355-93-1

Basic information

• Product Name: 1H,1H,5H-OCTAFLUOROPENTYL METHACRYLATE
• Synonyms: 2,2,3,3,4,4,5,5-Octafluoropentyl 2-methylacrylate;2-Propenoic acid, 2-methyl-, 2,2,3,3,4,4,5,5-octafluoropentyl ester;1H,1H,5H-PERFLUOROPENTYL METHACRYLATE;1H,1H,5H-OCTAFLUOROPENTYL METHACRYLATE;2,2,3,3,4,4,5,5-OCTAFLUOROPENTYL METHACRYLATE;METHACRYLIC ACID 1H,1H,5H-OCTAFLUOROPENTYL ESTER;METHACRYLIC ACID 1H,1H,5H-PERFLUOROPENTYL ESTER;DAIKIN M-5410
• CAS NO: 355-93-1
• Molecular Formula: C₉H₈F₈O₂
• Molecular Weight: 300.15
• EINECS: 206-596-0
• Product Categories: monomer;Fluorinated AcrylicsSelf Assembly&Contact Printing;Fluorine-Containing Monomers for 157 nm UV Lithography Resist Polymers;Lithography Monomers;Acrylic Monomers;Monomers
• Mol File: 355-93-1.mol

Chemical Properties

• Melting Point: 8-12°C
• Boiling Point: 88 °C40 mm Hg(lit.)
• Flash Point: 178 °F
• Appearance: /
• Density: 1.432 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0659mmHg at 25°C
• Refractive Index: n20/D 1.358(lit.)
• Storage Temp.: Keep Cold
• Water Solubility: 30mg/L at 20℃
• BRN: 1801409
• CAS DataBase Reference: 1H,1H,5H-OCTAFLUOROPENTYL METHACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: 1H,1H,5H-OCTAFLUOROPENTYL METHACRYLATE(355-93-1)
• EPA Substance Registry System: 1H,1H,5H-OCTAFLUOROPENTYL METHACRYLATE(355-93-1)

Safety Data

• Hazard Codes: Xi,F
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• HazardClass: KEEP COLD, FLAMMABLE
• Hazardous Substances Data: 355-93-1(Hazardous Substances Data)

Usage

Flammability and Explosibility

Notclassified

InChI:InChI=1/C9H8F8O2/c1-2-3-7(12,13)9(16,17)8(14,15)4(5(10)11)6(18)19/h2-3H2,1H3,(H,18,19)

Upstream product

• 355-80-6 2,2,3,3,4,4,5,5-octafluoropentan-1-ol 
• 920-46-7 Methacryloyl chloride 
• 6900-35-2 potassium methacrylate 
• 254756-55-3 5-[(chlorosulfinyl)oxy]-1,1,2,2,3,3,4,4-octafluoropentane 

Relevant articles and documents

Polyfluoroalkyl chlorosulfites as new polyfluorinating agents

The interaction of polyfluorinated alcohols with triethylamine and the kinetics of the reaction of the resulting triethylamine complexes with thionyl chloride were studied, the mechanism of formation of polyfluoroalkyl chlorosulfites was considered, and the optimal reaction conditions were found. The alkylating power of polyfluoroalkyl chlorosulfites was studied in reactions with alkali metal halides (to obtain polyfluorohaloalkanes), in synthesis of acrylic and methacrylic acid esters, and in synthesis of polyfluoroalkyl ethers (with polyfluoroalkyl 1-adamantyl ethers as example).

Synthesis of fluorinated block copolymers and their application as novel polymerisation surfactants in supercritical carbon dioxide

Screened anionic copolymerisation of methyl methacrylate with the perfluoroalkyl methacrylates 2 affords well-defined AB block copolymers 4-6, which serve as effective surfactants in the dispersion polymerisation of methyl methacrylate in supercritical carbon dioxide.

SYNTHESIS AND PHYSICOCHEMICAL PROPERTIES OF ORGANOFLUORINE ESTERS OF ACRYLIC, METHACRYLIC, AND MALEIC ACIDS.

The purpose of this work is to synthesize, and to study the physicochemical properties of organofluorine acrylates, methacrylates, and maleates.