31037-00-0

Basic information

• Product Name: m,m'-Diiodobiphenyl
• Synonyms: 3,3'-Diiodobiphenyl;m,m'-Diiodobiphenyl;3,3'-diiodo-1,1'-biphenyl
• CAS NO: 31037-00-0
• Molecular Formula: C₁₂H₈I₂
• Molecular Weight: 406.00086
• Mol File: 31037-00-0.mol

Chemical Properties

• Melting Point: 76-77℃ (ethanol )
• Boiling Point: 417.1±38.0 °C(Predicted)
• Appearance: /
• Density: 2.041±0.06 g/cm3(Predicted)
• CAS DataBase Reference: m,m'-Diiodobiphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: m,m'-Diiodobiphenyl(31037-00-0)
• EPA Substance Registry System: m,m'-Diiodobiphenyl(31037-00-0)

Safety Data

• Hazardous Substances Data: 31037-00-0(Hazardous Substances Data)

Upstream product

• 626-00-6 1,3-Diiodobenzene 
• 107-18-6 allyl alcohol 
• 2050-89-7 3,3'-diaminobiphenyl 

Downstream Products

• 92-52-4 biphenyl 
• 641-96-3 2,2'-diphenylbiphenyl 
• 56692-39-8 2,2'''-diphenyl-m-quaterphenyl 
• 84-15-1 o-terphenyl 
• 7104-67-8 2,2'''-diphenyl-p-quaterphenyl 
• 78486-73-4 4,4'''-di(2-biphenylyl)-m-quaterphenyl 
• 1166-18-3 meta-quaterphenyl 
• 4740-51-6 m-sexiphenyl 
• 1486-01-7 biphenyl-d10 
• 78486-61-0 3,3'-di(phenyl-d5)biphenyl 
• 25044-47-7 3,3'-di(4-biphenylyl)biphenyl 
• 1166-19-4 3,4'-diphenylbiphenyl 

Relevant articles and documents

Heck arylation of allyl alcohol catalyzed by Pd(0) nanoparticles

Pd(0) nanoparticles ca. 2 nm in diameter were obtained by the reduction of PdCl2 and Pd(OAc)2 in water at 80 °C in the presence of a PVP-stabilizing polymer. Pd(0) NPs were successfully used in the Heck coupling of allyl alcohol with iodo- and bromobenzenes. Iodobenzenes reacted under solventless conditions or in DMF solution producing 3-arylpropanals and 2-arylpropanals as the main products. The same products were obtained in the reaction of bromobenzene in TBAB as the reaction medium. The stability of Pd(0) NPs was evidenced in recycling experiments. Similar Heck coupling results were also obtained with the palladium compounds PdCl2(cod) and Pd(OAc)2 under the same conditions.