303752-90-1

Upstream product

• 88303-25-7 tetradecylmagnesium bromide 
• 99274-32-5 2,4-O-benzylidene-D-threose 
• 112-71-0 1-Bromotetradecane 

Downstream Products

• 150162-78-0 (2R,3S)-1,3-O-benzylidene-1,2,3-octadecanetriol-4-one 
• 117168-66-8 (2S,4R,5R)-4-[(R)-1-hydroxypentadecyl]-2-phenyl-1,3-dioxan-5-yl methanesulfonate 
• 150162-80-4 (2R,3S,4R)-1,3-O-benzylidene-2-(tert-butyldimethylsilyloxy)-4-methyloctadecane-1,3,4-triol 
• 150162-87-1 (2R,3S,4S)-1,3-O-benzylidene-2-(tert-butyldimethylsilyloxy)-4-methyloctadecane-1,3,4-triol 
• 150162-86-0 (2R,3S,4S)-1,3-O-benzylidene-4-methyloctadecane-1,2,3,4-tetrol 
• 150162-79-1 (2R,3S,4R)-1,3-O-benzylidene-4-methyloctadecane-1,2,3,4-tetrol 
• 117168-66-8 1,3-O-benzylidene-2-O-methanesulfonyl-L-xylo-1,2,3,4-octadecanetetrol 
• 117168-67-9 2-azido-1,3-O-benzylidene-L-lyxo-1,3,4-octadecanetriol 
• 117168-58-8 2-azido-1,3-O-benzylidene-D-ribo-1,3,4-octadecanetriol 
• 117168-65-7 (2R,3R,4S)-1,3-O-benzylidene-1,2,3,4-octadecanetetrol 
• 117168-55-5 (2R,3R,4R)-1,3-O-benzylidene-1,2,3,4-octadecanetetrol 
• 117168-59-9 (2S,3S,4R)-2-azido-1,3,4-octadecanetriol 
• 114275-40-0 (2R,3R)-trans-2-azide-1,3-O-benzylidene-1,3-octadec-4-enediol 
• 554-62-1 D-ribo-phytosphingosine 

Relevant academic research and scientific papers

Alpha-GLYCOSYL THIOLS AND alpha-S-LINKED GLYCOLIPIDS

The present invention relates to stereoselective methods for the preparation of α-glycosyl thiols and α-S-linked glycosylceramides.

Synthesis of Sphingosines, Part 8. Synthesis of Methyl-Branched Sphingosines

Treatment of 2,4-O-benzylidene-D-threose (3) with the Wittig reagent obtained from 2-bromopentadecane furnished 5-methyloctadec-4-ene derivatives (E,Z)-8.The introduction of the azido group into the 2-position and acid-catalyzed removal of the benzylidene