cas 27928-00-3, 8-Hydroxypyrene-1,3,6-trisulfonicacidtrisodiumsalt | Articles data ｜lookchem

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27928-00-3

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Structure-activity relationship studies in single-site esterase peptide dendrimers
We recently reported on peptide dendrimers with a single catalytic site at the dendrimer core catalyzing the hydrolysis of acetoxy- and butyryloxy-pyrene trisulfonate 1a/b in aqueous buffer with Michaelis-Menten kinetics. Substrate binding is mediated by
Javor, Sacha,Reymond, Jean-Louis
p. 129 - 136
(2009)
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Excited-State Proton-Transfer Kinetics: A Theoretical Model
The intersecting-state model is applied to excited state proton-transfer reactions.The results are consistent with those previously obtained for the analogous ground-state reactions.The transition-state bond order n* is similar in the ground and excited states: carbon acids have lower n* than nitrogen or oxygen acids.The mixing entropy parameter λ is found to be lower for excited-state than ground-state reactions.The mechanistic implications of this are discussed.
Arnaut, Luis G.,Formosinho, Sebastiao J.
p. 685 - 691
(2007/10/02)

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Chemical Properties

Density: 2.004 g/cm³
PKA: -0?+-.0.30(Predicted)
PSA: 208.48000
LogP: 5.27210

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