3539-42-2Relevant articles and documents
Extractant as well as preparation method and application thereof
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Paragraph 0083-0088, (2021/09/15)
The invention relates to the technical field of rare earth recovery, and discloses an extraction agent and a preparation method and application of the extraction agent. The extraction agent is a novelextraction agent with a dicarboxylic acid structure, an
Organic precipitator as well as preparation method and application thereof
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Paragraph 0091-0093, (2018/09/08)
The invention belongs to the field of rare earth gathering, and particularly relates to an organic precipitator as well as a preparation method and application thereof. The organic precipitator provided by the invention is prepared from one or more of structural compounds of formula (I) to formula (III), wherein R1, R2, R3 and R'3 are independently selected from hydrogen, substituted or non-substituted linear chain alkyl with the number of carbon atoms of 1 to 10, substituted or non-substituted branched alkyl with the number of the carbon atoms of 3 to 10, and substituted or non-substituted aryl; n is a natural integer; and M indicates cations. The organic precipitator provided by the invention has good selectivity to the rare earth and is very suitable for gathering rare-earth elements in a low-concentration rare-earth solution. The experiment result shows that when the organic precipitator provided by the invention is used for gathering the rare earth in the low-concentration rare earth solution, the precipitation speed is high, the purity of the gathered rare earth product is greater than 96 percent, and the yield is greater than 95 percent. (The formula (I) to (III) are shown in the description).
Dihydroxy aromatic compounds and methods for preparation
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Page/Page column 17, (2010/11/25)
A dihydroxy aromatic compound having a Formula (I), wherein R1 is a C6–C60 aromatic divalent functionality, R2 at each occurrence, can be the same or different and is independently at each occurrence selected from the group consisting of a cyano functionality, a nitro functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons and an aromatic functionality having 6 to 10 carbons, and “n” is an integer having a value of 0 to 4.
Tryptase inhibitors
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, (2008/06/13)
The invention relates to novel inhibitors of human tryptase which are used in the pharmaceutical industry for the production of medicaments.
Molecular recognition of β-ribofuranosides by synthetic polypyridine-macrocyclic receptors
Inouye, Masahiko,Miyake, Toshiyuki,Furusyo, Masaru,Nakazumi, Hiroyuki
, p. 12416 - 12425 (2007/10/03)
Artificial ribofuranoside receptors were designed and synthesized. The design of the polypyridine-macrocyclic receptors was based on the multipoint hydrogen bond complementarity between the receptors and methyl β-D-ribofuranoside. The binding affinity of the receptors for the ribofuranoside in CDCl3 was very high (up to K(a) = 5.2 x 103 M-1), so that even native ribose was extracted by them into such nonpolar solvents. Selective extraction of ribose by the receptors was observed: the extractabilities, or affinities to the receptors of various pentoses and hexoses decreased in the following order: ribose > deoxyribose ? lyxose ? xylose > fructose > arabinose > glucose ? mannose ? galactose. The selectivity is governed by the OH direction and the whole size of the sugars as well as their shapes. Furthermore, fluorescence emission of the receptors was largely enhanced in the presence of methyl β-D-ribofuranoside or ribose, and the degree for the fluorescence enhancement by the addition of various sugars was almost compatible with that of the extractabilities. The polypyridine-macrocycles represent rationally designed multifunctional artificial receptors for ribofuranosides.