Tetranitromethane as an efficient reagent for the conversion of epoxides into β-hydroxy nitrates
A convenient regioselective method for the preparation of β-hydroxy nitrates based on the ring opening reaction of epoxides by tetranitromethane in the presence of triethylamine is described. A series of substituted β-hydroxy nitrates were obtained in high yields under mild conditions.
Volkova, Yuliya A.,Ivanova, Olga A.,Budynina, Ekaterina M.,Averina, Elena B.,Kuznetsova, Tamara S.,Zefirov, Nikolai S.
p. 3935 - 3938
(2008/09/21)
NITRATION EQUILIBRIUM IN THE MESO-ERYTHRITOL-AQUEOUS NITRIC ACID SYSTEM
Twelve equilibrium constants have been measured from 16 for sequential-parallel reactions in meso-erythritol nitration to the fully nitrated compound in aqueous HNO3.Free-energy changes during nitration of the aliphatic polyatomic alcohols, glycerol and meso-erythritol, are highest when diprimary dinitrates (NOON) and (NON) are produced.
Kazakov, A. I.,Lagodzinskaya, G. V.,Yunda, N. G.,Andrienko, L. P.,Korolev, A. M.,et al.
p. 1966 - 1971
(2007/10/02)
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