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D-xylo-Hexitol, 2,5-anhydro-1,4,6-trideoxy-1,6-epithio-3-O-methyl- (9CI) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • D-xylo-Hexitol, 2,5-anhydro-1,4,6-trideoxy-1,6-epithio-3-O-methyl- (9CI)

    Cas No: 316376-08-6

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  • 316376-08-6 Structure
  • Basic information

    1. Product Name: D-xylo-Hexitol, 2,5-anhydro-1,4,6-trideoxy-1,6-epithio-3-O-methyl- (9CI)
    2. Synonyms: D-xylo-Hexitol, 2,5-anhydro-1,4,6-trideoxy-1,6-epithio-3-O-methyl- (9CI)
    3. CAS NO:316376-08-6
    4. Molecular Formula: C7H12O2S
    5. Molecular Weight: 160.23398
    6. EINECS: N/A
    7. Product Categories: METHOXY
    8. Mol File: 316376-08-6.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: D-xylo-Hexitol, 2,5-anhydro-1,4,6-trideoxy-1,6-epithio-3-O-methyl- (9CI)(CAS DataBase Reference)
    10. NIST Chemistry Reference: D-xylo-Hexitol, 2,5-anhydro-1,4,6-trideoxy-1,6-epithio-3-O-methyl- (9CI)(316376-08-6)
    11. EPA Substance Registry System: D-xylo-Hexitol, 2,5-anhydro-1,4,6-trideoxy-1,6-epithio-3-O-methyl- (9CI)(316376-08-6)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 316376-08-6(Hazardous Substances Data)

316376-08-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 316376-08-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,1,6,3,7 and 6 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 316376-08:
(8*3)+(7*1)+(6*6)+(5*3)+(4*7)+(3*6)+(2*0)+(1*8)=136
136 % 10 = 6
So 316376-08-6 is a valid CAS Registry Number.

316376-08-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,6:2,5-dianhydro-4-deoxy-3-O-methyl-1-thio-D-xylo-hexitol

1.2 Other means of identification

Product number -
Other names (1S,5R,6S)-6-Methoxy-8-oxa-3-thia-bicyclo[3.2.1]octane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:316376-08-6 SDS

316376-08-6Downstream Products

316376-08-6Relevant articles and documents

Synthesis of 4-cyano- and 4-nitrophenyl 2,5-anhydro-1,6-dithio-α-d-gluco- and -α-L-guloseptanosides carrying different substituents at C-3 and C-4

Bozo, Eva,Boros, Sandor,Parkanyi, Laszlo,Kuszmann, Janos

, p. 269 - 286 (2000)

Treatment of 1,6:2,5-dianhydro-3,4-di-O-methanesulfonyl-1-thio-D-glucitol in methanol with sodium hydroxide afforded 1,6:2,5:3,4-trianhydro-1-thio-allitol, 1,4:2,5-dianhydro-6-methoxy-1-thio-D-galactitol, 1,6:2,5-dianhydro-4-O-methyl-1-thio-D-glucitol, 1,6:2,5-dianhydro-3-O-methanesulfonyl-1-thio-D-glucitol and 1,6:2,5-dianhydro-4-deoxy-1-thio-D-erythro-hex-3-ulose (14) in 5, 4, 28, 5.5 and 41% yield, respectively. Formation of these derivatives can be explained via a common sulfonium intermediate. Reduction of 14 with sodium borohydride and subsequent acetylation afforded 3-O-acetyl-1,6:2,5-dianhydro-4-deoxy-1-thio-D-xylo-hexitol, the absolute configuration of which was proved by X-ray crystallography. The 1,6:2,5-dianhydro-1-thio-D-hexitol derivatives in which the free OH groups were protected by acetylation, methylation or mesylation were converted by a Pummerer reaction of their sulfoxides into the corresponding 1-O-acetyl hexoseptanose derivatives which were used as donors for the glycosidation of 4-cyano- and 4-nitrobenzenethiol, respectively. The Pummerer reaction of 1,6:2,5-dianhydro-4-deoxy-3-O-methyl-1-thio-D-xylo-hexitol S-oxide gave, besides 1-O-acetyl-2,5-anhydro-3-deoxy-4-O-methyl-6-thio-α-L- (23) and 1-O-acetyl-2,5-anhydro-4-deoxy-3-O-methyl-6-thio-α-D-xylo-hexose ptanose (25), 1-O-acetyl-4-deoxy-2,6-thioanhydro-D-lyxo-hexopyranose, formed in a rearrangement reaction. The same rearrangement took place, when a mixture of 23 and 25 was used as donor in the glycosidation reaction with 4-cyanobenzenethiol, applying trimethylsilyl triflate as promoter. The oral antithrombotic activity of the obtained α-thioglycosides was determined in rats, using Pescador's model. (C) Elsevier Science Ltd.

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