthesis of aryl/alkyl mixed phosphates from diphenylphosphoryl azides and aliphatic alcohols under mild conditions

An efficient and convenient one-pot protocol is developed to prepare aryl/alkyl mixed phosphates in the presence of copper catalyst under exceptionally mild conditions. A series of versatile, ubiquitous, and inexpensive phosphoryl azides and aliphatic alcohols are combined for the first time ever. Diphenylphosphoryl azide is employed as novel phosphors reagent through an unexpected cleavage of P[sbnd]N bond. The transformation is advantageous with respect to a broad of functional group compatibility and different esterification products are isolated in good to excellent results. This new catalytic system represents a superior platform towards a mild, operationally simple, practical, and scalability alternative to access target molecules. Furthermore, a plausible mechanism is proposed based on insightful mechanistic studies.

Synthesis method of copper-catalyzed phosphate mixed ester compound

The invention provides a synthesis method of a copper-catalyzed phosphate mixed ester compound. The synthesis method comprises the steps that a phosphate ester azide compound and fatty alcohol are mixed, then a copper catalyst is added, alkali is added, reaction is conducted at the temperature of 20-100 DEG C for 3-24 h, and the phosphate mixed ester compound is obtained through aftertreatment. According to the synthesis method, the phosphate ester azide compound and the fatty alcohol are adopted to synthesize the phosphate mixed ester compound for the first time, in the synthesis process, only the copper catalyst and the alkali with the catalytic dosage are needed to be added, operation is easy, the defect of needing inert gas protection is overcome, and the synthesis method is novel andefficient.

Direct aerobic oxidative esterification and arylation of P(O)-OH compounds with alcohols and diaryliodonium triflates

Copper-catalyzed aerobic oxidative esterification of P(O)-OH compounds is achieved using alcohols as efficient esterification reagents, giving the expected products with good to moderate yields. Furthermore, it is shown that the arylation of P(O)-OH compounds proceeds efficiently to produce the corresponding products via the treatment of diaryliodonium triflates under mild reaction conditions. It is a simple way to produce a broad spectrum of functionalized phosphinates, phosphonates, and phosphates from basic starting materials with good to excellent yields. The protocol is convenient for practical application. A plausible mechanism has been proposed for the reaction.

P-Toluenesulfonic acid-Celite as a reagent for synthesis of esters of alkylphosphonic acids under solvent-free conditions

The coupling reaction of alkylphosphonic acids and alcohols on the surface of p-toluenesulfonic acid-Celite under mild and solvent-free conditions gave the corresponding phosphonates in excellent yields. This method provides a useful rapid synthesis of phosphonates for use in the unambiguous identification of chemical warfare agents.

Efficient and convenient one-pot synthesis of phosphoramidates and phosphates

A simple and efficient one-pot method is described for the synthesis of phosphoramidates/phosphates in excellent yields from dialkylphosphites and trichloroisocyanuric acid in acetonitrile and subsequent treatment with dialkyl amines/alcohols. The procedure is operationally simple, has reduced reaction times, and uses a one-pot procedure. Copyright Taylor & Francis Group, LLC.

An efficient method for the esterification of phosphonic and phosphoric acids using silica chloride

Silica chloride is used as an effective heterogeneous catalyst for the rapid esterification of alkyl/aryl phosphonic/phosphoric acids to their corresponding alkyl/aryl phosphonates/phosphates under mild conditions with quantitative yields.

Surface-mediated solid phase reactions: A simple, efficient and base-free synthesis of phosphonates and phosphates on Al2O3

Al2O3-supported solvent free condensation of alkylphosphonic dichlorides with alcohols at room temperature yielded phosphorus esters in excellent yields.