cas 352303-67-4, 2-FLUORO-3-METHOXYPHENYLBORONIC ACID | Articles data ｜lookchem

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352303-67-4

Articles about 352303-67-4Total 3 be found

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Base free aryl coupling of diazonium compounds and boronic esters: Self-activation allowing an overall highly practical process
Boronic esters have long been considered as poor partners in cross-coupling reactions with arene diazoniums. Here is reported an unprecedented application of self-activated boronic esters in a base-free cross-coupling reaction with diazonium salts under mild and user friendly conditions.
Bonin, Helene,Delbrayelle, Dominique,Demonchaux, Patrice,Gras, Emmanuel
supporting information; experimental part
p. 2677 - 2679
(2010/07/08)

Gonadotropin-releasing hormone receptor antagonists and methods relating thereto
GnRH receptor antagonists are disclosed which have utility in the treatment of a variety of sex-hormone related conditions in both men and women. The compounds of this invention have the structure: wherein A, Q, R1, R2, R3a, R3b, R4, R5, R6 and n are as defined herein, including stereoisomers, prodrugs and pharmaceutically acceptable salts thereof. Also disclosed are compositions containing a compound of this invention in combination with a pharmaceutically acceptable carrier, as well as methods relating to the use thereof for antagonizing gonadotropin-releasing hormone in a subject in need thereof.
-
(2008/06/13)

Substituted 3-amino biaryl propionic acids as potent VLA-4 antagonists.
A series of substituted N-(3,5-dichlorobenzenesulfonyl)-(L)-prolyl- and (L)-azetidyl-beta-biaryl beta-alanine derivatives was prepared as selective and potent VLA-4 antagonists. The 2,6-dioxygenated biaryl substitution pattern is important for optimizing potency. Oral bioavailability was variable and may be a result of binding to circulating plasma proteins.
Kopka, Ihor E,Lin, Linus S,Mumford, Richard A,Lanza Jr., Thomas,Magriotis, Plato A,Young, David,DeLaszlo, Stephen E,MacCoss, Malcolm,Mills, Sander G,Van Riper, Gail,McCauley, Ermengilda,Lyons, Kathryn,Vincent, Stella,Egger, Linda A,Kidambi, Usha,Stearns, Ralph,Colletti, Adria,Teffera, Yohannes,Tong, Sharon,Owens, Karen,Levorse, Dorothy,Schmidt, John A,Hagmann, William K
p. 2415 - 2418
(2007/10/03)

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Chemical Properties

Melting Point: 117-122 ºC(lit.)
Boiling Point: 326.8 ºC at 760 mmHg
Flash Point:151.4 ºC
Density: 1.26 g/cm³
Solubility:Chloroform (Slightly, Heated), DMSO (Slightly), Methanol (Slightly)
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
Vapor Pressure: 8.56E-05mmHg at 25°C
Refractive Index: 1.503
PKA: 7.90±0.58(Predicted)
BRN: 9191510
PSA: 49.69000
LogP: -0.48590

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