Alpha-GLYCOSYL THIOLS AND alpha-S-LINKED GLYCOLIPIDS
The present invention relates to stereoselective methods for the preparation of α-glycosyl thiols and α-S-linked glycosylceramides.
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Page/Page column 5; Figure 2
(2010/08/07)
Synthesis of Sphingosines, Part 8. Synthesis of Methyl-Branched Sphingosines
Treatment of 2,4-O-benzylidene-D-threose (3) with the Wittig reagent obtained from 2-bromopentadecane furnished 5-methyloctadec-4-ene derivatives (E,Z)-8.The introduction of the azido group into the 2-position and acid-catalyzed removal of the benzylidene
Baer, Thomas,Kratzer, Bernd,Wild, Robert,Sandhoff, Konrad,Schmidt, Richard R.
p. 419 - 426
(2007/10/02)
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